Vapor detection apparatus and method using an acoustic interferometer

• US 5,289,715 A
• Filed: 11/12/1991
• Issued: 03/01/1994
• Est. Priority Date: 11/12/1991
• Status: Expired due to Term

• Current Assignee: Electronic Sensor Technology, Inc.
• Original Assignee: Amerasia Technology, Inc. (Electronic Sensor Technology, Inc.)
• Inventors: Watson, Gary W., Staples, Edward J.
• Primary Examiner(s): Williams, Hezron E.
• Assistant Examiner(s): ROSKOS, JOSEPH
• Application Number:
  US07/791,786
• Time in Patent Office: 840 Days
• Field of Search: 72/24.01, 72/24.06, 72/31.06, 72/23.40, 72/23.41, 72/23.42, 422/89
• US Class Current: 73/24.01
• CPC Class Codes: G01N 2030/008 Thermal desorption
• CPC Class Codes: G01N 2030/025 Gas chromatography
• CPC Class Codes: G01N 2030/303 using peltier elements
• CPC Class Codes: G01N 2291/0212 Binary gases
• CPC Class Codes: G01N 2291/02881 Temperature
• CPC Class Codes: G01N 2291/045 External reflections, e.g. on reflectors
• CPC Class Codes: G01N 29/024 by measuring propagation velocity or propagation time of acoustic waves
• CPC Class Codes: G01N 29/326 compensating for temperature variations
• CPC Class Codes: G01N 30/76 Acoustical detectors measurement of mechanical vibrations or ultrasonic, sonic or infrasonic waves G01H
• CPC Class Codes: G01N 30/78 using more than one detector

Abstract

A detector and method for identifying a chemical vapor and determining its concentration in the ambient atmosphere. The chemical detector apparatus preferably includes a means of collecting vapors in one atmosphere and transferring the vapors by injection into a chromatographic separation column. The exit of the separation column is confined by a nozzle which causes the vapors to be focused into a specific area of an acoustic wave interferometer wherein standing waves are created by constructive interference of waves reflected from a plurality of reflecting elements. Identification of vapor species is by a combination of timed adsorption rate peaks and temperature programmed desorption rates of the individual vapor species.

Claims

1. Apparatus for rapidly detecting and identifying a chemical vapors, comprising:

(a) a sensor having a surface exposed to the chemical vapors,

(b) a coated tubular section containing an inner coating of absorbant material whereby said tubular section separates individual vapor species according to their velocity in passing through said tubular section,

(c) a nozzle for directing a flow of chemical vapors onto said surface whereby said vapors are concentrated onto a specific region of said surface,

(c) monitoring means, coupled to the sensor, for monitoring the change in the physical parameter associated with said surface due to adsorption of the chemical substance, producing an electrical signal indicative of said change,

(d) analysis means, connected to the monitoring means, for determining a predicted time constant for adsorption of the chemical substance as a function of the electrical signal well before the chemical substance is completely adsorbed onto said surface,

(e) identification means for identifying the chemical substance from said group of chemical substances based upon its predicted time of arrival at said sensor and its rate of adsorption at a specific sensor temperature both of which are generally characteristic of individual chemical substances.

2. The apparatus of claim 1, wherein the sensor comprises an acoustic wave device having a plurality of spaced reflecting elements disposed so as to form standing acoustic waves by means of constructive interference between oppositely propagating acoustic waves and thereby increase the detection sensitivity of said surface to adsorbed vapors.

3. The apparatus of claim 2, wherein the sensor comprises an acoustic wave device of a characteristic frequency, said frequency decreasing as vapors are adsorbed on at least one surface.

4. The apparatus of claim 1, wherein a method of introducing the vapor sample into the coated tubular section is by means of transferring the sample from one atmosphere to another atmosphere including the steps of:

(a) adsorbing condensible vapors from one flowing gas by means of sorption/desorption tubular section,

(b) a transferring means for moving the adsorbed vapor from said sorption/desorption tubular section with a different flowing gas than the first said tubular section.

5. The apparatus of claim 4, wherein the tubular sections are electrically conductive capillaries.

6. The apparatus of claim 5, wherein a means of rapid vapor injection into a gas flow confined within said tubular sections by passage of an electrical current through said tubular sections.

7. Apparatus for rapidly detecting and identifying a chemical substance, comprising:

(a) a sensor having a surface exposed to the chemical substance,

(b) monitoring means, coupled to the sensor, for monitoring the change in the physical parameter associated with said surface due to desorption of the chemical substance, producing an electrical signal indicative of said change,

(c) a means of changing the temperature of said surface in a prescribed way with time whereby physical changes as a function of time and temperature are made clear,

(d) analysis means, connected to the monitoring means, for determining a predicted time constant for desorption of the chemical substance as a function of the electrical signal well before the chemical substance is completely desorbed from said surface,

(e) identification means for identifying the chemical substance from said group of chemical substances based upon its predicted time constant for desorption which is generally characteristic of the chemical substance and different than those of other chemical substances of the group.

8. The apparatus of claim 7, wherein the sensor comprises an acoustic wave device having a plurality of spaced reflecting elements disposed so as to form standing acoustic waves by means of constructive interference between oppositely propagating acoustic waves and thereby increase the sensitivity of said surface to desorbed vapors.