Organic electroluminescent multicolor image display device

• US 5,294,870 A
• Filed: 12/30/1991
• Issued: 03/15/1994
• Est. Priority Date: 12/30/1991
• Status: Expired due to Term

• Current Assignee: Global OLED Technology LLC (LG Display Co., Ltd.)
• Original Assignee: Eastman Kodak Company
• Inventors: Chang, Jack C., Williams, David J., Tang, Ching W.
• Primary Examiner(s): Yusko, Donald J.
• Assistant Examiner(s): Patel, Ashok
• Application Number:
  US07/814,553
• Time in Patent Office: 806 Days
• Field of Search: 313/486, 313/487, 313/489, 313/500, 313/504, 313/505, 313/506, 313/496, 428/690, 428/917, 340/781, 340/760, 315/169.3
• US Class Current: 313/504
• CPC Class Codes: C09K 11/06 containing organic luminescent materials
• CPC Class Codes: H05B 33/14 characterised by the chemical or physical composition or the arrangement of the electroluminescent material , or by the simultaneous addition of the electroluminescent material in or onto the light source
• CPC Class Codes: H05B 33/26 characterised by the composition or arrangement of the conductive material used as an electrode
• CPC Class Codes: H10K 50/805 Electrodes
• CPC Class Codes: H10K 59/17 Passive-matrix OLED displays
• CPC Class Codes: H10K 59/173 comprising banks or shadow masks
• CPC Class Codes: H10K 59/38 comprising colour filters or colour changing media [CCM]
• CPC Class Codes: H10K 59/805 Electrodes
• CPC Class Codes: Y10S 428/917 Electroluminescent

Abstract

An organic electroluminescent multicolor image display device is disclosed containing an image display array made up of a plurality of light emitting pixels arranged in intersecting files (rows and columns). Each pixel contains a light transmissive first electrode, an electroluminescent medium overlying the first electrode, and an overlying second electrode. The electrodes connect the pixels in an X-Y addressing pattern. The organic electroluminescent medium emits in the blue region of the spectrum. Each pixel is divided into at least two sub-pixels. The electrodes of one set of parallel files is divided into at least two laterally spaced elements each of which joins and forms a part of one sub-pixel of each pixel in the same file. A fluorescent medium capable of absorbing light emitted by the electroluminescent medium and emitting at a longer wavelength is positioned to receive emitted light from the first electrode means. The fluorescent medium is confined to only one of the sub-pixels of each pixel.

Claims

1. An image display device comprised of an array consisting of

a plurality of light emitting pixels arranged in two intersecting sets of parallel files, the pixels in a first set of parallel files forming columns and the pixels in a second set of parallel files forming rows on an electrically insulative support,

the pixels in each file of said first set of parallel files containing and being joined by a common light transmissive first electrode means overlying said support,

the first electrode means in adjacent files of said first set being laterally spaced on said support,

an organic electroluminescent medium overlying the first electrode means and said support,

the pixels in each file of said second set of parallel files containing and being joined by a common second electrode means overlying said organic electroluminescent medium, and

the second electrode means in adjacent files of said second set being laterally spaced on said organic electroluminescent medium,

characterized in that the device is capable of producing multicolor image display,

said organic electroluminescent medium emits in the blue region of the spectrum and has a peak emission at a wavelength of less than 480 nm,

each pixel in said first set of parallel files of pixels is divided into at least two subpixels,

in said first set one of said first and second electrode means that is contained in and joins the pixels in each file of said first set is divided into at least two laterally spaced electrode elements, each of the electrode elements joining and forming a part of one sub-pixel of each of the pixels in a file, and

a fluorescent medium located on the upper surface of said support and underlying the first electrode means, and capable of absorbing light emitted by said organic electroluminescent medium and emitting at a longer wavelength is positioned to receive emitted light from said organic electroluminescent medium transmitted through the first electrode means, said fluorescent medium being confined to one sub-pixel of each of the pixels in a file.

2. An image display device according to claim 1 further characterized in that a set of parallel walls overlies the first electrode means and separates adjacent second electrode means.

3. An image display device according to claim 2 further characterized in that

the first electrode means are arranged in parallel rows,

each first electrode means joins and forms a part of all of the sub-pixels in a row,

the second electrode means are arranged in parallel columns,

each second electrode means is divided into at least two laterally spaced electrode elements,

a first electrode element of each second electrode means joins and forms a part of one of the sub-pixels of all of the pixels in a column,

a second electrode element of each second electrode means joins and forms a part of a second of the sub-pixels of all of the pixels in the same column, and

the walls are laterally located between adjacent columns of sub-pixels.

4. An image display device according to claim 2 further characterized in that

the second electrode means are arranged in parallel rows,

each second electrode means joins and forms a part of all of the sub-pixels in a row,

the first electrode means are arranged in parallel columns,

each first electrode means is divided into at least two laterally spaced electrode elements,

a first electrode element of each first electrode means joins and forms a part of one of the sub-pixels of all of the pixels in a column,

a second electrode element of each first electrode means joins and forms a part of a second of the sub-pixels of all of the pixels in the same column, and

the walls are laterally located between adjacent rows of pixels.

5. An image display device according to claim 1 further characterized in that the device has a full-color display capability, each of the pixels being divided into three sub-pixels, a first fluorescent medium located on the upper surface of said support and underlying the first electrode means, and capable of absorbing light emitted by said electroluminescent medium and emitting green light is positioned to receive emitted light from said organic electroluminescent medium transmitted through the first electrode means and is confined to one subpixel of each of the pixels in a file, and a second fluorescent medium located on the upper surface of said support and underlying the first electrode means, and capable of absorbing light emitted by said organic electroluminescent medium and emitting red light is positioned to receive emitted light from said organic electroluminescent medium transmitted through the first electrode means and is confined to a second sub-pixel of each of the pixels in the same file.

6. An image display device having full color capability according to claim 5 further characterized in that said organic electroluminescent medium is comprised of a bis (8-quinolinolato) (phenolato) aluminum (III) chelate or a bis(8-quinolinolato)aluminum(III)-μ

-oxo-bis(8-quinolinolato)aluminum(III) chelate.

7. An image display device comprised of an array consisting of

a plurality of light emitting pixels arranged in two intersecting sets of parallel files, the pixels in a first set of parallel files forming columns and the pixels in a second set of parallel files forming rows on an electrically insulative support, the pixels in each file of said first set of parallel files containing and being joined by a common light transmissive first electrode means overlying said support,

the first electrode means in adjacent files of said first set being laterally spaced on said support,

an organic electroluminescent medium overlying the first electrode means and said support,

the pixels in each file of said second set of parallel files containing and being joined by a common second electrode means overlying said organic electroluminescent medium, and

the second electrode means in adjacent files of said second set being laterally spaced on said organic electroluminescent medium,

characterized in that the device is capable of producing full color image display,

said organic electroluminescent medium emits in the blue region of the spectrum and has a peak emission at a wavelength of less than 480 nm,

each pixel in said first set of parallel files of pixels is divided into three sub-pixels,

in said first set one of said first and second electrode means that is contained in and joins the pixels in each file of said first set is divided into three laterally spaced electrode elements, each one of the electrode elements joining and forming a part of one sub-pixel of each of the pixels in a file,

one fluorescent medium located on the upper surface of said support and underlying the first electrode means, and capable of absorbing light emitted by said organic electroluminescent medium and emitting green light is positioned to receive emitted light from said organic electroluminescent medium transmitted through the first electrode means and is confined to one sub-pixel of each of the pixels in a file,

a second fluorescent medium located on the upper surface of said support and underlying the first electrode means, and capable of absorbing light emitted by said organic electroluminescent medium and emitting red light is positioned to receive emitted light from said organic electroluminescent medium transmitted through the first electrode means and is confined to a second sub-pixel in each of the pixels in the same file, and

a set of parallel walls overlying the first electrode means and separating adjacent second electrode means.

8. An image display device according to claim 7 further characterized in that

the first electrode means are arranged in parallel rows,

each first electrode means joins and forms a part of all of the sub-pixels in a row,

the second electrode means are arranged in parallel columns,

each second electrode means is divided into at least three laterally spaced electrode elements,

a first electrode element of each second electrode means joins and forms a part of one of the sub-pixels of all of the pixels in a column,

a second electrode element of each second electrode means joins and forms a part of a second of the sub-pixels of all of the pixels in the same column,

a third electrode element of each second electrode means joins and forms a part of a third of the sub-pixels of all of the pixels in the same column, and

the walls are laterally located between adjacent columns of sub-pixels.

9. An image display device according to claim 7 further characterized in that

the second electrode means are arranged in parallel rows,

each second electrode means joins and forms a part of all of the sub-pixels in a row,

the first electrode means are arranged in parallel columns,

each first electrode means is divided into at least three laterally spaced electrode elements,

a first electrode element of each first electrode means joins and forms a part of one of the sub-pixels of all of the pixels in a column,

a second electrode element of each first electrode means joins and forms a part of a second of the sub-pixels of all of the pixels in the same column,

a third electrode element of each first electrode means joins and forms a part of a third of the sub-pixels all of the pixels in the same column, and

the walls are laterally located between adjacent rows of pixels.

10. An image display device according to claim 7 further characterized in that said organic electroluminescent medium is comprised of a bis(8-quinolinolato)(phenolato)aluminum (III) chelate or a bis(8-quinolinolato)aluminum(III)-μ

-oxobis(8-quinolinolato)aluminum(III) chelate.

11. An image display device according to claim 10 further characterized in that said organic electroluminescent medium contains an electron injecting layer containing an aluminum trisoxine in contact with the second electrode means.