Off-axis cavity absorption cell

• US 5,291,265 A
• Filed: 06/03/1992
• Issued: 03/01/1994
• Est. Priority Date: 06/03/1992
• Status: Expired due to Term

• Current Assignee: Aerodyne Corporation
• Original Assignee: Aerodyne Corporation
• Inventors: Kebabian, Paul L.
• Primary Examiner(s): McGraw, Vincent P.
• Application Number:
  US07/893,120
• Time in Patent Office: 636 Days
• Field of Search: 356/246, 356/440, 356/437, 250/343, 372/107
• US Class Current: 356/246
• CPC Class Codes: G01N 21/031 Multipass arrangements
• CPC Class Codes: G01N 21/05 Flow-through cuvettes G01N21/09 takes precedence; handling fluid samples G01N1/10
• CPC Class Codes: G01N 21/3504 for analysing gases, e.g. multi-gas analysis

Abstract

An off-axis cavity absorption cell (10) includes astigmatic mirrors (22, 28). The cell design is based on a prototype design that yields a closed beam path having a desired geometry, but the mirrors are fabricated so that the ratios of their radii of curvature are actually larger than those calculated for the prototype. To achieve the desired closed beam path, the mirror spacing is adjusted from that of the prototype design, and the planes of their axes of greatest curvature are oriented out of the alignment that characterizes the prototype design. If the mirrors'"'"' manufacturing process yields errors in the curvature-radius ratios within certain prescribed limits, a cell of this design can be adjusted to achieve the closed beam path by simply changing the mirror separation and the "twist angle" between their respective planes of maximum curvature radius.

Claims

1. An absorption cell forming a coupling aperture and comprising opposed astigmatic mirrors that define an actual closed optical path from the coupling aperture and back to it, consisting of an odd number N of cycles through the absorption cell, in which the locations of the spots at which the actual path hits one of the mirrors, as a function of those spots'"'"' order of occurrence, exhibits motion consisting essentially of only two frequency components k_x /N and k_y /N associated with high-frequency and low-frequency axes, respectively, along which the contribution of the other frequency component is essentially zero, where k_x and k_y are different integers and their common factors, other than unity, with N are distinct, each of the mirrors having principal radii r_x '"'"' and r_y '"'"' related to the principal radii r_x and r_y >

r_x of a prototype cell by the relationships r_x '"'"'<

r_x /(1+Δ

e) and r_y '"'"'>

r_y /(1-Δ

e), where Δ

e=2×

10^-4, the axes of the prototype cell'"'"'s mirrors are oriented with their principal axes aligned and define a prototype closed optical path consisting of the same odd number N of cycles through the prototype cell, and the locations at which the prototype path strikes a mirror make k_x cycles in the direction of one principal axis and k_y cycles in the direction of the other principal axis.

2. An absorption cell as defined in claim 1 wherein the actual path consists of 182 traverses between the mirrors, during which the position at which the light hits a mirror executes forty cycles along the high-frequency axis and thirty-eight cycles along the low-frequency axis.

3. An absorption cell as defined in claim 1 wherein the actual path consists of 370 traverses between the mirrors, during which the position at which the light hits a mirror executes eighty-six cycles along the high-frequency axis and eighty-one cycles along the low-frequency axis.

4. An absorption as defined in claim 1 wherein 0.35<

k_x /N<

0.65 and 0.35<

k_y /N<

0.65.

5. An absorption cell forming a coupling aperture and comprising opposed astigmatic mirrors forming a twist angle of more than 1.0 degree with respect to each other and defining, for light entering the coupling aperture at a predetermined angle, a closed multiple-reflection path from the inlet aperture and back to it.

6. An absorption cell as defined in claim 5 wherein each mirror'"'"'s ratio of maximum to minimum radius of curvature exceeds 1.001.

7. An absorption cell as defined in claim 5 wherein the twist angle between the mirrors exceeds 10 degrees.

8. A method of constructing an absorption cell comprising the steps of:

A) constructing a cell that forms a coupling aperture and includes opposed astigmatic mirrors spaced apart along a central axis therethrough; and

B) varying the mirrors'"'"' twist angle and their separation along the central axis until, at a twist angle that exceeds 1.0 degree, the mirrors define, for light entering the inlet aperture at a predetermined angle, a closed multiple-reflection path from the coupling inlet aperture and back.

9. A method as defined in claim 8 wherein the step of varying the mirrors'"'"' twist angle comprises varying it to a value, at which the mirrors define the multiple-reflection path, that exceeds 10 degrees.

10. A method as defined in claim 9 wherein each mirror'"'"'s ratio of maximum to minimum radius of curvature exceeds 1.001.

11. A method as defined in claim 8 wherein each mirror'"'"'s ratio of maximum to minimum radius of curvature exceeds 1.001.