Method and apparatus for processing manure

• US 5,290,451 A
• Filed: 04/03/1992
• Issued: 03/01/1994
• Est. Priority Date: 04/17/1991
• Status: Expired due to Fees

• Current Assignee: Ecotechniek B. V.
• Original Assignee: Ecotechniek B. V.
• Inventors: Klapwijk, Abraham, Koster, Iman W.
• Primary Examiner(s): Upton, Christopher
• Application Number:
  US07/863,161
• Time in Patent Office: 697 Days
• Field of Search: 210/605, 210/610, 210/614, 210/621, 210/623, 210/624, 210/626, 210/630, 210/903, 210/906, 210/631, 210/195.1, 210/195.3, 210/202, 210/209, 210/220, 210/257.1 , 210/259, 210/607
• US Class Current: 210/605
• CPC Class Codes: C02F 1/385 by centrifuging suspensions centrifuges B04B
• CPC Class Codes: C02F 1/5236 using inorganic agents
• CPC Class Codes: C02F 2209/06 pH
• CPC Class Codes: C02F 2209/15 N03-N
• CPC Class Codes: C02F 2209/20 Total organic carbon [TOC]
• CPC Class Codes: C02F 2209/22 O2
• CPC Class Codes: C02F 2303/12 Prevention of foaming
• CPC Class Codes: C02F 3/006 Regulation methods for biological treatment
• CPC Class Codes: C02F 3/1215 Combinations of activated sludge treatment with precipitation, flocculation, coagulation and separation of phosphates
• CPC Class Codes: C02F 3/302 Nitrification and denitrification treatment C02F3/308 takes precedence
• CPC Class Codes: Y02E 50/30 Fuel from waste, e.g. synthetic alcohol or diesel
• CPC Class Codes: Y02W 10/10 Biological treatment of water, waste water, or sewage
• CPC Class Codes: Y02W 30/40 Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse
• CPC Class Codes: Y10S 210/903 Nitrogenous
• CPC Class Codes: Y10S 210/906 Phosphorus containing

Abstract

The invention relates to a method for processing manure, liquid manure and/or Kjeldahl-N containing waste water being subjected to a nitrification in an aerated reactor containing active sludge and to a denitrification in a high rate recirculation denitrification reactor (13) containing a very compact biomass capable of converting nitrate to nitrogen gas. The loading of the nitrification reactor (9) being controlled to obtain an optimal nitrification and denitrification, the effluent from the nitrification reactor (9) partially being passed to the denitrification reactor (13), adding a source of carbon to the effluent to be passed to the recirculation denitrification reactor (13) and passing another portion of the effluent stream from the nitrification reactor (9) to a separation step (19) to separate a sludge, the effluent from separation step (19) being passed to a discharge line denitrification reactor (37) under the addition of a carbon source if desired. The invention further relates to an apparatus constructed for this purpose.

Claims

1. Method for processing manure, liquid manure and/or Kjeldahl-N containing waste water being subjected to a nitrification in an aerated nitrification reactor (9) which contains active sludge rich in nitrifying bacteria being used in the nitirification reactor (9) if necessary and to a denitrification in a high rate recirculation denitrification reactor (13) which contains a very compact biomass which is capable of converting nitrate to nitrogen gas and to which an organic substrate is supplied obtained from the denitrification step in the nitrification reactor (9), characterized in that the loading of the nitrification reactor (9) is controlled to obtain an optimal nitrification and denitrification on the basis of one or more of the following data;

the incoming nitrogen load;

the information from a WAZU respiration meter (not shown);

the oxygen concentration in the nitrification reactor (9);

the pH value in the nitrification reactor (9), the criterion for which is that the pH value is in the range limited by 6 and 8.5;

the amount of air required

the residence time

the temperature in both the nitrification reactor (9) and the recirculation denitrification reactor (13) is kept below 40°

C.;

the concentration of oxidized nitrogen in the influent for the recirculation denitrification reactor (13), the criterion for which is that the concentration is between 0 and 4 g N/1;

the concentration of oxidized nitrogen in the nitrification reactor (9), the criterion for which in the sludge/liquid mixture in the nitrification reactor is that the concentration is between 0 and 4 g N/1;

the concentration of the carbon source in the effluent from the recirculation denitrification reactor (13);

the gas production in the recirculation denitrification reactor (13)

the effluent from the nitrification reactor (9) partially being passed to the recirculation dentrification reactor (13), adding a source of carbon to the effluent to be passed to the recirculation denitrification reactor (13) and passing another portion of the effluent stream from the nitrification reactor (9) to a separation step (19) to separate a sludge, mixture in the nitrification reactor is that the concentration is between 0 and 4 g N/1;

the concentration of the carbon source in the effluent from the recirculation denitrification reactor (13);

the gas production in the recirculation denitrification reactor (13)

the effluent from the nitrification reactor (9) partially being passed to the recirculation denitrification reactor (13), adding a source of carbon to the effluent to be passed to the recirculation denitrification reactor (13) and passing another portion of the effluent stream from the nitrification reactor (9) to a separation step (19) to separate a sludge, the effluent from separation step (19) being passed to a discharge line denitrification reactor (37) under the addition of a carbon source if desired, the discharge line denitrification reactor (37) being provided with means for an effluent discharge (38) and a nitrogen discharge (17).

2. The method according to claim 1, characterized in that the effluent (12) from the nitrification reactor (9) is passed through a buffer tank, provided a) with a means to remove sludge and b) a discharge leading to stream (39) to separation step (19) with and a discharge leading to stream (36) leading to discharge line denitrification reactor 37 and buffer tank and c) further being provided with a discharge (19) leading to stream (12) leading to recirculation denitrification reactor (13).

3. The method according to claim 1, characterized in that liquid from the recirculation denitrification reactor (13) is recycled to the nitrification reactor (9).

4. The method according to claim 3, characterized in that the effluent stream 12 from the nitrification reactor (9) passed to the separation step (19) is subjected to a physical chemical treatment.

5. The method according to claim 4, wherein the flocculating substance comprises iron chloride.

6. The method according to claim 5, wherein the recycled liquid of the effluent from the recirculation denitrification reactor (13) is passed to the nitrification reactor (9) via a spray installation.

7. The method according to claim 6, characterized in that the recycled liquid is passed to the nitrification reactor (9) via a spray installation.

8. The method according to claim 7, characterized in that part of the effluent (12) is also recycled to the influent of the recirculation denitrification reactor (13).

9. The method according to claim 1, characterized in that the nitrification reactor (9) used is a batch reactor or a fed batch reactor (with a continuous or batchwise addition of influent).

10. The method according to claim 1, characterized in that chemicals for phosphate precipitation are added to at least one of the denitrification reactors (13 and/or 37).

11. The method according to claim 9, wherein an organic substance or a mixture of organic substances is added to at least one of the denitrification reactors, wherein a ratio between chemical oxygen consumption and total organic carbon (COC/TOC ratio) of greater than 3.75 is maintained.

12. The method according to claim 10, characterized in that methanol is added as an organic substrate to at least one of the denitrification reactors (13) and/or (37).

13. The method according to claim 11, characterized in that glycol is added as organic substrate to at least one of the denitrification reactors (13) and/or (37).

14. The method according to claim 13, with which an organic substance or a mixture of organic substance is added to at least one of the denitrification reactors (13) and/or (37), characterized in that a ratio between chemical oxygen consumption and total organic carbon (COC/TOC ratio) of less than or equal to 3.75 is maintained.

15. The method according to claim 14, characterized in that the influent to be treated is fully or partially supplied to the recirculation denitrification reactor (13).

16. The method according to claim 1, characterized in that one or more acid-neutralizing chemicals are added to the nitrification reactor (9).

17. The method according to claim 1, wherein the temperature in both the nitrification reactor (9) and in the denitrification reactors (13 and 37) is maintained at 20°

-35°

Celsius.

18. The method according to claim 17, wherein the concentration of oxidized nitrogen in the influent for the denitrification reactors is maintained at 1.0-1.4 g N/1.

19. The method according to claim 1, characterized in that the temperature in both the nitrification reactor (9) and in the denitrification reactors (13 and 37) is maintained at 20°

-35°

Celsius.

20. The method according to claim 1, wherein the loading of the nitrification reactor (9) is controlled to obtain the desired nitrification and denitrification on the basis of the incoming nitrogen load of said waste water.

21. The method according to claim 1, wherein the loading of the nitrification reactor (9) is controlled to obtain the desired nitrification and denitrification on the basis of the information from a WAZU respiration meter.

30. The method according to claim 1, wherein the loading of the nitrification reactor (9) is controlled to obtain the desired nitrification and denitrification on the basis of the gas production in the recirculation denitrification reactor (13).

22. An apparatus comprising:

a nitrification reactor (9) which is provided with an aeration (10), feed of liquid (7) to be treated, with a feed of acid-neutralizing chemicals (8), active sludge rich in nitrifying bacteria, a sludge discharge (11), an effluent discharge (12);

a line (12) through which a part of the effluent (15) from the nitrification reactor (9) can be fed to the recirculation denitrification reactor (13);

a recirculation denitrification reactor (13) which is provided with a feed of effluent (12) from the nitrification reactor (9), a feed of a carbon source (14), a discharge (17), effluent discharge (16, 33 or

     34) to reactor (9);

characterized in that the installation (shown schematically in FIG.

     11) is constructed such that part of the effluent from reactor (9) is passed to recirculation denitrification reactor (13) and part is passed to separation unit (19) provided with a sludge discharge (29) and an effluent discharge (36) connected with a discharge line denitrification reactor (37) with an effluent discharge (38) and a nitrogen outlet (17).

23. Apparatus according to claim 22, characterized in that it is provided with a feed of chemicals for phosphate precipitation (20).

24. Apparatus according to claim 22, characterized in that this is provided with buffer tanks (23).

25. Apparatus according to claim 24, characterized in that it is provided with a means for chemical phosphate precipitation (not shown) arranged between separation step (19) and the discharge line denitrification reactor (37).

26. Apparatus according to claim 25, characterized in that it is provided with means to catch sludge after a buffer tank and/or a denitrification reactor.

27. Apparatus according to claim 26, characterized in that a buffer tank is provided with means to remove sludge.

28. Apparatus according to claim 27, characterized in that discharge (38) of the discharge line denitrification reactor is provided with means to remove sludge.

29. Apparatus according to claim 28, characterized in that it is provided with means to recirculate sludge from a buffer tank to a circulation denitrification reactor (13) and/or from a buffer tank to the nitrification reactor (9) to said discharge line denitrification reactor (37).

31. An apparatus comprising:

a nitrification reactor (9) having an aerator (10), feed of liquid (7) to be treated, a feed of acid-neutralizing chemicals (8), active sludge rich in nitrifying bacteria, a sludge discharge (11), and an effluent discharge (12);

a recirculation denitrification reactor (13) having an inlet, a feed of a carbon source (14), a nitrogen discharge means (17), and a recirculating effluent discharge (16, 33 or 34 to the nitrification reactor (9);

a discharge line denitrification reactor (37) having an inlet, an effluent discharge (38) and a nitrogen outlet (17);

means for feeding a part of the effluent (12) from the nitrification reactor (9) to the inlet of the recirculation denitrification reactor (13) and the remaining part to a separation unit (19) having a sludge discharge (29) and an effluent discharge (36) connected with the inlet of the discharge line denitrification reactor (37).

32. The apparatus according to claim 31, wherein said apparatus further includes a feed of chemicals for phosphate precipitation (20) to at least one denitrification reactor.

33. The apparatus according to claim 31, wherein said apparatus further includes at least one buffer tank (23) between and nitrification tank and said separation unit.

34. The apparatus according to claim 33, wherein said apparatus further includes a means for chemical phosphate precipitation arranged between the separation unit (19) and the discharge line denitrification reactor (37).

35. The apparatus according to claim 34, wherein said apparatus further includes means to catch sludge after the buffer tank and/or one of the denitrification reactors.

36. The apparatus according to claim 34, wherein the buffer tank includes means to remove sludge.

37. The apparatus according to claim 36, wherein the discharge (38) of the discharge line denitrification reactor includes means to remove sludge.

38. The apparatus according to claim 37, wherein said apparatus further includes means to recirculate sludge from the buffer tank to the recirculation denitrification reactor (13) and/or from the buffer tank to the nitrification reactor (9) and/or from the discharge line denitrification reactor (37) to the discharge line denitrification reactor (37).