Insulating shaped articles comprising inorganic fibrous matrices and xanthan gum/cationic starch binders

• US 5,290,350 A
• Filed: 11/20/1991
• Issued: 03/01/1994
• Est. Priority Date: 11/28/1990
• Status: Expired due to Fees

• Current Assignee: Rhone-Poulenc Chimie
• Original Assignee: Rhone-Poulenc Chimie
• Inventors: Brenner, Fabrice, Besnard, Marie-Madeleine, Knipper, Magali
• Primary Examiner(s): Michl, Paul R.
• Assistant Examiner(s): DEWITT, LAVONDA R
• Application Number:
  US07/794,902
• Time in Patent Office: 832 Days
• Field of Search: 106/209, 106/214, 252/62, 524/55, 524/401, 524/494, 524/12, 524/443, 524/447, 524/451
• US Class Current: 106/205.01
• CPC Class Codes: C04B 2235/3418 Silicon oxide, silicic acids, or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint glass constituents C04B2235/36
• CPC Class Codes: C04B 2235/349 Clays, e.g. bentonites, smectites such as montmorillonite, vermiculites or kaolines, e.g. illite, talc or sepiolite
• CPC Class Codes: C04B 2235/5228 Silica and alumina, including aluminosilicates, e.g. mullite
• CPC Class Codes: C04B 2235/5248 Carbon, e.g. graphite
• CPC Class Codes: C04B 2235/606 Drying
• CPC Class Codes: C04B 2235/608 Green bodies or pre-forms with well-defined density
• CPC Class Codes: C04B 2235/61 Mechanical properties, e.g. fracture toughness, hardness, Young's modulus or strength
• CPC Class Codes: C04B 2235/9607 Thermal properties, e.g. thermal expansion coefficient
• CPC Class Codes: C04B 2235/9615 Linear firing shrinkage
• CPC Class Codes: C04B 33/36 Reinforced clay-wares
• CPC Class Codes: C04B 35/18 rich in aluminium oxide
• CPC Class Codes: C04B 35/6263 characterised by their solids loadings, i.e. the percentage of solids
• CPC Class Codes: C04B 35/632 Organic additives
• CPC Class Codes: C04B 35/6365 Cellulose or derivatives thereof
• CPC Class Codes: C04B 35/80 Fibres, filaments, whiskers, platelets, or the like
• CPC Class Codes: C04B 35/82 Asbestos; Glass; Fused silica

Abstract

Physically/mechanically improved insulating shaped articles such as panels or plates, adapted to withstand very elevated temperatures, comprise an inorganic fiber matrix, e.g., a matrix of ceramic fibers, such inorganic fiber matrix containing at least one inorganic filler material, e.g., a mineral wool and/or kaolin, and a consolidating of a binder therefor which comprises admixture of a xanthan gum and a cationic starch.

Claims

1. An insulating shaped article comprising an inorganic fiber matrix, said inorganic fiber matrix containing at least one inorganic filler material and a consolidating amount of a binder therefor which comprises admixture of a xanthan gum and a cationic starch.

2. The insulating shaped article as defined by claim 1, said inorganic fiber matrix comprising boron fibers, carbon fibers, glass fibers, ceramic fibers, wool fibers, or mixture thereof.

3. The insulating shaped article as defined by claim 1, said at least one inorganic filler material comprising a silica, an alumina, an aluminum silicate, kaolin, bentonite, wollastonite, magnesia, calcium carbonate, talc or zirconium oxide.

4. The insulating shaped article as defined by claim 3, said at least one inorganic filler material comprising bentonite or a colloidal silica.

5. The insulating shaped article as defined by claim 3, said at least one inorganic filler material further comprising expanded perlite or exfoliated vermiculite.

6. The insulating shaped article as defined by claim 1, comprising from 30% to 90% by weight of said inorganic fiber matrix.

7. The insulating shaped article as defined by claim 6, comprising from 40% to 85% by weight of said inorganic fiber matrix.

8. The insulating shaped article as defined by claim 1, comprising from 5% to 60% by weight of said at least one inorganic filler material.

9. The insulating shaped article as defined by claim 8, comprising from 20% to 50% by weight of said at least one inorganic filler material.

10. The insulating shaped article as defined by claim 1, comprising from 2% to 10% by weight of said binder.

11. The insulating shaped article as defined by claim 1, said inorganic fiber matrix further containing at least one flocculant.

12. The insulating shaped article as defined by claim 11, said at least flocculant comprising a synthetic anionic polymer and/or a quaternary ammonium compound.

13. The insulating shaped article as defined by claim 1, wherein the ratio by weight of said xanthan gum to said cationic starch ranges from 1/2 to 1/10.

14. The insulating shaped article as defined by claim 13, said ratio ranging from 1/4 to 1/8.

15. The insulating shaped article as defined by claim 1, having a residual moisture content of less than 2%.

16. The insulating shaped article as defined by claim 15, having a residual moisture content of less than 1%.

17. The insulating shaped article as defined by claim 1, comprising an insulating plate, panel or molded article.

18. The insulating shaped article as defined by claim 1, heat-treated at a baking temperature.

19. The insulating shaped article as defined by claim 18, heat-treated at a baking temperature ranging from 300°

to 1,600°

C.

20. A process for the production of the insulating shaped article as defined by claim 1, comprising (a) intimately admixing, with water, a matrix-forming amount of inorganic fibers, said at least one inorganic filler material, said binder and, optionally, a flocculant, to formulate an aqueous slurry therefrom, (b) shaping the slurry thus formulated, and (c) drying said shaped slurry.

21. The process as defined by claim 20, comprising draining said slurry prior to the shaping thereof.

22. The process as defined by claim 20, said slurry having a solids content ranging from 1% to 10% by weight.

23. The process as defined by claim 22, said slurry having a solids content ranging from 4% to 6% by weight.