Surface-treated stent, catheter, cannula, and the like

• US 5,289,831 A
• Filed: 04/21/1992
• Issued: 03/01/1994
• Est. Priority Date: 03/09/1989
• Status: Expired due to Term

• Current Assignee: Cook Medical Incorporated (Cook Group Incorporated)
• Original Assignee: Vance Products Incorporated (Cook Group Incorporated)
• Inventors: Bosley, Rodney W.
• Primary Examiner(s): Kamm, William E.
• Assistant Examiner(s): MANUEL, GEORGE C
• Application Number:
  US07/871,644
• Time in Patent Office: 679 Days
• Field of Search: 128/660.07, 128/662.02, 128/662.05, 128/654, 128/754, 128/899, 356/243, 623/12, 604/21, 204/168, 204/169
• US Class Current: 128/899
• CPC Class Codes: A01K 85/00 Artificial bait for fishing
• CPC Class Codes: A61B 2090/3925 ultrasonic
• CPC Class Codes: A61B 8/0833 involving detecting or locating foreign bodies or organic structures
• CPC Class Codes: A61B 8/0841 for locating instruments
• CPC Class Codes: A61B 90/39 Markers, e.g. radio-opaque or breast lesions markers
• CPC Class Codes: A61L 31/14 Materials characterised by their function or physical properties , e.g. injectable or lubricating compositions, shape-memory materials, surface modified materials
• CPC Class Codes: A61L 31/18 Materials at least partially X-ray or laser opaque
• CPC Class Codes: A61M 25/0009 Making of catheters or other medical or surgical tubes

Abstract

Echogenic medical devices and methods of fabrication and of use are disclosed. The devices are adapted to be inserted into a patient. The device includes an elongated member including a material having an acoustic impedance different from that of the surrounding medium. The medium includes surrounding biological tissue or fluids surrounding the member when inserted into a passageway of the patient. The acoustic impedance of the elongated member is sufficiently different from the surrounding medium for enhancing an image produced in response to a sonic beam produced from imaging equipment. The elongated member also includes an interface layer of a high density metal of which the deposition on the base material of the member is ion beam assisted. The interface layer includes an outside surface having a plurality of particulate-type, discontinuous curved surfaces of partially spherical indentations formed therein or spheres extending therefrom. The difference between the acoustic impedances of the interface layer and the surrounding medium along with the discontinuous surfaces of the interface layer cooperate in response to a beam from sonic imaging equipment to significantly enhance the image of the medical device member.

Claims

1. A treated surface catheter, stent, or cannulae, comprising:

an elongated member including a first predetermined material having a first surface energy; and

an outer surface of said member including said first material and having a second surface energy different from said first surface energy and in a range of 20 to 30 dynes per centimeter.

2. The treated surface catheter, stent, or cannulae of claim 1 wherein said first material includes a base material from a group consisting of polyurethane, polyethylene, nylon, C-FLEX™

, polytetrafluoroethylene, polyvinyl chloride, polypropylene, polyester, and silicone.

3. The treated surface catheter, stent, or cannulae of claim 2 wherein aid elongated member is for insertion into a medium having a first acoustic impedance, said member including an interface layer on said first material, said interface layer having a particulate-type, discontinuous curved surface having a dimension less than a wavelength of a sonic beam from sonic imaging equipment, said interface layer including a second material different from said first material and having a second acoustic impedance different from said first acoustic impedance of said medium, said first and second acoustic impedance having at least a predetermined difference therebetween, whereby said difference between said first and second acoustic impedances and said curved surface cooperate in response to said sonic beam to produce an image of said member.

4. The treated surface catheter, stent, or cannulae of claim 3 wherein said first material exhibits a first coefficient of friction and wherein said outer surface exhibits a second coefficient of friction less than said first coefficient of friction.

5. The treated surface catheter, stent, or cannulae, of claim 4 wherein said interface layer has a surface energy in the range of 20 to 30 dynes per centimeter.

6. The treated surface catheter, stent, or cannulae of claim 1 wherein said first material includes polyurethane.

7. The treated surface catheter, stent, or cannulae of claim 6 wherein said outer surface of said first material has been ion beam bombarded with predetermined ions and, as a result, has said second surface energy.

8. The treated surface catheter, stent, or cannulae of claim 7 wherein said first material has a first coefficient of friction and said outer surface of said first material has a second coefficient of friction less than said first coefficient of friction.

9. A treated surface catheter, stent, or cannulae comprising:

an elongated member including a first predetermined material having a first surface energy; and

an outer surface including said first material and having a second surface energy different from said first surface energy, water when applied to said outer surface beading and forming a contact angle in a range of 75°

to 95°

.

10. The treated surface catheter, stent, or cannulae of claim 9 wherein said first material includes a base material from a group consisting of polyurethane, polyethylene, nylon, C-FLEX™

, polytetrafluoroethylene, polyvinyl chloride, polypropylene, polyester, and silicone.

11. The treated surface catheter, stent, or cannulae of claim 9 wherein said first material includes polyurethane.

12. The treated surface catheter, stent, or cannulae of claim 11 wherein said first material has been ion beam bombarded with predetermined ions and, as a result, has said second surface energy.

13. The treated surface catheter, stent, or cannulae of claim 9 wherein said first material exhibits a first coefficient of friction and said outer surface of said first material exhibits a second coefficient of friction less than said first coefficient of friction.

14. The treated surface catheter, stent, or cannulae of claim 9 wherein said first material includes a composite material echogenically imageable, said composite material including a solid matrix material and discrete sound reflective particles fixedly positioned throughout said matrix material ultrasonically different from tissue and more sonically reflective than said matrix material to enhance the echogenicity of said first material, said first material also including an outer layer ion beam deposited on said outer surface to further enhance the echogenicity of said elongated member.

15. An echogenic medical device insertable into a medium and imageable with sonic imaging equipment, comprising:

a member for insertion into a medium having a first acoustic impedance, said member including a base material from a group consisting of polyurethane, polyethylene, nylon, C-FLEX™

, polytetrafluoroethylene, polyvinyl chloride, polypropylene, polyester, and silicone and an interface layer deposited on said base material, said base material having an outer surface having a surface energy in a range of 20 to 30 dynes per centimeter, said interface layer deposited on said outer surface forming a deposition surface and having a discrete, particulate-type, discontinuous curved surface having a diameter less than a wavelength of a sonic beam from said imaging equipment, said member including a particulate in said deposition surface for forming said particulate-type, discontinuous surface in said deposition surface, said particulate including a plurality of particles from a group of tungsten and glass materials in a generally spherical shape, said interface layer including a metal from a group consisting of titanium, tungsten, barium, bismuth, silver, gold, platinum, and palladium different from said base material and having a second acoustic impedance different from said first acoustic impedance of said medium, said first and second acoustic impedances having at least a predetermined difference therebetween, said metal of said interface layer having been vacuum deposited on said deposition surface of said base material using ion beam assistance, whereby said difference between said first and second acoustic impedances and said curved surface responds to said sonic beam to produce an image of said member.

16. A medical device intended for use in contact with body fluid, said device comprising a member of a first predetermined material exhibiting a first coefficient of friction;

said member comprising an outer surface of said first material having been treated by ion beam bombardment with predetermined ions and exhibiting a second coefficient of friction less than said first coefficient of friction and wherein said outer surface of said first material has a surface energy within a range of 20 to 30 dynes per centimeter.

17. The medical device of claim 16 wherein said first material is from a group consisting of polyurethane, polyethylene, nylon, C-FLEX™

, polytetrafluoroethylene, polyvinyl chloride, polypropylene, polyester, and silicone.

18. The medical device of claim 17 wherein said first material has been treated by ion beam bombardment with argon ions.

19. The medical device of claim 16 wherein said outer surface has a surface energy and, when water is applied thereto, said outer surface forms a contact angle in a range of 75°

to 95°

.