High temperature stabilized mullite-aluminum titanate

• US 5,290,739 A
• Filed: 09/22/1992
• Issued: 03/01/1994
• Est. Priority Date: 09/22/1992
• Status: Expired due to Term

• Current Assignee: Corning Incorporated
• Original Assignee: Corning Incorporated
• Inventors: Hickman, David L.
• Primary Examiner(s): Bell, Mark L.
• Assistant Examiner(s): WRIGHT, ALAN
• Application Number:
  US07/949,454
• Time in Patent Office: 525 Days
• Field of Search: 501/127, 501/128, 501/134, 501/153
• US Class Current: 501/128
• CPC Class Codes: C04B 35/185 Mullite 3Al2O3-2SiO2
• CPC Class Codes: C04B 35/478 based on aluminium titanates

Abstract

This invention relates to a sintered mullite-aluminum titanate article formed by doping the mullite with 1-5% titania and/or titania precursors, and 1-5% hematite and/or hematite precursors, pre-calcining the mullite and mixing with calcined aluminum titanate to form a mullite-aluminum titanate composition which may be formed into a high temperature stabilized ceramic article such as a honeycomb.

Claims

1. A method of producing a high temperature stabilized mullite-aluminum-titanate article, the article consisting essentially, expressed in weight percent based on the oxides, of 1.5-20%, SiO₂, 5-25% Fe₂ O₃, 35-75% Al₂ O₃, and 10-40% TiO₂, said method comprising the steps of:

forming doped mullite by a process selected from;

(1) doping mullite with dopant selected from titania, titania precursors, hematite, and hematite precursors to form doped mullite; and

(2) pre-reacting mullite precursors with dopant selected from titania, titania precursors, hematite, and hematite precursors to form doped mullite precursors;

calcining and milling the doped mullite;

calcining and milling aluminum-titanate;

mixing the mullite and the aluminum-titanate with a binder to form a ceramic batch;

shaping the ceramic batch to form a green ceramic article; and

firing the green ceramic article at a temperature and for a duration of time sufficient to form the sintered ceramic article.

2. The method of claim 1, wherein the sintered ceramic article comprises iron aluminum titanate solid solution and mullite as the two predominant crystal phases.

3. The method of claim 1, wherein prior to mixing the doped and calcined mullite and the calcined aluminum titanate with a binder to form the ceramic batch, mullite and the aluminum titanate are milled to a mean particle size of 20 microns.

4. The method of claim 1, wherein 15-25 mole percent of aluminum in the aluminum titanate has been replaced with iron.

5. The method of claim 4, wherein 20 mole percent of the aluminum in the aluminum titanate has been replaced with iron.

6. The method of claim 1, wherein the ceramic article is fired at a temperature in the range of 1400°

to 1500°

C., for a duration in the range of 5 to 25 hours.

7. A method of producing a sintered ceramic body consisting essentially of the composition expressed in terms of weight percent based on the oxides, of 1.5-20% SiO₂, >

5-25% Fe₂ O₃, 35-75% Al₂ O₃. 10-40% TiO₂, and 0.1-5% RE₂ O₃, the steps comprising;

(a) calcining a mixture of Fe₂ O₃, TiO₂ and Al₂ O₃ to a single phase solid solution;

(b) grinding the solid solution to a powder;

(c) mixing mullite with the powder to from a homogeneous body;

(d) combining rare earth metal oxides either to the mixture prior to the calcining step or to the powder in the mixing step; and

(e) firing the body to form the sintered ceramic body;

the improvement being that prior to mixing the mullite with the powder to form a homogeneous body, the mullite is first (1) doped with dopant selected from titania, titania precursors, hematite, and hematite precursors to form doped mullite precursors, and (2) calcined.

8. A method of producing a sintered ceramic body consisting essentially of the composition expressed in terms of weight percent based on the oxides, of 1.5-20% SiO₂, 5-25% Fe₂ O₃, 35-75% Al₂ O₃, and 10-40% TiO₂, the steps comprising:

(a) calcining a mixture of TiO₂ and Al₂ O₃ to a single phase solid solution;

(b) grinding the solid solution to a powder;

(c) doping mullite with hematite;

(d) calcining the doped mullite;

(e) mixing the doped mullite with the powder to form a homogeneous body; and

(f) firing the body to form the sintered ceramic body.

9. The method of claim 8, wherein the mullite comprises mullite precursors.