Member coated with ceramic material and method of manufacturing the same

• US 5,300,951 A
• Filed: 05/18/1993
• Issued: 04/05/1994
• Est. Priority Date: 11/28/1985
• Status: Expired due to Fees

• Current Assignee: Kabushiki Kaisha Toshiba (Toshiba Corporation)
• Original Assignee: Kabushiki Kaisha Toshiba (Toshiba Corporation)
• Inventors: Yamazaki, Mutsuki
• Primary Examiner(s): TURNER, ARCHENE A
• Application Number:
  US08/064,749
• Time in Patent Office: 322 Days
• Field of Search: 346/145, 346/108, 346/1.1, 428/446, 428/698, 428/472, 428/408, 428/457, 428/697, 428/701, 428/702, 428/704, 428/469, 427/576, 427/577, 427/578, 427/579, 427/245, 427/255.1, 427/255.2, 427/255.3
• US Class Current: 347/263
• CPC Class Codes: C23C 16/0272 Deposition of sub-layers, e.g. to promote the adhesion of the main coating
• CPC Class Codes: F16C 33/043 Sliding surface consisting mainly of ceramics, cermets or hard carbon, e.g. diamond like carbon [DLC]
• CPC Class Codes: F16J 15/3496 use of special materials

Abstract

A support containing iron as a major constituent is plasma-treated in an Ar-gas atmosphere containing carbon gas, to form a region on the main surface of the support. This region contains carbon at a high concentration. A plasma is generated in an Si- and N-containing gas atmosphere, to form an SiN ceramic layer on the main surface. The ceramic layer is placed contact with a rich carbon region on the surface of the support. The ceramic layer is firmly adhered to the support, by means of this region.

Claims

1. In a laser printer, the combination comprising a laser scanner and a sliding shaft member for said laser scanner which slidingly rotates at high speed and comprises (a) an iron-based cylindrical shaft having a main surface with a region containing at least one element selected from the group consisting of oxygen and nitrogen at a concentration higher than that of another region in said main surface, said region being formed by treating the main surface with a plasma of a gas containing at least one element selected from the group consistent of oxygen and nitrogen, and (b) a Si atoms-containing layer formed on said main surface of said cylindrical shaft by a plasma chemical vapor deposition using Si atoms-containing raw gas, said Si atoms-containing layer formed on said main surface of said cylindrical shaft comprising a material selected from the group consisting of silicon nitride, silicon carbonitride and silicon carboxide, and containing at least one element selected from the group consisting of hydrogen and halogen.

2. A laser printer according to claim 1, wherein said iron-based cylindrical shaft is formed of iron containing at least one additive selected from the group consisting of nickel, chromium, aluminum, manganese, magnesium and vanadium.

3. A laser printer as recited in claim 1 wherein said region of said main surface of said cylindrical shaft contains oxygen at a concentration higher than that of another region in said main surface.

4. A laser printer as recited in claim 1 wherein said region of said main surface of said cylindrical shaft contains nitrogen at a concentration higher than that of another region in said main surface.

5. A method of inhibiting wear in a sliding shaft member of a laser scanner, which slidingly rotates at high speed, in a laser printer, which comprises the steps of:

(a) exposing a main surface of an iron-based cylindrical shaft member with a plasma in an atmosphere containing at least one element selected from the group consisting of oxygen and nitrogen to form a region containing at least one element selected from the group consisting of oxygen and nitrogen at a concentration higher than that of another region in said main surface; and

(b) forming a Si atoms-containing layer on said main surface of said cylindrical sliding shaft member by a plasma chemical vapor deposition using Si atoms-containing raw gas, said layer comprising a material selected from the group consisting of silicon nitride, silicon carbonitride and silicon carboxide, and containing at least one element selected from the group consisting of hydrogen and halogen, wherein said cylindrical sliding shaft member is preheated before step (a).

6. A method according to claim 5, wherein said cylindrical sliding shaft member is preheated at a temperature of 150°

to 300°

C.

7. A method of inhibiting wear in a sliding shaft member of a laser scanner in a laser printer, which comprises the steps of:

(a) carbonizing a surface of said sliding shaft member by exposing the surface of said shaft member to RF plasma in an atmosphere containing CF₄ or CH₄ at a reduced pressure; and

(b) forming a ceramic layer made of a material selected from the group consisting of silicon nitride, silicon carbide, silicon carbonitride and silicon carboxide, on said carbonized surface of said shaft member by plasma chemical vapor deposition in an atmosphere containing SiH₄ or Si₂ H₆, and one member selected from the group consisting of N₂, CH₄ and O₂, wherein said cylindrical sliding shaft member is preheated before step (a).

8. A method according to claim 7, wherein said cylindrical sliding shaft member is preheated at a temperature of 150°

to 300°

C.