Toner composition with semi-crystalline polyester wax and method of preparation

• US 5,298,355 A
• Filed: 11/13/1992
• Issued: 03/29/1994
• Est. Priority Date: 11/13/1992
• Status: Expired due to Term

• Current Assignee: Eastman Kodak Company
• Original Assignee: Eastman Kodak Company
• Inventors: Tyagi, Dinesh, Sorriero, Louis J., DiPrima, Donna A.
• Primary Examiner(s): MARTIN, ROLAND E
• Application Number:
  US07/975,741
• Time in Patent Office: 501 Days
• Field of Search: 430/110, 430/137
• US Class Current: 430/108.4
• CPC Class Codes: C09B 67/0013 with polymeric coatings
• CPC Class Codes: G03G 9/0804 whereby the components are brought together in a liquid dispersing medium
• CPC Class Codes: G03G 9/0812 Pretreatment of components
• CPC Class Codes: G03G 9/08755 Polyesters
• CPC Class Codes: G03G 9/09 Colouring agents for toner particles

Abstract

A method is described for the preparation of electrostatographic toner particles which involves the surface treatment of a pigment by depositing thereon a coating of a low melting point hydrophobic semi-crystalline polyester wax. The method involves preparing a wax solution by dissolving at ambient temperature a low melting point hydrophobic semi-crystalline polyester wax in a first solvent capable of dissolving the wax at ambient temperature; forming a pigment dispersion by mixing at ambient temperature a pigment, a first polymer material and a second solvent in which the hydrophobic wax is insoluble at ambient temperature; admixing the wax solution with the pigment dispersion so resulting in precipitation of the wax upon the surface of the pigment; mixing the wax coated pigment dispersion thus formed with a solvent in which the hydrophobic wax is insoluble at ambient temperature and, optionally, a second polymer material and, optionally, a charge-control agent to form an organic phase; dispersing the organic phase in an aqueous phase comprising a particulate stabilizer and, optionally, a promoter; homogenizing the resultant mixture, and evaporating the solvent and washing and drying the resultant product.

Claims

1. A method for the preparation of electrostatographic toner comprising the steps of:

(a) dissolving at ambient temperature a low melting point hydrophobic semi-crystalline polyester wax in a first solvent capable of dissolving the wax at ambient temperature, thereby forming a solution;

(b) forming a pigment dispersion at ambient temperature by mixing a pigment, a first polymer material and a second solvent in which the hydrophobic wax is insoluble at ambient temperature;

(c) admixing the wax solution with the pigment dispersion so resulting in precipitation of the wax upon the surface of the pigment;

(d) mixing the wax coated pigment dispersion thus formed with a solvent in which the hydrophobic wax is insoluble at ambient temperature, and optionally, a second polymer material and, optionally, a charge-control agent to form an organic phase;

(e) dispersing the organic phase in an aqueous phase comprising a particulate stabilizer and, optionally, a promoter and homogenizing the resultant mixture; and

(f) evaporating the solvent and washing and drying the resultant product.

2. The method of claim 1, wherein the pigment employed comprises from about 4 to 20%, by weight, of total solids including wax.

3. The method of claim 1, wherein the wax is a hydrophobic wax and is employed in an amount ranging from about 20 to 200%, by weight, of the pigment employed.

4. The method of claim 1, wherein the relationship between the aqueous phase and the organic phase, by volume, ranges from about 1.5:

1 to 9;

1.

5. The method of claim 1, wherein the low melting point wax has a melting point within the range of about 55°

to 120°

C.

6. The method of claim 1, wherein the low melting point wax is poly(decamethylene sebacate), the first solvent is dichloromethane and the second solvent is ethyl acetate and the polymer is buty acrylate-styrene copolymer.

7. The method of claim 1, wherein the particulate stabilizer is selected from the group consisting of highly cross-linked latex particles and SiO₂.

8. The method of claim 1, wherein the dispersion comprises media milled quinacridone magenta.

9. The method of claim 1, wherein the polymer is butyl acrylate-styrene copolymer.

18. Electrostatographic toner prepared in accordance with the method of claim 1.

10. In a method of preparing electrostatographic toner by dispersing an organic phase in an aqueous phase to yield a layer of particulate suspension stabilizer on the surface of a polymer, the improvement which comprises forming a wax coated pigment dispersion by dissolving a low melting point hydrophobic semi-crystalline hydrophobic wax in a first solvent capable of dissolving the wax at ambient temperature thereby forming a wax solution;

forming a pigment dispersion by mixing at ambient temperature a pigment, a first polymer material and a second solvent in which the hydrophobic wax is insoluble at ambient temperature;

admixing the wax solution with the pigment dispersion so resulting in the wax precipitating out upon the surface of the pigment;

mixing the wax coated pigment dispersion thus formed with a solvent in which the hydrophobic wax is insoluble at ambient temperature and, optionally, a second polymer material and, optionally, a charge-control agent to form the organic phase for dispersing in the aqueous phase.

11. The method of claim 10, wherein the low melting point wax has a melting point within a range of 55°

to 120°

C.

12. The method of claim 11, wherein the low melting point wax is poly(decamethylene sebacate), the first solvent is dichloromethane, the second solvent is ethyl acetate and the polymer is butyl acrylate-styrene copolymer.

13. The method of claim 12, wherein the pigment dispersion comprises quinacridone magenta.

14. The method of claim 13, wherein the pigment to wax ratio in the pigment dispersion-wax solution is about 2.5:

1.

15. The method of claim 14, wherein the wax has a melting temperature of approximately 70°

C.

19. Electrostatographic toner prepared in accordance with the method of claim 10.

16. A method of preparing a uniform coating of a low melting point hydrophobic semi-crystalline polyester wax on pigment particles comprising the steps of:

(a) forming a solution of the low melting point hydrophobic wax in a first solvent capable of dissolving the wax at ambient temperature;

(b) mixing the wax solution with a pigment particle dispersion in a dispersing liquid at ambient temperature to deposit the wax on the pigment particles as a coating on the surface of the particles; and

(c) recovering the coated pigment particles.

17. A method according to claim 16, wherein the dispersing liquid is water.