Polymeric composition

• US 5,296,558 A
• Filed: 08/05/1993
• Issued: 03/22/1994
• Est. Priority Date: 05/05/1988
• Status: Expired due to Term

• Current Assignee: Tyco Electronics UK Limited (TE Connectivity Limited)
• Original Assignee: Raychem Limited (TE Connectivity Limited)
• Inventors: Day, Stephen, Hood, Kathleen A., Penneck, Richard J.
• Primary Examiner(s): WOODWARD, ANA LUCRECIA
• Application Number:
  US08/102,679
• Time in Patent Office: 229 Days
• Field of Search: 525/425, 525/432, 525/436
• US Class Current: 525/425
• CPC Class Codes: C08L 67/03 the dicarboxylic acids and dihydroxy compounds having the carboxyl- and the hydroxy groups directly linked to aromatic rings
• CPC Class Codes: C08L 77/00 Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain of polyhydrazides C08L79/06; of polyamideimides or polyamide acids C08L79/08; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 79/08 Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
• CPC Class Codes: H01B 3/306 Polyimides or polyesterimides
• CPC Class Codes: H01B 3/421 Polyesters

Abstract

A polymeric composition comprises:

(i) an aromatic polyimide or an aromatic carboxylic ester polymer,

(ii) a substantially wholly aliphatic polyamide, and

(iii) a polyamide that contains both aromatic aliphatic moieties.

It is found that the mechanical properties of blends of the aromatic polymers (i) and the polyamides (iii) can be significantly improved by the incorporation of a quantity of the aliphatic amides (ii), even though the miscibility of polymers, as observed by their glass transition temperatures may remain unchanged.

Claims

1. A polymeric composition which comprises:

(i) from 10 to 60% by weight of an aromatic polyimide or an aromatic carboxylic ester polymer,

(ii) from 2 to 20% by weight of an aliphatic polyamide, and

(iii) from 30 to 75% by weight of a polyamide that contains both aromatic and aliphatic moieties.

2. A composition as claimed in claim 1, in which the polyamide that contains both aromatic and aliphatic moieties has alkylene groups of the same length or carbon atom number as the aliphatic polyamide.

3. A composition as claimed in claim 1 wherein the aromatic polyimide or carboxylic ester polymer has not more than one aliphatic backbone carbon atom per repeat unit.

4. A composition as claimed in claim 1 wherein the aromatic polymer (i) has a glass transition temperature of at least 140°

C.

5. A composition as claimed in claim 1, wherein the aromatic polymer (i) has the repeat unit:

##STR9## in which A represents a single or fused double membered aromatic group which is unsubstituted or substituted by one or more alkyl or alkoxy groups;

B represents arylene group that has one or more aromatic rings and which may be substituted with an alkylene moiety; and

R represents a divalent aromatic or aliphatic group.

6. A composition as claimed n claim 5, wherein the aromatic polymer has the general repeat unit:

##STR10##

7. A composition as claimed in claim 1 wherein the aliphatic polyamide has an alkylene group containing at least 5 carbon atoms.

8. A composition as claimed in claim 1 wherein the aromatic polymer (i) has the repeat unit:

##STR11## which contains a mixture of isophthalic and terephthalic acid units.

9. A composition as claimed in claim 8, wherein the aliphatic polyamide has an alkylene group containing 11 carbon atoms.

10. A composition as claimed in claim 1 wherein the aromatic/aliphatic polyamide includes units derived from a phthalic acid.

11. A composition as claimed in claim 1 wherein the aromatic/aliphatic polyamide has units derived from laurinlactam, isophthalic acid and bis-(4-amino-3-methylcyclohexyl)methane.

12. A composition as claimed in claim 1 wherein the aromatic/aliphatic polyamide has units derived from 2,2,4- and 2,4,4-trimethylhexamethylene diamine and terephthalic acid.

13. A composition as claimed in claim 1 which contains from 20% to 60% by weight of the aromatic polymer based on the total weight of the aromatic polymer and polyamides.

14. A composition as claimed in claim 1 which is crosslinked.

15. An extruded article that comprises a composition as claimed in claim 1.

16. A dimensionally recoverable article formed from a composition as claimed in claim 1.