Thermoplastic molding compositions which are mixtures of amorphous and semi-crystalline polyamides, a method of preparation thereof and products made therefrom

• US 5,288,799 A
• Filed: 07/02/1992
• Issued: 02/22/1994
• Est. Priority Date: 07/04/1991
• Status: Expired due to Term

• Current Assignee: EMS-Patent AG (Emesta Holding AG)
• Original Assignee: EMS-Inventa AG (Emesta Holding AG)
• Inventors: Thullen, Helmuth, Schmid, Eduard
• Primary Examiner(s): Carrillo, Ana L.
• Application Number:
  US07/908,322
• Time in Patent Office: 600 Days
• Field of Search: 525/420.5, 525/66, 525/183, 528/339.3
• US Class Current: 525/66
• CPC Class Codes: C08L 77/00 Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain of polyhydrazides C08L79/06; of polyamideimides or polyamide acids C08L79/08; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 77/08 from polyamines and polymerised unsaturated fatty acids

Abstract

Thermoplastic molding compositions including a semicrystalline polyamide a) and an amorphous copolyamide b), the latter containing dimerized fatty acid as one monomer building block. Optionally, a compatibility agent and other additives are also included.

The molding compounds having high stiffness up to at least 100° C. are produced by melt-mixing components a) and b), and optionally a compatibilizer, and are used for making molded parts which are outstanding in their thermal properties, high solvent resistance, and resistance to stress corrosion.

Claims

1. A thermoplastic molding composition comprising

a) 25-75 parts of a semicrystalline polyamide;

b) 75-25 parts of an amorphous copolyamide of

(i) 25-45 molar parts of at least one aromatic dicarboxylic acid,

(ii) 25-5 molar parts of at least one dimerized fatty acid,

(iii) 50 molar parts of at least one cycloaliphatic diamine, the sum of the acid groups of acids (i) and (ii) substantially equaling the sum of the amine groups of amine (iii);

c) 0-30 parts of a compatibility agent,

a), b) and c) totaling 100 parts.

2. The composition of claim 1 wherein b) (i) is present in an amount of 38-45 molar parts and b) (ii) is present in an amount of 5-12 molar parts.

3. The composition of claim 1 wherein c) is present in an amount of 1-30 parts.

4. The composition of claim 1 wherein c) is present in an amount of less than 10 parts.

5. The composition of claim 1 further comprising 0 to 60 parts of at least one additive selected from the group consisting of processing aids, stabilizers, flame retardants, fillers, and reinforcing fibers.

6. The composition of claim 5 wherein said additive is selected from the group consisting of flame retardants, fillers, and reinforcing fibers.

7. The composition of claim 1 wherein said semicrystalline polyamide is a homopolyamide derived from at least one substance selected from the group consisting of ω

-aminocarboxylic acids having 6 to 9 carbon atoms, lactams having 6 to 9 carbon atoms, aliphatic diamines having 4 to 12 carbon atoms, and linear dicarboxylic acids having 6 to 12 carbon atoms.

8. The composition of claim 7 wherein said semicrystalline polyamide is selected from the group consisting of PA 6, PA 4.6, Pa 6.6, PA 6.9, PA6.10, and PA 6.12.

9. The composition of claim 1 wherein said semicrystalline polyamide is a copolyamide having a melting point, measured as the endothermic maximum of the DSC melting curve, of at least 170°

C.

10. The composition of claim 9 wherein said semicrystalline copolyamide is selected from the group consisting of PA 6, PA 4.6, PA 6.6, PA 6.8, PA 6.9, PA 6.10, Pa 6.12, PA 9.6, and PA 12.6.

11. The composition of claim 1 wherein said aromatic dicarboxylic acid is selected from the group consisting of mononucleic dicarboxylic acids, multi-nucleic dicarboxylic acids, and mixtures thereof.

12. The composition of claim 11 wherein said aromatic dicarboxylic acid is selected from the group consisting of isophthalic acid, terephtalic acid, 5-tert-butyl-isophthalic acid, naphthalene dicarboxylic acid, ##STR4## and mixtures thereof.

13. The composition of claim 1 wherein said dimerized fatty acid has 36 to 45 carbon atoms.

14. The composition of claim 13 wherein said dimerized fatty acid has a dimer fraction of at least 90%.

15. The composition of claim 13 wherein said dimer fraction is at least 97%.

16. The composition of claim 1 wherein b) (iii) is selected from the group consisting of a mononucleic diamine;

a polynucleic diamine of the Formula ##STR5## wherein R is an alkyl radical having 1 to 10 carbon atoms, R'"'"' is hydrogen or an alkyl radical having 1 to 6 carbon atoms; and

x is 0 to 4; and

mixtures thereof.

17. The composition of claim 16 wherein said polynucleic diamine is selected from the group consisting of ##STR6## and mixtures thereof.

18. The composition of claim 16 wherein said mononucleic diamine is selected from the group consisting of 1-amino-3-aminomethyl-3,5,5-trimethylcyclohexane, 1,3-diaminocyclohexane, 1,4-diamonocyclohexane, 1,3-diaminomethylcyclohexane, 1,4-diaminomethylcyclohexane, and mixtures thereof.

19. The composition of claim 1 wherein c) is at least one oligomeric or polymeric meltable compound which possesses groups reactive with terminal groups of said semicrystalline polyamide and said amorphous copolyamide.

20. The composition of claim 19 wherein said reactive groups are selected from the class consisting of carboxylic acid groups neutralized with a metal salt, acid anhydrides, carboxylic acids, epoxy, and amino.

21. The composition of claim 19 wherein c) is a copolyolefin grafted with maleic anhydride to a graft degree of 0.2 to 2.0 molar %.

22. The composition of claim 19 wherein c) is a oligomeric polyolefin or copolyolefin.

23. The composition of claim 22 wherein c) is selected from the group consisting of styrene-maleic acid anhydride oligomers having 4 to 10 acid anhydride groups.

24. The composition of claim 19 wherein c) is a core-shell polymer comprising a core which has a second-order transition temperature less than -30°

C., and a crosslinked shell of polar building blocks.

25. The composition of claim 24 wherein said shell contains groups reactive to polyamides.

26. The composition of claim 25 wherein said shell contains reactive groups taken from the class consisting of acrylic acid, methacrylic acid esters, maleic acid anhydride, carboxylic acid, and epoxy groups.

27. A process for the production of the composition of claim 1 comprising melting and intensively mixing a), b), and c) under the action of shearing forces to form a melt, then discharging said melt, and forming said melt into shapes.

28. The process of claim 27 wherein said melt is discharged as a strand that is cooled and granulated.

29. Shapes which are formed of the composition of claim 1.