Engineering resin-propylene polymer graft composition

• US 5,290,856 A
• Filed: 04/16/1992
• Issued: 03/01/1994
• Est. Priority Date: 04/16/1992
• Status: Expired due to Term

• Current Assignee: Himont, Inc (Government of France)
• Original Assignee: Himont, Inc (Government of France)
• Inventors: Okamoto, Kelvin T., Guyaniyogi, Suhas C., Eastenson, Kyle D.
• Primary Examiner(s): Seidleck, James J.
• Assistant Examiner(s): WARZEL, MARK L
• Application Number:
  US07/869,982
• Time in Patent Office: 684 Days
• Field of Search: 525/68, 525/63, 525/66, 525/70, 525/80, 525/92, 525/71, 525/74, 525/67
• US Class Current: 525/64
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 2666/04 Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
• CPC Class Codes: C08L 2666/14 Macromolecular compounds according to C08L59/00 - C08L87/00; Derivatives thereof
• CPC Class Codes: C08L 2666/24 Graft or block copolymers according to groups C08L51/00, C08L53/00 or C08L55/02; Derivatives thereof
• CPC Class Codes: C08L 51/00 Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds for ABS polymers C08L55/02; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 51/06 grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
• CPC Class Codes: C08L 67/02 Polyesters derived from dicarboxylic acids and dihydroxy compounds C08L67/06 takes precedence
• CPC Class Codes: C08L 71/123 not modified by chemical after-treatment
• CPC Class Codes: C08L 77/00 Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain of polyhydrazides C08L79/06; of polyamideimides or polyamide acids C08L79/08; Compositions of derivatives of such polymers

Abstract

Disclosed are resin compositions comprising (a) a polyphenylene ether resin or a polyamide resin or a polyester resin; (b) a glycidyl moiety-styrenic grafted propylene polymer material in combination with a styrenic polymer copolymerized with a glycidyl moiety; optionally (c) (1) one or more monoalkenyl aromatic hydrocarbon-conjugated diene block copolymers, hydrogenated products thereof or mixtures thereof, with or without (2) olefin copolymer rubber; and optionally (d) a propylene polymer material. The compositions exhibit increased resistance to delamination, indicating improved compatibility between the engineering resins and propylene polymer material.

Claims

1. A composition comprising, by weight (a) from about 10 to about 90% of a resin material selected from the group consisting of (i) a polyphenylene ether resin, (ii) a polyamide resin and (iii) a polyester resin;

(b) from about 10 to about 90% of a propylene polymer material grafted with styrenic polymer and a glycidyl moiety and further comprising from about 35 to about 95 weight percent of the total grafting monomer of styrenic polymer copolymerized with said glycidyl moiety as a discrete component wherein the total concentration of styrenic and glycidyl moiety monomers added during the grafting of said propylene polymer material is from about 50 to about 200 parts by weight per hundred of said propylene polymer material and said glycidyl moiety monomer is present during said grafting at a concentration of from about 0.1 to about 20.0 weight percent of said total monomer concentration;

optionally (c) from about 1 to about 25% of at least one rubber polymer component comprising (1) from about 0 to 100% of at least one of (i) monoalkenyl aromatic hydrocarbon-conjugated diene block copolymers, (ii) hydrogenated products of (i), or (iii) mixtures of (i) and (ii); and

(2) from about 100 to 0% of an olefin copolymer rubber;

wherein the total amount of (a)+(b) is 100%.

2. The composition of claim 1 wherein (a) is present in an amount from about 20 to about 85%.

3. The composition of claim 1 wherein component (a) is a polyphenylene ether resin present in an amount of from about 20 to about 85%.

4. The composition of claim 1, wherein component (a) is a polyamide resin present in an amount of from about 20 to about 85%.

5. The composition of claim 1, wherein component (a) is a polyester resin present in an amount of from about 20 to about 5%.

6. The composition of claim 1 wherein said glycidyl moiety is selected from the group consisting of glycidyl acrylate, glycidyl methacrylate, glycidyl itaconate, allyl glycidyl ether, 2-methallyl glycidyl ether, and p-styryl glycidyl ether.

7. The composition of claim 1 wherein said glycidyl moiety and styrenic polymer grafted propylene polymer material of said component (b) is selected from the group consisting of a graft copolymer of glycidyl methacrylate and styrene on polypropylene backbone, a graft copolymer of glycidyl methacrylate and styrene on ethylene-propylene random copolymer backbone, a graft copolymer of glycidyl methacrylate and styrene on polypropylene backbone impact modified with ethylene-propylene rubber, a graft copolymer of glycidyl methacrylate and styrene/alpha-methylstyrene on polypropylene backbone impact-modified with ethylene-propylene rubber, a graft copolymer of glycidyl methacrylate and styrene/alpha-methylstyrene on ethylene-propylene random copolymer backbone and a graft copolymer of glycidyl methacrylate and styrene/alpha-methylstyrene on polypropylene backbone.

8. The composition of claim 7 wherein the total glycidyl methacrylate and styrenic monomer during grafting is from about 50 to about 200 parts per hundred and said glycidyl methacrylate is present at a concentration of from about 0.1 to about 20 weight percent of said total monomer content.

9. The composition of claim 1 wherein up to about 90% of the amount of said propylene polymer material grafted with said glycidyl moiety and styrenic polymer of component (b) is replaced with a propylene polymer material grafted with styrenic polymer having a styrenic monomer content of from about 5 to about 70%.