Ink compositions for ink jet printing
First Claim
1. An ink composition which comprises water, a water soluble dye, a first component selected from the group consisting of diphenyl sulfone, methyl phenyl sulfone, ethyl phenyl sulfone, propyl phenyl sulfone, butyl phenyl sulfone, pentyl phenyl sulfone, hexyl phenyl sulfone, heptyl phenyl sulfone, octyl phenyl sulfone, nonyl phenyl sulfone, decyl phenyl sulfone, phenyl benzyl sulfone, phenyl polyoxyethylene sulfone, phenyl ethanol sulfone, phenyl propanol sulfone, phenyl polyoxypropylene sulfone, and mixtures thereof, and a second component selected from the group consisting of (a) cyclic amines having at least one hydrogen atom bonded to a nitrogen atom;
- (b) cyclic amides having at least one hydrogen atom bonded to a nitrogen atom;
(c) diamides having at least one hydrogen atom bonded to a nitrogen atom;
(d) polyalkoxy-substituted amides having at least one hydrogen atom bonded to a nitrogen atom;
(e) polyimine-substituted amides having at least one hydrogen atom bonded to a nitrogen atom; and
(f) mixtures thereof, wherein at least one of the first and second components is a solid at 25°
C., and wherein the ink is a liquid.
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Accused Products
Abstract
Disclosed is an ink composition which comprises water, a water soluble dye, a first component selected from the group consisting of sulfones and mixtures thereof, and a second component selected from the group consisting of cyclic amines having at least one hydrogen atom bonded to a nitrogen atom, cyclic amides having at least one hydrogen atom bonded to a nitrogen atom, diamides having at least one hydrogen atom bonded to a nitrogen atom, polyalkoxy-substituted amides having at least one hydrogen atom bonded to a nitrogen atom, polyimine-substituted amides having at least one hydrogen atom bonded to a nitrogen atom, and mixtures thereof. Also disclosed is an ink jet printing process employing these inks.
44 Citations
37 Claims
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1. An ink composition which comprises water, a water soluble dye, a first component selected from the group consisting of diphenyl sulfone, methyl phenyl sulfone, ethyl phenyl sulfone, propyl phenyl sulfone, butyl phenyl sulfone, pentyl phenyl sulfone, hexyl phenyl sulfone, heptyl phenyl sulfone, octyl phenyl sulfone, nonyl phenyl sulfone, decyl phenyl sulfone, phenyl benzyl sulfone, phenyl polyoxyethylene sulfone, phenyl ethanol sulfone, phenyl propanol sulfone, phenyl polyoxypropylene sulfone, and mixtures thereof, and a second component selected from the group consisting of (a) cyclic amines having at least one hydrogen atom bonded to a nitrogen atom;
- (b) cyclic amides having at least one hydrogen atom bonded to a nitrogen atom;
(c) diamides having at least one hydrogen atom bonded to a nitrogen atom;
(d) polyalkoxy-substituted amides having at least one hydrogen atom bonded to a nitrogen atom;
(e) polyimine-substituted amides having at least one hydrogen atom bonded to a nitrogen atom; and
(f) mixtures thereof, wherein at least one of the first and second components is a solid at 25°
C., and wherein the ink is a liquid.
- (b) cyclic amides having at least one hydrogen atom bonded to a nitrogen atom;
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2. An ink composition which comprises water, a water soluble dye, a first component selected from the group consisting of sulfones and mixtures thereof, and a second component which is a cyclic amine, wherein the cyclic amine is selected from the group consisting of (a) cyclic amines of the formula ##STR91## wherein R is an optional substituent, m is an integer representing the number of substituents, and n is an integer of at least about 3;
- (b) cyclic amines of the formula ##STR92## wherein R is an optional substituent, z is an integer representing the number of substituents, and m and n are integers independently selected from 0, 1, 2, and 3, wherein the sum of m+n is at least about 2;
(c) cyclic polyamines of the formula ##STR93## wherein R is an optional substituent, z is an integer representing the number of substituents, p, q, and r are each integers selected from the group consisting of 0, 1, 2, 3, and 4, wherein the sum of p+q+r is at least about 2, s is an integer of from 1 to about 4, and R'"'"' and R" are independently selected from the group consisting of hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, alcohol, alkoxy, and polyalkoxy, wherein at least one of R'"'"' and R" is hydrogen;
(d) cyclic polyamines of the formula ##STR94## wherein R is an optional substituent, z is an integer representing the number of substituents, m, n, and p are each integers selected from the group consisting of 0, 1, 2, 3, and 4, wherein the sum of m+n+p is at least about 2, s is an integer of from 1 to about 4, and R'"'"' and R" are independently selected from the group consisting of hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, alcohol, alkoxy, and polyalkoxy, wherein at least one of R'"'"' and R" is hydrogen; and
(e) mixtures thereof, wherein at least one of the first and second components is a solid at 25°
C., and wherein the ink is a liquid.
- (b) cyclic amines of the formula ##STR92## wherein R is an optional substituent, z is an integer representing the number of substituents, and m and n are integers independently selected from 0, 1, 2, and 3, wherein the sum of m+n is at least about 2;
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3. An ink composition which comprises water, a water soluble dye, a first component selected from the group consisting of sulfones and mixtures thereof, and a second component which is a cyclic amine, wherein the cyclic amine is selected from the group consisting of pyrrolidine, substituted pyrrolidines, pyrazole, substituted pyrazoles, imidazole, substituted imidazoles, triazoles, substituted triazoles, tetrazoles, substituted tetrazoles, piperazines, substituted piperazines, and mixtures thereof, wherein at least one of the first and second components is a solid at 25°
- C., and wherein the ink is a liquid.
-
4. An ink composition which comprises water, a water soluble dye, a first component selected from the group consisting of sulfones and mixtures thereof, and a second component which is a cyclic amide, wherein the cyclic amide is selected from the group consisting of 2-azacyclooctanone, substituted 2-azacyclooctanones, 2-azacyclononanone, substituted 2-azacyclononanones, and mixtures thereof, wherein at least one of the first and second components is a solid at 25°
- C., and wherein the ink is a liquid.
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5. An ink composition which comprises water, a water soluble dye, a first component selected from the group consisting of sulfones and mixtures thereof, and a second component which is a diamide, wherein the diamide is of the formula ##STR95## wherein R1 is selected from the group consisting of alkylene groups, substituted alkylene groups, arylene groups, substituted arylene groups, alcohol moieties, alkoxy moieties, polyalkoxy moieties, and mixtures thereif, wherein R2, R3, R4, and R5 are independently selected from the group consisting of hydrogen, alkyl groups, substituted alkyl groups, aryl groups, substituted aryl groups, alcohol moieties, alkoxy moieties, polyalkoxy moieties, and mixtures thereof, and wherein at least one of R2, R3, R4, and R5 is a hydrogen atom, wherein at least one of the first and second components is a solid at 25°
- C., and wherein the ink is a liquid.
-
6. An ink composition which comprises water, a water soluble dye, a first component selected from the group consisting of sulfones and mixtures thereof, and a second component which is a diamide, wherein the diamide is selected from the group consisting of malonamide, succinamide, glutaramide, adipamide, and mixtures thereof, wherein at least one of the first and second components is a solid at 25°
- C., and wherein the ink is a liquid.
-
7. An ink composition which comprises water, a water soluble dye, a first component selected from the group consisting of sulfones and mixtures thereof, and a second component which is an amide of the formula ##STR96## wherein R is a hydrogen atom or an alkyl group and R'"'"' is selected from the group consisting of alkoxy groups, polyalkoxy groups, imine groups, and polyimine groups, wherein at least one of the first and second components is a solid at 25°
- C., and wherein the ink is a liquid.
- 8. An ink composition which comprises water, a water soluble dye, a first component selected from the group consisting of sulfones and mixtures thereof, and a second component which is an amide of the formula ##STR97## wherein R is a hydrogen atom or an alkyl group and R'"'"' is selected from the group consisting of
- space="preserve" listing-type="equation">([--CH.sub.2 ].sub.n --O).sub.m --[CH.sub.2 ].sub.n --OH
wherein n is an integer of from 1 to about 4 and m is an integer of from 0 to about 9;
##STR98## wherein a is an integer of from 1 to about 4, b and c are each integers of from 0 to about 4, wherein the sum of a+b+c is no greater than about 6, and m is an integer of from 0 to about 9;
##STR99## wherein a and b are each integers of from 1 to about 4, c and d are each integers of from 0 to about 4, wherein the sum of a+b+c+d is no greater than about 8, and m is an integer of from 0 to about 9;
##STR100## wherein a is an integer of from 1 to about 4, b and c are each integers of from 0 to about 4, wherein the sum of a+b+c is no greater than about 6, and m is an integer of from 0 to about 9;
##STR101## wherein a and b are each integers of from 1 to about 4, c and d are each integers of from 0 to about 4, wherein the sum of a+b+c+d is no greater than about 8, and m is an integer of from 0 to about 9;
##STR102## wherein a is an integer of from 1 to about 4, b and c are each integers of from 0 to about 4, wherein the sum of a+b+c is no greater than about 6, m is an integer of from 0 to about 9, and R1, R2, R3, R4, and R5 are independently selected from the group consisting of hydrogen, alkyl groups, and substituted alkyl groups, wherein the total number of carbon atoms in R1 +R2 +R3 +R4 +R5 is from 1 to about 10;
##STR103## wherein a and b are each integers of from 1 to about 4, c and d are each integers of from 0 to about 4, wherein the sum of a+b+c+d is no greater than about 8, m is an integer of from 0 to about 9, and R1, R2, R3, and R4 are independently selected from the group consisting of hydrogen, alkyl groups, and substituted alkyl groups, wherein the total number of carbon atoms in R1 +R2 +R3 +R4 is from 1 to about 8;
space="preserve" listing-type="equation">([--CH.sub.2 ].sub.l --NH).sub.k --[CH.sub.2 ].sub.l --NH.sub.2wherein l is an integer of from 1 to about 4 and k is an integer of from 0 to about 9;
##STR104## wherein a is an integer of from 1 to about 4, b and c are each integers of from 0 to about 4, wherein the sum of a+b+c is no greater than about 6, and k is an integer of from 0 to about 9;
##STR105## wherein a and b are each integers of from 1 to about 4, c and d are each integers of from 0 to about 4, wherein the sum of a+b+c+d is no greater than about 8, and k is an integer of from 0 to about 9;
##STR106## wherein a is an integer of from 1 to about 4, b and c are each integers of from 0 to about 4, wherein the sum of a+b+c is no greater than about 6, and k is an integer of from 0 to about 9;
##STR107## wherein a and b are each integers of from 1 to about 4, c and d are each integers of from 0 to about 4, wherein the sum of a+b+c+d is no greater than about 8, and k is an integer of from 0 to about 9;
##STR108## wherein a is an integer of from 1 to about 4, b and c are each integers of from 0 to about 4, wherein the sum of a+b+c is no greater than about 6, k is an integer of from 0 to about 9, and R1, R2, R3, R4, and R5 are independently selected from the group consisting of hydrogen, alkyl groups, and substituted alkyl groups, wherein the total number of carbon atoms in R1 +R2 +R3 +R4 +R5 is from 1 to about 10;
##STR109## wherein a and b are each integers of from 1 to about 4, c and d are each integers of from 0 to about 4, wherein the sum of a+b+c+d is no greater than about 10, m is an integer of from 0 to about 9, and R1, R2, R3, and R4 are independently selected from the group consisting of hydrogen, alkyl groups, and substituted alkyl groups, wherein the total number of carbon atoms in R1 +R2 +R3 +R4 is from 1 to about 8;
##STR110## wherein e and f are each integers of from 1 to about 4, the sum of e+f is no greater than about 6, and k is an integer of from 0 to about 9;
##STR111## wherein a and e are each integers of from 1 to about 4, b and c are each integers of from 0 to about 4, wherein the sum of a+b+c+e is no greater than about 8, and k is an integer of from 0 to about 9;
##STR112## wherein a, b, and e are each integers of from 1 to about 4, c and d are each integers of from 0 to about 4, wherein the sum of a+b+c+d+e is no greater than about 10, and k is an integer of from 0 to about 9;
##STR113## wherein a and e are each integers of from 1 to about 4, b and c are each integers of from 0 to about 4, wherein the sum of a+b+c+e is no greater than about 8, and k is an integer of from 0 to about 9;
##STR114## wherein a, b, and e are each integers of from 1 to about 4, c and d are each integers of from 0 to about 4, wherein the sum of a+b+c+d+e is no greater than about 10, and k is an integer of from 0 to about 9;
##STR115## wherein a and e are each integers of from 1 to about 4, b and c are each integers of from 0 to about 4, wherein the sum of a+b+c+e is no greater than about 8, m is an integer of from 0 to about 9, and R1, R2, R3, R4, and R5 are independently selected from the group consisting of hydrogen, alkyl groups, and substituted alkyl groups, wherein the total number of carbon atoms in R1 +R2 +R3 +R4 +R5 is from 1 to about 10; and
##STR116## wherein a, b, and e are each integers of from 1 to about 4, c and d are each integers of from 0 to about 4, wherein the sum of a+b+c+d+e is no greater than about 10, m is an integer of from 0 to about 9, and R1, R2, R3, and R4 are independently selected from the group consisting of hydrogen, alkyl groups, and substituted alkyl groups, wherein the total number of carbon atoms in R1 +R2 +R3 +R4 is from 1 to about 8, wherein at least one of the first and second components is a solid at 25°
C., and wherein the ink is a liquid.
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9. An ink which comprises water, a water soluble dye, a first component selected from the group consisting of sulfones and mixtures thereof, and a second component selected from the group consisting of formylethanolamine, acetylethanolamine, propionyl ethanolamine, formyl n-propanolamine, acetyl n-propanolamine, propionyl n-propanolamine, and mixtures thereof, wherein at least one of the first and second components is a solid at 25°
- C., and wherein the ink is a liquid.
-
10. An ink composition which comprises water, a water soluble dye, a first component selected from the group consisting of (a) sulfones of the formula R1 ? ##STR117## wherein R1 and R2 are independently selected from the group consisting of aliphatic hydrocarbons, substituted aliphatic hydrocarbons, aromatic hydrocarbons, substituted aromatic hydrocarbons, alcohol moieties, alkoxy moieties, and polyalkoxy moieties, wherein at least one of R1 and R2 is either an aromatic hydrocarbon or a substituted aromatic hydrocarbon;
- (b) polysulfones;
(c) cyclic polysulfones; and
(d) mixtures thereof, and a second component selected from the group consisting of (a) cyclic amines having at least one hydrogen atom bonded to a nitrogen atom;
(b) cyclic amides having at least one hydrogen atom bonded to a nitrogen atom;
(c) diamides having at least one hydrogen atom bonded to a nitrogen atom;
(d) amides of the formula ##STR118## wherein R is a hydrogen atom or an alkyl group and R'"'"' is selected from the group consisting of alkoxy groups, polyalkoxy groups, imine groups, and polyimine groups; and
(e) mixtures thereof, wherein the ink is a liquid. - View Dependent Claims (11, 12, 13, 14, 17, 18)
- (b) polysulfones;
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15. An ink composition which comprises water, a water soluble dye, a first component selected from the group consisting of (a) sulfones of the formula ##STR119## wherein R1 and R2 are independently selected from the group consisting of aliphatic hydrocarbons, substituted aliphatic hydrocarbons, aromatic hydrocarbons, substituted aromatic hydrocarbons, alcohol moieties, alkoxy moieties, and polyalkoxy moieties;
- (b) cyclic sulfones of the formula ##STR120## wherein R is an optional substituent, m is an integer representing the number of substituents, and n is an integer of at least about 4;
(c) cyclic sulfones of the formula ##STR121## wherein R is a substituent selected from the group consisting of alkyl, hydroxy, alcohol, and alkoxy, x is an integer representing the number of substituents, and n is an integer of at least about 2;
(d) cyclic sulfones of the formula ##STR122## wherein R is an optional substituent, z is an integer representing the number of substituents, and m and n are integers independently selected from 0, 1, 2, and 3, wherein the sum of m+n is at least about 1;
(e) polysulfones;
(f) cyclic polysulfones;
(g) sulfonamides; and
(h) mixtures thereof, and a second component selected from the group consisting of (a) cyclic amines of the formula ##STR123## wherein R is an optional substituent, m is an integer representing the number of substituents, and n is an integer of at least about 3;
(b) cyclic amines of the formula ##STR124## wherein R is an optional substituent, z is an integer representing the number of substituents, and m and n are integers independently selected from 0, 1, 2, and 3, wherein the sum of m+n is at least about 2;
(c) cyclic polyamines of the formula ##STR125## wherein R is an optional substituent, z is an integer representing the number of substituents, p, q, and r are each integers selected from the group consisting of 0, 1, 2, 3, and 4, wherein the sum of p+q+r is at least about 2, s is an integer of from 1 to about 4, and R'"'"' and R" are independently selected from the group consisting of hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, alcohol, alkoxy, and polyalkoxy, wherein at least one of R'"'"' and R" is hydrogen;
(d) cyclic polyamines of the formula ##STR126## wherein R is an optional substituent, z is an integer representing the number of substituents, m, n, and p are each integers selected from the group consisting of 0, 1, 2, 3, and 4, wherein the sum of m+n+p is at least about 2, s is an integer of from 1 to about 4, and R'"'"' and R" are independently selected from the group consisting of hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, alcohol, alkoxy, and polyalkoxy, wherein at least one of R'"'"' and R" is hydrogen; and
(e) mixtures thereof, wherein the ink is a liquid.
- (b) cyclic sulfones of the formula ##STR120## wherein R is an optional substituent, m is an integer representing the number of substituents, and n is an integer of at least about 4;
-
16. An ink composition which comprises water, a water soluble dye, a first component selected from the group consisting of (a) sulfones of the formula ##STR127## wherein R1 and R2 are independently selected from the group consisting of aliphatic hydrocarbons, substituted aliphatic hydrocarbons, aromatic hydrocarbons, substituted aromatic hydrocarbons, alcohol moieties, alkoxy moieties, and polyalkoxy moieties;
- (b) cyclic sulfones of the formula ##STR128## wherein R is an optional substituent, m is an integer representing the number of substituents, and n is an integer of at least about 4;
(c) cyclic sulfones of the formula ##STR129## wherein R is a substituent selected from the group consisting of alkyl, hydroxy, alcohol, and alkoxy, x is an integer representing the number of substituents, and n is an integer of at least about 2;
(d) cyclic sulfones of the formula ##STR130## wherein R is an optional substituent, z is an integer representing the number of substituents, and m and n are integers independently selected from 0, 1, 2, and 3, wherein the sum of m+n is at least about 1;
(e) polysulfones;
(f) cyclic polysulfones;
(g) sulfonamides; and
(h) mixtures thereof, and a second component selected from the group consisting of pyrrolidine, substituted pyrrolidines, pyrazole, substituted pyrazoles, imidazole, substituted imidazoles, triazoles, substituted triazoles, tetrazoles, substituted tetrazoles, piperazines, substituted piperazines, and mixtures thereof, wherein the ink is a liquid.
- (b) cyclic sulfones of the formula ##STR128## wherein R is an optional substituent, m is an integer representing the number of substituents, and n is an integer of at least about 4;
-
19. An ink composition which comprises water, a water soluble dye, a first component selected from the group consisting of (a) sulfones of the formula ##STR135## wherein R1 and R2 are independently selected from the group consisting of aliphatic hydrocarbons, substituted aliphatic hydrocarbons, aromatic hydrocarbons, substituted aromatic hydrocarbons, alcohol moieties, alkoxy moieties, and polyalkoxy moieties;
- (b) cyclic sulfones of the formula ##STR136## wherein R is an optional substituent, m is an integer representing the number of substituents, and n is an integer of at least about 4;
(c) cyclic sulfones of the formula ##STR137## wherein R is a substituent selected from the group consisting of alkyl, hydroxy, alcohol, and alkoxy, x is an integer representing the number of substituents, and n is an integer of at least about 2;
(d) cyclic sulfones of the formula ##STR138## wherein R is an optional substituent, z is an integer representing the number of substituents, and m and n are integers independently selected from 0, 1, 2, and 3, wherein the sum of m+n is at least about 1;
(e) polysulfones;
(f) cyclic polysulfones;
(g) sulfonamides; and
(h) mixtures thereof, and a second component which is a diamide, wherein the diamide is of the formula ##STR139## wherein R1 is selected from the group consisting of alkylene groups, substituted alkylene groups, arylene groups, substituted arylene groups, alcohol moieties, alkoxy moieties, polyalkoxy moieties, and mixtures thereif, wherein R2, R3, R4, and R5 are independently selected from the group consisting of hydrogen, alkyl groups, substituted alkyl groups, aryl groups, substituted aryl groups, alcohol moieties, alkoxy moieties, polyalkoxy moieties, and mixtures thereof, and wherein at least one R2, R3, R4, and R5 is a hydrogen atom, wherein the ink is a liquid.
- (b) cyclic sulfones of the formula ##STR136## wherein R is an optional substituent, m is an integer representing the number of substituents, and n is an integer of at least about 4;
-
20. An ink composition which comprises water, a water soluble dye, a first component selected from the group consisting of (a) sulfones of the formula ##STR140## wherein R1 and R2 are independently selected from the group consisting of aliphatic hydrocarbons, substituted aliphatic hydrocarbons, aromatic hydrocarbons, substituted aromatic hydrocarbons, alcohol moieties, alkoxy moieties, and polyalkoxy moieties;
- (b) cyclic sulfones of the formula ##STR141## wherein R is an optional substituent, m is an integer representing the number of substituents, and n is an integer of at least about 4;
(c) cyclic sulfones of the formula ##STR142## wherein R is a substituent selected from the group consisting of alkyl, hydroxy, alcohol, and alkoxy, x is an integer representing the number of substituents, and n is an integer of at least about 2;
(d) cyclic sulfones of the formula ##STR143## wherein R is an optional substituent, z is an integer representing the number of substituents, and m and n are integers independently selected from 0, 1, 2, and 3, wherein the sum of m+n is at least about 1;
(e) polysulfones;
(f) cyclic polysulfones;
(g) sulfonamides; and
(h) mixtures thereof, and a second component which is a diamide, wherein the diamide is selected from the group consisting of malonamide, succinamide, glutaramide, adipamide, and mixtures thereof, wherein the ink is a liquid.
- (b) cyclic sulfones of the formula ##STR141## wherein R is an optional substituent, m is an integer representing the number of substituents, and n is an integer of at least about 4;
-
21. An ink composition which comprises water, a water soluble dye, a first component selected from the group consisting of (a) sulfones of the formula ##STR144## wherein R1 and R2 are independently selected from the group consisting of aliphatic hydrocarbons, substituted aliphatic hydrocarbons, aromatic hydrocarbons, substituted aromatic hydrocarbons, alcohol moieties, alkoxy moieties, and polyalkoxy moieties;
- (b) cyclic sulfones of the formula ##STR145## wherein R is an optional substituent, m is an integer representing the number of substituents, and n is an integer of at least about 4;
(c) cyclic sulfones of the formula ##STR146## wherein R is a substituent selected from the group consisting of alkyl, hydroxyl, alcohol, and alkoxy, x is an integer representing the number of substituents, and n is an integer of at least about 2;
(d) cyclic sulfones of the formula ##STR147## wherein R is an optional substituent, z is an integer representing the number of substituents, and m and n are integers independently selected from 0, 1, 2, and 3, wherein the sum of m+n is at least about 1;
(e) polysulfones;
(f) cyclic polysulfones;
(g) sulfonamides; and
(h) mixtures thereof, and a second component which is an amide of the formula ##STR148## wherein R is a hydrogen atom or an alkyl group and R'"'"' is selected from the group consisting of
space="preserve" listing-type="equation">([--CH.sub.2 ].sub.n --O).sub.m --[CH.sub.2 ].sub.n --OHwherein n is an integer of from 1 to about 4 and m is an integer of from 0 to about 9;
##STR149## wherein a is an integer of from 1 to about 4, b and c are each integers of from 0 to about 4, wherein the sum of a+b+c is no greater than about 6, and m is an integer of from 0 to about 9;
##STR150## wherein a and b are each integers of from 1 to about 4, c and d are each integers of from 0 to about 4, wherein the sum of a+b+c+d is no greater than about 8, and m is an integer of from 0 to about 9;
##STR151## wherein a is an integer of from 1 to about 4, b and c are each integers of from 0 to about 4, wherein the sum of a+b+c is no greater than about 6, and m is an integer of from 0 to about 9;
##STR152## wherein a and b are each integers of from 1 to about 4, c and d are each integers of from 0 to about 4, wherein the sum of a+b+c+d is no greater than about 8, and m is an integer of from 0 to about 9;
##STR153## wherein a is an integer of from 1 to about 4, b and c are each integers of from 0 to about 4, wherein the sum of a+b+c is no greater than about 6, m is an integer of from 0 to about 9, and R1, R2, R3, R4, and R5 are independently selected from the group consisting of hydrogen, alkyl groups, and substituted alkyl groups, wherein the total number of carbon atoms in R1 +R2 +R3 +R4 +R5 is from 1 to about 10;
##STR154## wherein a and b are each integers of from 1 to about 4, c and d are each integers of from 0 to about 4, wherein the sum of a+b+c+d is no greater than about 8, m is an integer of from 0 to about 9, and R1, R2, R3, and R4 are independently selected from the group consisting of hydrogen, alkyl groups, and substituted alkyl groups, wherein the total number of carbon atoms in R1 +R2 +R3 +R4 is from 1 to about 8;
space="preserve" listing-type="equation">([--CH.sub.2 ].sub.l --NH).sub.k --[CH.sub.2 ].sub.l --NH.sub.2wherein l is an integer of from 1 to about 4 and k is an integer of from 0 to about 9;
##STR155## wherein a is an integer of from 1 to about 4, b and c are each integers of from 0 to about 4, wherein the sum of a+b+c is no greater than about 6, and k is an integer of from 0 to about 9;
##STR156## wherein a and b are each integers of from 1 to about 4, c and d are each integers of from 0 to about 4, wherein the sum of a+b+c+d is no greater than about 8, and k is an integer of from 0 to about 9;
##STR157## wherein a is an integer of from 1 to about 4, b and c are each integers of from 0 to about 4, wherein the sum of a+b+c is no greater than about 6, and k is an integer of from 0 to about 9;
##STR158## wherein a and b are each integers of from 1 to about 4, c and d are each integers of from 0 to about 4, wherein the sum of a+b+c+d is no greater than about 8, and k is an integer of from 0 to about 9;
##STR159## wherein a is an integer of from 1 to about 4, b and c are each integers of from 0 to about 4, wherein the sum of a+b+c is no greater than about 6, k is an integer of from 0 to about 9, and R1, R2, R3, R4, and R5 are independently selected from the group consisting of hydrogen, alkyl groups, and substituted alkyl groups, wherein the total number of carbon atoms in R1 +R2 +R3 +R4 +R5 is from 1 to about 10;
##STR160## wherein a and b are each integers of from 1 to about 4, c and d are each integers of from 0 to about 4, wherein the sum of a+b+c+d is no greater than about 10, m is an integer of from 0 to about 9, and R1, R2, R3, and R4 are independently selected from the group consisting of hydrogen, alkyl groups, and substituted alkyl groups, wherein the total number of carbon atoms in R1 +R2 +R3 +R4 is from 1 to about 8;
##STR161## wherein e and f are each integers of from 1 to about 4, the sum of e+f is no greater than about 6, and k is an integer of from 0 to about 9;
##STR162## wherein a and e are each integers of from 1 to about 4, b and c are each integers of from 0 to about 4, wherein the sum of a+b+c+e is no greater than about 8, and k is an integer of from 0 to about 9;
##STR163## wherein a, b, and e are each integers of from 1 to about 4, c and d are each integers of from 0 to about 4, wherein the sum of a+b+c+d+e is no greater than about 10, and k is an integer of from 0 to about 9;
##STR164## wherein a and e are each integers of from 1 to about 4, b and c are each integers of from 0 to about 4, wherein the sum of a+b+c+e is no greater than about 8, and k is an integer of from 0 to about 9;
##STR165## wherein a, b, and e are each integers of from 1 to about 4, c and d are each integers of from 0 to about 4, wherein the sum of a+b+c+d+e is no greater than about 10, and k is an integer of from 0 to about 9;
##STR166## wherein a and e are each integers of from 1 to about 4, b and c are each integers of from 0 to about 4, wherein the sum of a+b+c+e is no greater than about 8, m is an integer of from 0 to about 9, and R1, R2, R3, R4, and R5 are independently selected from the group consisting of hydrogen, alkyl groups, and substituted alkyl groups, wherein the total number of carbon atoms in R1 +R2 +R3 +R4 +R5 is from 1 to about 10; and
##STR167## wherein a, b, and e are each integers of from 1 to about 4, c and d are each integers of from 0 to about 4, wherein the sum of a+b+c+d+e is no greater than about 10, m is an integer of from 0 to about 9, and R1, R2, R3, and R4 are independently selected from the group consisting of hydrogen, alkyl groups, and substituted alkyl groups, wherein the total number of carbon atoms in R1 +R2 +R3 +R4 is from 1 to about 8, wherein the ink is a liquid.
- (b) cyclic sulfones of the formula ##STR145## wherein R is an optional substituent, m is an integer representing the number of substituents, and n is an integer of at least about 4;
-
22. An ink composition which comprises water, a water soluble dye, a first component selected from the group consisting of (a) sulfones of the formula ##STR168## wherein R1 and R2 are independently selected from the group consisting of aliphatic hydrocarbons, substituted aliphatic hydrocarbons, aromatic hydrocarbons, substituted aromatic hydrocarbons, alcohol moieties, alkoxy moieties, and polyalkoxy moieties;
- (b) cyclic sulfones of the formula ##STR169## wherein R is an optional substituent, m is an integer representing the number of substituents, and n is an integer of at least about 4;
(c) cyclic sulfones of the formula ##STR170## wherein R is a substituent selected from the group consisting of alkyl, hydroxy, alcohol, and alkoxy, x is an integer representing the number of substituents, and n is an integer of at least about 2;
(d) cyclic sulfones of the formula ##STR171## wherein R is an optional substituent, z is an integer representing the number of substituents, and m and n are integers independently selected from 0, 1, 2, and 3, wherein the sum of m+n is at least about 1;
(e) polysulfones;
(f) cyclic polysulfones;
(g) sulfonamides; and
(h) mixtures thereof, and a second component which is a material selected from the group consisting of formylethanolamine, acetylethanolamine, propionyl ethanolamine, formyl n-propanolamine, acetyl n-propanolamine, propionyl n-propanolamine, and mixtures thereof, wherein the ink is a liquid.
- (b) cyclic sulfones of the formula ##STR169## wherein R is an optional substituent, m is an integer representing the number of substituents, and n is an integer of at least about 4;
-
23. An ink composition which comprises water, a water soluble dye, a first component selected from the group consisting of sulfones and mixtures thereof, and a second component selected from the group consisting of (a) cyclic amines;
- (b) cyclic polyamines;
(c) cyclic polyamides;
(d) diamides having at least one hydrogen atom bonded to a nitrogen atom;
(e) amides of the formula ##STR172## wherein R is a hydrogen atom or an alkyl group and R'"'"' is selected from the group consisting of alkoxy groups, polyalkoxy groups, imine groups, and polyimine groups; and
(f) mixtures thereof, wherein the ink is a liquid. - View Dependent Claims (24, 25, 26, 27, 28)
- (b) cyclic polyamines;
-
29. An ink composition which comprises water, a water soluble dye, a first component selected from the group consisting of sulfones and mixtures thereof, and a second component selected from the group consisting of (a) cyclic amines of the formula ##STR176## wherein R is an optional substituent, m is an integer representing the number of substituents, and n is an integer of at least about 3;
- (b) cyclic amines of the formula ##STR177## wherein R is an optional substituent, z is an integer representing the number of substituents, and m and n are integers independently selected from 0, 1, 2, and 3, wherein the sum of m+n is at least about 2;
(c) cyclic polyamines of the formula ##STR178## wherein R is an optional substituent, z is an integer representing the number of substituents, p, q, and r are each integers selected from the group consisting of 0, 1, 2, 3, and 4, wherein the sum of p+q+r is at least about 2, s is an integer of from 1 to about 4, and R'"'"' and R" are independently selected from the group consisting of hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, alcohol, alkoxy, and polyalkoxy, wherein at least one of R'"'"' and R" is hydrogen;
(d) cyclic polyamines of the formula ##STR179## wherein R is an optional substituent, z is an integer representing the number of substituents, m, n, and p are each integers selected from the group consisting of 0, 1, 2, 3, and 4, wherein the sum of m+n+p is at least about 2, s is an integer of from 1 to about 4, and R'"'"' and R" are independently selected from the group consisting of hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, alcohol, alkoxy, and polyalkoxy, wherein at least one of R'"'"' and R" is hydrogen; and
(e) mixtures thereof, wherein the ink is a liquid.
- (b) cyclic amines of the formula ##STR177## wherein R is an optional substituent, z is an integer representing the number of substituents, and m and n are integers independently selected from 0, 1, 2, and 3, wherein the sum of m+n is at least about 2;
-
30. An ink composition which comprises water, a water soluble dye, a first component selected from the group consisting of sulfones and mixtures thereof, and a second component selected from the group consisting of pyrrolidine, substituted pyrrolidines, pyrazole, substituted pyrazoles, imidazole, substituted imidazoles, triazoles, substituted triazoles, tetrazoles, substituted tetrazoles, piperazines, substituted piperazines, and mixtures thereof, wherein the ink is a liquid.
-
31. An ink composition which comprises water, a water soluble dye, a first component selected from the group consisting of sulfones and mixtures thereof, and a second component selected from the group consisting of 2-azacyclooctanone, substituted 2-azacyclooctanones, 2-azacyclononanone, substituted 2-azacyclononanones, and mixtures thereof, wherein the ink is a liquid.
-
32. An ink composition which comprises water, a water soluble dye, a first component selected from the group consisting of sulfones and mixtures thereof, and a second component which is a diamide, wherein the diamide is of the formula ##STR180## wherein R1 is selected from the group consisting of alkylene groups, substituted alkylene groups, arylene groups, substituted arylene groups, alcohol moieties, alkoxy moieties, polyalkoxy moieties, and mixtures thereif, wherein R2, R3, R4, and R5 are independently selected from the group consisting of hydrogen, alkyl groups, substituted alkyl groups, aryl groups, substituted aryl groups, alcohol moieties, alkoxy moieties, polyalkoxy moieties, and mixtures thereof, and wherein at least one of R2, R3, R4, and R5 is a hydrogen atom, wherein the ink is a liquid.
-
33. An ink composition which comprises water, a water soluble dye, a first component selected from the group consisting of sulfones and mixtures thereof, and a second component which is a diamide, wherein the diamide is selected from the group consisting of malonamide, succinamide, glutaramide, adipamide, and mixtures thereof, wherein the ink is a liquid.
- 34. An ink composition which comprises water, a water soluble dye, a first component selected from the group consisting of sulfones and mixtures thereof, and a second component which is an amide of the formula ##STR181## wherein R is a hydrogen atom or an alkyl group and R'"'"' is selected from the group consisting of
- space="preserve" listing-type="equation">([--CH.sub.2 ].sub.n --O).sub.m --[CH.sub.2 ].sub.n --OH
wherein n is an integer of from 1 to about 4 and m is an integer of from 0 to about 9;
##STR182## wherein a is an integer of from 1 to about 4, b and c are each integers of from 0 to about 4, wherein the sum of a+b+c is no greater than about 6, and m is an integer of from 0 to about 9;
##STR183## wherein a and b are each integers of from 1 to about 4, c and d are each integers of from 0 to about 4, wherein the sum of a+b+c+d is no greater than about 8, and m is an integer of from 0 to about 9;
##STR184## wherein a is an integer of from 1 to about 4, b and c are each integers of from 0 to about 4, wherein the sum of a+b+c is no greater than about 6, and m is an integer of from 0 to about 9;
##STR185## wherein a and b are each integers of from 1 to about 4, c and d are each integers of from 0 to about 4, wherein the sum of a+b+c+d is no greater than about 8, and m is an integer of from 0 to about 9;
##STR186## wherein a is an integer of from 1 to about 4, b and c are each integers of from 0 to about 4, wherein the sum of a+b+c is no greater than about 6, m is an integer of from 0 to about 9, and R1, R2, R3, R4, and R5 are independently selected from the group consisting of hydrogen, alkyl groups, and substituted alkyl groups, wherein the total number of carbon atoms in R1 +R2 +R3 +R4 +R5 is from 1 to about 10;
##STR187## wherein a and b are each integers of from 1 to about 4, c and d are each integers of from 0 to about 4, wherein the sum of a+b+c+d is no greater than about 8, m is an integer of from 0 to about 9, and R1, R2, R3, and R4 are independently selected from the group consisting of hydrogen, alkyl groups, and substituted alkyl groups, wherein the total number of carbon atoms in R1 +R2 +R3 +R4 is from 1 to about 8;
space="preserve" listing-type="equation">([--CH.sub.2 ].sub.l --NH).sub.k --[CH.sub.2 ].sub.l --NH.sub.2wherein l is an integer of from 1 to about 4 and k is an integer of from 0 to about 9;
##STR188## wherein a is an integer of from 1 to about 4, b and c are each integers of from 0 to about 4, wherein the sum of a+b+c is no greater than about 6, and k is an integer of from 0 to about 9;
##STR189## wherein a and b are each integers of from 1 to about 4, c and d are each integers of from 0 to about 4, wherein the sum of a+b+c+d is no greater than about 8, and k is an integer of from 0 to about 9;
##STR190## wherein a is an integer of from 1 to about 4, b and c are each integers of from 0 to about 4, wherein the sum of a+b+c is no greater than about 6, and k is an integer of from 0 to about 9;
##STR191## wherein a and b are each integers of from 1 to about 4, c and d are each integers of from 0 to about 4, wherein the sum of a+b+c+d is no greater than about 8, and k is an integer of from 0 to about 9;
##STR192## wherein a is an integer of from 1 to about 4, b and c are each integers of from 0 to about 4, wherein the sum of a+b+c is no greater than about 6, k is an integer of from 0 to about 9, and R1, R2, R3, R4, and R5 are independently selected from the group consisting of hydrogen, alkyl groups, and substituted alkyl groups, wherein the total number of carbon atoms in R1 +R2 +R3 +R4 +R5 is from 1 to about 10;
##STR193## wherein a and b are each integers of from 1 to about 4, c and d are each integers of from 0 to about 4, wherein the sum of a+b+c+d is no greater than about 10, m is an integer of from 0 to about 9, and R1, R2, R3, and R4 are independently selected from the group consisting of hydrogen, alkyl groups, and substituted alkyl groups, wherein the total number of carbon atoms in R1 +R2 +R3 +R4 is from 1 to about 8;
##STR194## wherein e and f are each integers of from 1 to about 4, the sum of e+f is no greater than about 6, and k is an integer of from 0 to about 9;
##STR195## wherein a and e are each integers of from 1 to about 4, b and c are each integers of from 0 to about 4, wherein the sum of a+b+c+e is no greater than about 8, and k is an integer of from 0 to about 9;
##STR196## wherein a, b, and e are each integers of from 1 to about 4, c and d are each integers of from 0 to about 4, wherein the sum of a+b+c+d+e is no greater than about 10, and k is an integer of from 0 to about 9;
##STR197## wherein a and e are each integers of from 1 to about 4, b and c are each integers of from 0 to about 4, wherein the sum of a+b+c+e is no greater than about 8, and k is an integer of from 0 to about 9;
##STR198## wherein a, b, and e are each integers of from 1 to about 4, c and d are each integers of from 0 to about 4, wherein the sum of a+b+c+d+e is no greater than about 10, and k is an integer of from 0 to about 9;
##STR199## wherein a and e are each integers of from 1 to about 4, b and c are each integers of from 0 to about 4, wherein the sum of a+b+c+e is no greater than about 8, m is an integer of from 0 to about 9, and R1, R2, R3, R4, and R5 are independently selected from the group consisting of hydrogen, alkyl groups, and substituted alkyl groups, wherein the total number of carbon atoms in R1 +R2 +R3 +R4 +R5 is from 1 to about 10; and
##STR200## wherein a, b, and e are each integers of from 1 to about 4, c and d are each integers of from 0 to about 4, wherein the sum of a+b+c+d+e is no greater than about 10, m is an integer of from 0 to about 9, and R1, R2, R3, and R4 are independently selected from the group consisting of hydrogen, alkyl groups, and substituted alkyl groups, wherein the total number of carbon atoms in R1 +R2 +R3 +R4 is from 1 to about 8, and wherein the ink is a liquid.
-
35. An ink composition which comprises water, a water soluble dye, a first component selected from the group consisting of sulfones and mixtures thereof, and a second component which is a material selected from the group consisting of formylethanolamine, acetylethanolamine, propionyl ethanolamine, formyl n-propanolamine, acetyl n-propanolamine, propionyl n-propanolamine, and mixtures thereof, wherein the ink is a liquid.
-
36. A thermal ink jet printing process which comprises incorporating into a thermal ink jet printing apparatus an ink composition which comprises water, a water soluble dye, a first component selected from the group consisting of (a) sulfones of the formula ##STR201## wherein R1 and R2 are independently selected from the group consisting of aliphatic hydrocarbons, substituted aliphatic hydrocarbons, aromatic hydrocarbons, substituted aromatic hydrocarbons, alcohol moieties, alkoxy moieties, and polyalkoxy moieties;
- (b) cyclic sulfones of the formula ##STR202## wherein R is an optional substituent, m is an integer representing the number of substituents, and n is an integer of at least about 4;
(c) cyclic sulfones of the formula ##STR203## wherein R is a substituent selected from the group consisting of alkyl, hydroxy, alcohol, and alkoxy, x is an integer representing the number of substituents, and n is an integer of at least about 2;
(d) cyclic sulfones of the formula ##STR204## wherein R is an optional substituent, z is an integer representing the number of substituents, and m and n are integers independently selected from 0, 1, 2, and 3, wherein the sum of m+n is at least about 1;
(e) polysulfones;
(f) cyclic polysulfones;
(g) sulfonamides; and
(h) mixtures thereof, and a second component selected from the group consisting of (a) cyclic amines having at least one hydrogen atom bonded to a nitrogen atom;
(b) cyclic amides having at least one hydrogen atom bonded to a nitrogen atom;
(c) diamides having at least one hydrogen atom bonded to a nitrogen atom;
(d) amides of the formula ##STR205## wherein R is a hydrogen atom or an alkyl group and R'"'"' is selected from the group consisting of alkoxy groups, polyalkoxy groups, imine groups, and polyimine groups; and
(e) mixtures thereof, wherein the ink is a liquid, and causing droplets of the ink composition to be ejected in an imagewise pattern onto a substrate by selectively heating the ink in the nozzles in an imagewise pattern.
- (b) cyclic sulfones of the formula ##STR202## wherein R is an optional substituent, m is an integer representing the number of substituents, and n is an integer of at least about 4;
-
37. A thermal ink jet printing process which comprises incorporating into a thermal ink jet printing apparatus an ink composition which comprises water, a water soluble dye, a first component selected from the group consisting of sulfones and mixtures thereof, and a second component selected from the group consisting of (a) cyclic amines;
- (b) cyclic polyamines;
(c) cyclic amides of the formula ##STR206## wherein R is an optional substituent, m is an integer representing the number of substituents, and n is an integer of at least about 4;
(d) cyclic amides of the formula ##STR207## wherein R is a substituent selected from the group consisting of alkyl, alcohol, hydroxy, and alkoxy, m is an integer representing the number of substituents, and n is an integer of at least about 3;
(e) cyclic amides of the formula ##STR208## wherein R is an optional substituent, z is an integer representing the number of substituents, p and q are each integers selected from the group consisting of 0, 1, 2, 3, and 4, wherein the sum of p+q is at least about 1, and s is an integer of from 1 to about 4;
(f) cyclic amides of the formula ##STR209## wherein R is an optional substituent, z is an integer representing the number of substituents, p and q are each integers selected from the group consisting of 0, 1, 2, 3, and 4, wherein the sum of p+q is at least about 1, s is an integer of from 1 to about 4, and R'"'"' and R" are independently selected from the group consisting of hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, alcohol, alkoxy, and polyalkoxy, wherein at least one of R'"'"' and R" is hydrogen;
(g) cyclic polyamides;
(h) diamides having at least one hydrogen atom bonded to a nitrogen atom;
(i) amides of the formula ##STR210## wherein R is a hydrogen atom or an alkyl group and R'"'"' is selected from the group consisting of alkoxy groups, polyalkoxy groups, imine groups, and polyimine groups; and
(j) mixtures thereof, wherein the ink is a liquid, and causing droplets of the ink composition to be ejected in an imagewise pattern onto a substrate by selectively heating the ink in the nozzles in an imagewise pattern.
- (b) cyclic polyamines;
Specification