Gel-free paint containing zinc pyrithione, cuprous oxide, and amine treated rosin

• US 5,298,061 A
• Filed: 05/14/1993
• Issued: 03/29/1994
• Est. Priority Date: 05/14/1993
• Status: Expired due to Term

• Current Assignee: Arch Chemicals Incorporated (Lonza Group AG)
• Original Assignee: OLIN Corporation
• Inventors: Waldron, Craig, Hani, Rahim, Farmer, Jr., Douglas A.
• Primary Examiner(s): Bell, Mark L.
• Assistant Examiner(s): Green, Anthony J.
• Application Number:
  US08/061,124
• Time in Patent Office: 319 Days
• Field of Search: 106/15.05, 106/16, 106/18.33, 106/18.34, 514/188, 514/345, 514/494, 504/121, 424/78.09, 523/122
• US Class Current: 106/18.33
• CPC Class Codes: C09D 5/1612 Non-macromolecular compounds

Abstract

The present invention relates generally to paints and paint bases, and, more specifically to a process and composition for providing a stable gel-free dispersion of zinc pyrithione plus cuprous oxide biocide in paint. In accordance with the process of the present invention, the paint or paint base contains an amine treated wood rosin in order to impart desired gelation-inhibition to the paint.

Claims

1. A paint or paint base composition characterized by enhanced biocidal efficacy and gelation resistance wherein the paint or paint base contains a biocide consisting essentially of cuprous oxide and zinc pyrithione, said zinc pyrithione being present in an amount of between about 1% and about 25%, and said cuprous oxide being present in an amount of between about 20% and about 70%, wherein the total amount of said zinc pyrithione plus said cuprous oxide is between about 20% and about 80%, based upon the total weight of the paint or paint base composition, wherein the paint or paint base additionally contains rosin amine or rosin amide in an amount sufficient to stabilize said paint or paint base against gelation, and wherein the amount of said rosin amine or rosin amide is between about 1% and 20% based upon the total weight of the paint or paint base composition.

3. The paint or paint base of claims 1 or 2 which additionally contains a resin selected from the group consisting of vinyl, alkyd, epoxy, acrylic, polyurethane and polyester resins, and combinations thereof.

4. The paint or paint base of claims 1 or 2 which additionally contains a swelling agent selected from the group consisting of natural and synthetic clay and natural and synthetic polymer swelling agents.

2. A solvent-based paint or paint base composition characterized by enhanced biocidal efficacy and gelation resistance wherein the paint or paint base contains a biocide consisting essentially of cuprous oxide and zinc pyrithione, and the paint or paint base further comprises a rosin amine or rosin amide or mixture of rosin amine or rosin amide plus underivatized rosin, said mixture having a total acidity indicated by an acid number of not greater than 70, and said rosin amine or rosin amide or mixture of said rosin amine or said rosin amide plus underivatized rosin being present in a total amount of between about 1% and 20%, based upon the total weight of the paint or paint base, said zinc pyrithione being present in an amount of between about 1% and about 25%, and said cuprous oxide being present in an amount of between about 20% and about 70%, wherein the total amount of said zinc pyrithione plus said cuprous oxide is between about 20% and about 80%, based upon the total weight of the paint or paint base composition.

5. A process for providing a gelation-inhibited solvent-based paint or paint base containing zinc pyrithione and cuprous oxide which comprises the steps of:

(a) incorporating said zinc pyrithione and also incorporating cuprous oxide into a solvent-based paint or paint base to provide a biocide-containing paint or paint base, said zinc pyrithione being present in an amount of between about 1% and about 25%, and said cuprous oxide being present in an amount of between about 20% and about 70%, the total amount of said zinc pyrithione plus said cuprous oxide being between about 20% and about 80%, said weight percents being based upon the total weight of the biocide-containing paint or paint base, and

(b) incorporating a rosin amine or rosin amide or a mixture of said amine or said amide plus underivatized rosin into said biocide-containing paint or paint base, said amine and said amide being the reaction product(s) of a carboxylic acid-containing rosin with an amine selected from the group with the formula of (NH₂)_x RNH₂, where x is 0 or 1 and R is H or C₁ to C₈ alkyl, alkenyl, alkynl, cycloalkyl, cycloalkenyl, or cycloalkynyl, each R group optionally having pendant hydroxyl or amino functionality, wherein the total amount of said rosin amine or rosin amide or mixture of rosin amine or rosin amide plus underivatized rosin is between about 1% and 20% based upon the total weight of the paint or paint base composition.

6. The process of claim 5 wherein the total amount of said zinc pyrithione plus said cuprous oxide is between about 20% and about 75% based upon the total weight of the paint or paint base composition.

7. The process of claim 5 wherein said composition additionally contains a resin selected from the group consisting of vinyl, alkyd, epoxy, acrylic, polyurethane and polyester resins, and combinations.

8. The process of claim 5 wherein said composition additionally contains a swelling agent selected from the group consisting of natural and synthetic clay and natural and synthetic polymer 5 swelling agents.

9. The process of claim 5 wherein steps (a) and (b) are carried out simultaneously.

10. The process of claim 8 wherein said swelling agent is selected from the group consisting of kaolin, montomorillonite (bentonite), clay mica (muscovite), and chlorite (hectonite), and combinations thereof.