Thermal reclamation method for the recovery of metals from air bag inflators

• US 5,294,244 A
• Filed: 07/27/1993
• Issued: 03/15/1994
• Est. Priority Date: 07/27/1993
• Status: Expired due to Term

• Current Assignee: TRW Vehicle Safety Systems Incorporated (Zeppelin - Stiftung der Stadt Friedrichshafen)
• Original Assignee: TRW Vehicle Safety Systems Incorporated (Zeppelin - Stiftung der Stadt Friedrichshafen)
• Inventors: Coburn, James L., Thames, Bernie M., Allerton, Hugh G. III, Bal, Dennis S.
• Primary Examiner(s): Andrews, Melvyn J.
• Application Number:
  US08/097,661
• Time in Patent Office: 231 Days
• Field of Search: 75/401, 75/405, 75/581, 75/687
• US Class Current: 75/401
• CPC Class Codes: C21B 3/04 Recovery of by-products, e.g. slag
• CPC Class Codes: C22B 21/0092 Remelting scrap, skimmings or any secondary source aluminium
• CPC Class Codes: C22B 7/004 separating two or more metals by melting out (liquation), i.e. heating above the temperature of the lower melting metal component(s); by fractional crystallisation (controlled freezing)
• CPC Class Codes: Y02P 10/20 Recycling
• CPC Class Codes: Y02W 30/50 Reuse, recycling or recovery technologies

Abstract

A method of recovering an aluminum alloy and a stainless steel alloy from an air bag inflator 10 that has aluminum alloy parts, including an aluminum alloy housing 12 and non-aluminum alloy parts, including a non-aluminum gas filter 18. The non-aluminum parts have a higher melting temperature than the aluminum alloy parts of the air bag inflator 10. The method comprises heating the air bag inflator 10 in the range of the melting temperature of aluminum and then recovering the aluminum alloy which is not contaminated with the material of the higher melting temperature parts. After the aluminum alloy has melted from the air bag inflator 10, the non-aluminum parts are heated to a higher temperature to melt any stainless steel alloy from the non-aluminum parts. The stainless steel alloy is recovered as a high purity stainless steel alloy end product.

Claims

1. A method of recovering an aluminum alloy from an air bag inflator having aluminum alloy parts, including an aluminum alloy housing, and having other non-aluminum parts, including a non-aluminum gas filter in the housing, said other non-aluminum parts being made of a material having a higher melting temperature than aluminum, said method comprising the steps of:

placing the air bag inflator in a furnace;

heating the air bag inflator to the melting temperature of aluminum to melt the aluminum alloy parts;

removing the non-aluminum parts from the furnace before the higher melting temperature non-aluminum parts reach their melting temperature; and

collecting the molten aluminum alloy.

2. The method of claim 1 wherein the step of heating the air bag inflator to the melting temperature of aluminum to melt the aluminum alloy parts comprises heating the air bag inflator to a temperature in the range of about 700°

C. to about 1,000°

C.

3. The method of claim 1 wherein the air bag inflator placed in the furnace comprises (a) aluminum alloy parts including a housing, an end cap for the housing and a layer of foil and (b) non-aluminum parts including a non-aluminum gas filter, and wherein said step of heating to melt the aluminum alloy parts includes melting the housing, end cap and layer of foil.

4. The method of claim 1 further comprising the step of recovering the collected molten aluminum alloy as ingots which are about the same purity as the original aluminum parts.

5. The method of claim 1 wherein the step of heating to melt the aluminum alloy parts includes placing the air bag inflator in a natural gas furnace.

6. The method of claim 1 wherein the non-aluminum parts of the air bag inflator include stainless steel alloy parts and wherein the step of heating the air bag inflator to the melting temperature of aluminum comprises heating the air bag inflator to a temperature in the range of about 700°

C. to about 1000°

C. so that the aluminum alloy melts from the inflator and the stainless steel parts of the inflator collapse and form a stainless steel alloy case.

7. The method of claim 6 wherein the stainless steel parts of the air bag inflator comprise stainless steel screen and stainless steel wool and the stainless steel alloy case comprises the stainless steel screen and the stainless steel wool and further including the step of enclosing a residue of a combustible gas generating material that includes sodium azide and a metal oxide in the stainless steel alloy case.

8. The method of claim 7 further comprising the step of recovering the stainless steel alloy from the stainless steel alloy case by:

adding a flux to the stainless steel alloy case;

placing the stainless steel alloy case mixed with the added flux into another furnace;

heating the stainless steel alloy case and the added flux to a temperature in the range from about 1450°

C. to about 1650°

C. in the other furnace to melt the stainless steel alloy case and form a molten slag;

separating the molten stainless steel alloy from the molten slag; and

recovering the molten stainless steel alloy.

9. The method of claim 8 wherein the step of adding a flux to the stainless steel alloy case comprises adding a flux selected from the group consisting of limestone, silica, rock, gravel and combinations thereof.

10. The method of claim 8 further comprising the step of recovering the molten slag which is non-hazardous and which comprises calcium oxide, magnesium oxide, silicon oxide, aluminum oxide, sodium oxide and combinations thereof.

11. The method of claim 8 wherein the step of placing the stainless steel alloy case into another furnace includes placing the stainless steel alloy case in a cupola furnace.

12. A method of recovering aluminum alloy and stainless steel alloy metals from an air bag inflator having aluminum alloy parts, including an aluminum alloy housing, and having other non-aluminum alloy parts, including a non-aluminum gas filter in the housing, said non-aluminum parts being made of materials, including a stainless steel alloy, having a higher melting temperature than aluminum, said method comprising the steps of:

heating the air bag inflator to a temperature in the range of about 700°

C. to about 1000°

C. to melt the aluminum alloy parts and collapse the non-aluminum parts of the inflator to form a stainless steel alloy case;

separating the molten aluminum alloy from the stainless steel alloy case;

collecting the molten aluminum alloy;

adding a flux to the separated stainless steel alloy case, said flux being selected from the group consisting of limestone, silica, rock, gravel and combinations thereof;

heating the stainless steel alloy case and the added flux to a temperature in the range from about 1,450°

C. to about 1,650°

C. to melt the stainless steel alloy and form a molten slag;

separating the molten stainless steel alloy from the molten slag; and

recovering the molten stainless steel alloy.