Reflective articles having improved corrosion resistance

• US 5,296,297 A
• Filed: 11/01/1991
• Issued: 03/22/1994
• Est. Priority Date: 11/03/1990
• Status: Expired due to Term

• Current Assignee: Glaverbel
• Original Assignee: Glaverbel
• Inventors: Servais, Albert, Somerhausen, Bernard, Dauby, Christian
• Primary Examiner(s): Ryan, Patrick J.
• Assistant Examiner(s): Bahta, Abraham
• Application Number:
  US07/786,826
• Time in Patent Office: 872 Days
• Field of Search: 428/457, 428/432, 428/428, 428/426, 428/433, 428/434
• US Class Current: 428/426
• CPC Class Codes: C03C 17/36 at least one coating being a metal
• CPC Class Codes: C03C 17/3605 Coatings of the type glass/metal/inorganic compound
• CPC Class Codes: C03C 17/3644 the metal being silver
• CPC Class Codes: C03C 17/3652 the coating stack containing at least one sacrificial layer to protect the metal from oxidation
• CPC Class Codes: C03C 17/366 Low-emissivity or solar control coatings
• CPC Class Codes: C03C 17/3663 specially adapted for use as mirrors
• CPC Class Codes: Y10T 428/31678 Of metal

Abstract

A reflective article such as a mirror or an energy-screening transparent panel comprises a reflective metal coating deposited on a glass substrate. The metal coating comprises a reflective layer of silver and has been treated with a solution containing ions of at least one of the group consisting of: Cr(II); V(II or III); Ti(III or II); Fe(II); In(I or II); Cu(I); and Al(III). Such a treatment affords protection of the reflective coating against corrosion.

Claims

1. A reflective article, comprising:

a glass substrate; and

a reflective metal coating deposited on the glass substrate and comprised of a reflective layer of silver which has been treated with a solution containing at least one ion selected from the group consisting of Cr(II), V(II or III), Ti(III or II), Fe(II), In(I or II), Cu(I), and Al(III), washed and dried, whereby the reflective metal coating is protected against corrosion.

2. The reflective article according to claim 1, wherein the glass substrate is a sheet of glass and the metal coating is a transparent coating applied to the sheet of glass, and wherein the reflective article is a hollow glazing unit comprised of the glass substrate and at least one other glass sheet held in spaced relation to one another to form the hollow glazing unit, the metal coating being located inside the hollow glazing unit.

3. The reflective article according to claim 1, wherein the reflective article is a mirror.

4. The reflective article according to claim 3, further comprising at least one protective layer of paint overcoated onto the reflective metal coating.

5. The reflective article according to claim 4, wherein the reflective metal coating is treated with a silane prior to overcoating with the at least one protective layer of paint.

6. The reflective article according to claim 4, wherein the at least one protective layer of paint consists essentially of paint which is substantially lead-free.

7. The reflective article according to claim 1, wherein the reflective layer of silver is a vacuum deposited layer of silver.

8. The reflective article according to claim 1, wherein the reflective metal coating is the reflective layer of silver.

9. The reflective article according to claim 1, wherein the reflective metal coating is constituted by the reflective layer of silver and an overcoating which is a film of copper.

10. The reflective article according to claim 1, wherein the solution with which the reflective layer of silver is treated is an aqueous solution containing an ion selected from the group consisting of chloride and sulfate.

11. The reflective article according to claim 1, wherein the solution additionally contains ions of Sn(II).

12. A reflective article, comprising:

a glass substrate, and

a reflective metal coating deposited on the glass substrate and comprised of a reflective layer of silver which has been treated with a solution containing Al(III) ions whereby edge corrosion is reduced so that the reflective metal coating has a maximum edge corrosion which does not exceed 179 μ

m measured by a CASS test and a mean edge corrosion which does not exceed 322 μ

m measured by the CASS test, and a mean edge corrosion which does not exceed 37 μ

m measured according to a Salt Fog Test.

13. A reflective article, comprising:

a glass substrate, and

a reflective metal coating deposited on the glass substrate and comprised of a reflective layer of silver which has been treated with a solution containing Cr(II) ions whereby edge corrosion is reduced so that the reflective metal coating has a maximum edge corrosion which does not exceed 4100 μ

m measured by a CASS test and a mean edge corrosion which does not exceed 3000 μ

m measured by the CASS test, and a mean edge corrosion which does not exceed 24 μ

m measured according to a Salt Fog Test.

14. A reflective article, comprising:

a glass substrate, and

a reflective metal coating deposited on the glass substrate and comprised of a reflective layer of silver which has been treated with a solution containing V(III) ions whereby edge corrosion is reduced so that the reflective metal coating has a maximum edge corrosion which does not exceed 769 μ

m measured by a CASS test and a mean edge corrosion which does not exceed 240 μ

m measured by the CASS test, and a mean edge corrosion which does not exceed 18 μ

m measured according to a Salt Fog Test.

15. A reflective article, comprising:

a glass substrate, and

a reflective metal coating deposited on the glass substrate and comprised of a reflective layer of silver which has been treated with a solution containing Ti(III) ions whereby edge corrosion is reduced so that the reflective metal coating has a maximum edge corrosion which does not exceed 404 μ

m measured by a CASS test and a mean edge corrosion which does not exceed 147 μ

m measured by the CASS test, and a mean edge corrosion which does not exceed 18 μ

m measured according to a Salt Fog Test.

16. A reflective article, comprising:

a glass substrate, and

a reflective metal coating deposited on the glass substrate and comprised of a reflective layer of silver which has been treated with a solution containing Fe(II) ions whereby edge corrosion is reduced so that the reflective metal coating has a maximum edge corrosion which does not exceed 3218 μ

m measured by a CASS test and a mean edge corrosion which does not exceed 1478 μ

m measured by the CASS test.