Trivalent chromium conversion coatings for aluminum

• US 5,304,257 A
• Filed: 09/27/1993
• Issued: 04/19/1994
• Est. Priority Date: 09/27/1993
• Status: Expired due to Fees

• Current Assignee: the united states of america as represented by the secretary of the navy
• Original Assignee: the united states of america as represented by the secretary of the navy
• Inventors: Agarawala, Vinod S., Pearlstein, Fred
• Primary Examiner(s): Silverstein, Sam
• Application Number:
  US08/126,869
• Time in Patent Office: 204 Days
• Field of Search: 148/265, 148/267, 148/276, 148/275
• US Class Current: 148/265
• CPC Class Codes: C23C 22/34 containing fluorides or complex fluorides
• CPC Class Codes: C23C 22/83 Chemical after-treatment
• CPC Class Codes: C23C 2222/10 Use of solutions containing trivalent chromium but free of hexavalent chromium
• CPC Class Codes: C25D 11/246 for sealing layers

Abstract

Corrosion resistant coatings are formed on aluminum by immersion in aqueousolutions containing chromic salts, a fluoride ion from compounds such as a fluosilicate with an alkali added near or slightly beyond the precipitation of the insoluble basic compounds. Trivalent chromium films formed on the aluminum surface when tested in 5% NaCl salt spray chamber showed corrosion resistance in excess of 96 hours. After a post-treatment with peroxide or permanganate solutions, the corrosion resistance for the aluminum substrates exceeded 168 hours. Trivalent chromium coated aluminum serves as an effective base for paint primers. Anodized aluminums were also afforded excellent corrosion resistance, after being treated in dilute/basic chromic sulfate solutions and post-treated with peroxide.

Claims

1. A process for preparing a corrosion-resistant trivalent chromium coating on aluminum and aluminum-alloy substrates which comprises treating said substrates with an acidic aqueous solution free of hexavalent chromium and contains from about 0.2 to 3.0 grams per liter of a water soluble trivalent chromium compound, from about 0.05 to 1.5 grams per liter of a water soluble fluoride compound and a sufficient amount of an alkaline reagent to maintain the aqueous solution at a pH ranging from about 4.0 to 5.5 to form the trivalent-chromium coating on said aluminum substrates.

2. The process of claim 1 wherein the trivalent chromium coating on the substrate is post-treated with an effective amount of an oxidizing agent to convert less than about 2.0 percent of the trivalent chromium in the coating to hexavalent chromium.

3. The process of claim 1 wherein the trivalent chromium salt is chromium sulfate and the fluoride compound is an alkali metal fluosilicate.

4. The process of claim 2 wherein the oxidizing agent is a peroxide.

5. The process of claim 4 wherein the oxidizing agent is a 0.2 to 40 percent by volume aqueous solution of 30% hydrogen peroxide.

6. The process of claim 1 wherein the substrate is an aluminum alloy.

7. The process of claim 1 wherein the substrates are treated in the acidic aqueous solution at ambient temperatures.

8. The process of claim 1 wherein the alkaline reagent is an alkali metal hydroxide.