Method for removing coatings from compact discs

• US 5,306,349 A
• Filed: 11/23/1992
• Issued: 04/26/1994
• Est. Priority Date: 11/23/1992
• Status: Expired due to Term

• Current Assignee: Sony Music Entertainment Incorporated (Sony Group Corp.)
• Original Assignee: Sony Music Entertainment Incorporated (Sony Group Corp.)
• Inventors: Nee, Han H.
• Primary Examiner(s): Breneman, R. Bruce
• Assistant Examiner(s): Chaudhry, Saeed T.
• Application Number:
  US07/980,582
• Time in Patent Office: 519 Days
• Field of Search: 134/1, 134/2, 134/3, 134/10, 134/26, 134/29, 134/32, 134/33, 134/38, 252/156, 252/525, 252/526, 252/535, 252/544, 252/545, 252/DIG. 11
• US Class Current: 134/1
• CPC Class Codes: B29B 17/02 Separating plastics from other materials
• CPC Class Codes: B29B 2017/0293 Dissolving the materials in gases or liquids
• CPC Class Codes: B29B 2017/0296 Dissolving the materials in aqueous alkaline solutions, e.g. NaOH or KOH
• CPC Class Codes: B29K 2069/00 Use of PC, i.e. polycarbonates or derivatives thereof, as moulding material
• CPC Class Codes: B29K 2705/02 Aluminium
• CPC Class Codes: B29L 2009/005 coated
• CPC Class Codes: B29L 2017/005 CD''s, DVD''s
• CPC Class Codes: C22B 21/0007 Preliminary treatment of ores or scrap or any other metal source Bayer processes C01F
• CPC Class Codes: G11B 7/241 characterised by the selection of the material
• CPC Class Codes: G11B 7/2534 polycarbonates [PC]
• CPC Class Codes: G11B 7/2542 consisting essentially of organic resins
• CPC Class Codes: G11B 7/2585 based on aluminium
• CPC Class Codes: Y02P 10/20 Recycling
• CPC Class Codes: Y02W 30/62 Plastics recycling; Rubber recycling

Abstract

A method for removing the lacquer and aluminum coatings from the polycarbonate substrate of scrap compact discs so as to reclaim the polycarbonate includes the steps of immersing the discs in a an alkaline solution, heating the solution to a predetermined temperature and mechanically agitating the immersed discs by applying ultrasonic energy to the solution at a sufficient energy density and for a sufficient time to dissolve the lacquer and the aluminum into the solution. The solution containing the dissolved lacquer and aluminum is decanted from the stripped polycarbonate discs, the discs are washed with water to remove remanent alkaline solution, and then dried.

Claims

1. A method for removing the lacquer and aluminum coatings from the polycarbonate substrate or a compact disc, comprising the steps of:

(a) immersing a batch of compact discs comprising compact discs coated with a solvent based lacquer coating and/or compact discs coated with a UV-cured acrylic lacquer coating in an alkaline solution at a pH of about 13 or more;

(b) heating said alkaline solution;

(c) mechanically agitating said immersed discs by applying to said heated alkaline solution ultrasonic energy having a frequency in the range from about 20 to about 40 Khz with an energy density in the range from about 10 to about 200 watts per liter, the alkaline solution being at a sufficient concentration and temperature and in contact with the agitated discs for a time sufficient to dissolve the lacquer and aluminum coatings into solution and to leave behind stripped polycarbonate discs;

(d) washing the stripped polycarbonate discs to remove remanent alkaline solution therefrom; and

(e) drying the washed polycarbonate discs.

2. A method as defined in claim 1, wherein said alkaline solution is contained in a tank, wherein said batch of discs is contained in a rotatable perforate barrel which is immersed in the alkaline solution, and wherein said barrel is rotated at a speed in the range from about 10 rpm to about 200 rpm.

3. A method as defined in claim 2, wherein said barrel is rotated at a speed in the range from about 60 rpm to about 100 rpm.

4. A method as defined in claim 1, wherein said alkaline solution is an aqueous solution of an alkaline salt or a base, a chelating additive and a wetting agent.

5. A method as defined in claim 1, wherein said alkaline solution is an aqueous solution of:

a member selected from the group consisting of alkali metal phosphate, alkali metal hydroxide and alkali metal carbonate wherein the metal is selected from the group consisting of sodium and potassium;

a chelating additive selected from the alkali metal salts of citric acid, ethylenediamine tetraacetic acid (EDTA), gluconic acid and nitrilotriacetic acid; and

a wetting agent selected from the group consisting of sodium alkylbenzene sulfonate, naphthalene sulfonate, fatty acid esters and sodium lauryl sulfate.

6. A method as defined in claim 5, wherein said alkaline solution said member has a concentration in the range from about 30 to about 500 gm/liter, said chelating additive has a concentration in the range from about 0.5 to about 100 gm/liter and said wetting agent has a concentration in the range from about 0.5 to about 10 gm/liter.

7. A method as defined in claim 5, wherein in said alkaline solution said member has a concentration in the range from 60 to 200 gm/liter, said chelating additive has a concentration in the range from 5 to 50 gm/liter and said wetting agent has a concentration in the range from 1.0 to 5 gm/liter.

8. A method as defined in claim 7, wherein said alkaline solution is contained in an ultrasonic tank,

wherein said batch of discs is placed in a perforate cylindrical barrel which is immersed in the alkaline solution and is rotated in said solution at a speed in the range from 60 to 100 rpm.

9. A method as defined in claim 8, wherein the stripped polycarbonate discs are washed in water having a temperature in the range from 100°

to 210°

F., and

wherein the washed polycarbonate discs are air dried at a temperature in the range from 100°

to 210°

F.

10. A method as defined in claim 5, wherein said alkaline solution is contained in a tank,

wherein said batch of discs is contained in a perforate cylindrical tank which is immersed and rotated in said alkaline solution at a speed in the range from about 60 to 100 rpm.