Coextruded weatherable film structures and laminates

• US 5,306,548 A
• Filed: 05/20/1992
• Issued: 04/26/1994
• Est. Priority Date: 05/20/1992
• Status: Expired due to Fees

• Current Assignee: Rensselaer Polytechnic Institute
• Original Assignee: The Dow Chemical Company (Dow, Inc.)
• Inventors: Zabrocki, Vincent S., Kelch, Robert H.
• Primary Examiner(s): Sluby, P. C.
• Application Number:
  US07/886,655
• Time in Patent Office: 706 Days
• Field of Search: 428/515, 428/215, 428/220, 428/408, 428/423.1, 428/424.6, 428/424.7, 428/424.8, 428/483, 428/517, 428/519, 428/521, 264/176.1
• US Class Current: 428/215
• CPC Class Codes: B32B 2307/712 Weather resistant
• CPC Class Codes: B32B 27/08 of synthetic resin
• CPC Class Codes: B32B 27/18 characterised by the use of special additives
• CPC Class Codes: B32B 27/20 using fillers, pigments, thixotroping agents
• CPC Class Codes: B32B 27/302 comprising aromatic vinyl (co)polymers, e.g. styrenic (co)polymers
• CPC Class Codes: B32B 27/304 comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
• CPC Class Codes: B32B 27/322 comprising halogenated polyolefins, e.g. PTFE
• CPC Class Codes: B32B 27/40 comprising polyurethanes
• CPC Class Codes: B32B 7/12 using interposed adhesives or interposed materials with bonding properties
• CPC Class Codes: Y10T 428/24967 Absolute thicknesses specified
• CPC Class Codes: Y10T 428/30 Self-sustaining carbon mass or layer with impregnant or other layer
• CPC Class Codes: Y10T 428/31551 Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
• CPC Class Codes: Y10T 428/3158 Halide monomer type [polyvinyl chloride, etc.]
• CPC Class Codes: Y10T 428/31583 Nitrile monomer type [polyacrylonitrile, etc.]
• CPC Class Codes: Y10T 428/31587 Hydrocarbon polymer [polyethylene, polybutadiene, etc.]
• CPC Class Codes: Y10T 428/31797 Next to addition polymer from unsaturated monomers
• CPC Class Codes: Y10T 428/31917 Next to polyene polymer
• CPC Class Codes: Y10T 428/31924 Including polyene monomers
• CPC Class Codes: Y10T 428/31931 Polyene monomer-containing

Abstract

A coextruded weatherable film for lamination to an underlying nonweatherable substrate, including, for example, a two-layer film structure including an outer layer of a weatherable polymer that provides weather resistance such as ethylene/propylene/nonconjugated diene-reinforced styrene/acrylonitrile copolymer (AES) or butyl acrylate-reinforced styrene/acrylonitrile copolymer (ASA), coextruded over a thermoplastic underlying layer, for example, of a carbon black pigmented, UV stabilized polymer such as chlorinated polyethylene that provides UV protection for an underlying substrate such as vinyl siding or polymer layers.

Claims

1. A coextruded multilayer weatherable film product adapted to be adhered as a weatherable surface coating onto a substrate in a separate process operation, comprising:

at least a first thermoplastic surface layer of a weatherable polymer comprising (a) AES, ASA, SAN or mixtures thereof or (b) any of the polymers of (a) blended with PVC, CPE, aliphatic polyurethanes or saturated styrenic block copolymers;

said first layer having a 1% secant modulus of greater than about 100,000 psi and said first layer having a thickness of about 20 mils or less; and

at least a second thermoplastic layer underlying the weatherable layer, said second layer being adjacent to and adhered to said first layer and said second layer adapted to be adhered to the substrate in a subsequent operation;

said second layer having a 1% secant modulus of less than about 200,000 psi and said second layer having a thickness of about 20 mils or less;

wherein the total thickness of the coextruded weatherable film is less than 25 mils.

2. The film of claim 1 wherein the second layer comprises CPE, styrenic block polymer, copolyamide adhesives, copolyester adhesives, PVC, polyurethanes and mixtures thereof.

3. The film structure of claim 2 wherein the second layer is a styrenic block copolymer.

4. The film of claim 2 wherein the second layer is a chlorinated polyethylene.

5. The film of claim 1 wherein the weatherable layer contains an ultraviolet light stabilizer.

6. The film of claim 5 wherein the ultraviolet stabilizer is from about 0.05 to about 3 weight percent.

7. The film of claim 1 wherein the first and/or second layer contains pigment.

8. The film of claim 7 wherein the pigment of the second layer is carbon black.

9. The film of claim 8 wherein the carbon black is from about 0.5 to about 5 weight percent.

10. A laminated structure comprising a substrate having adhered thereto a coextruded film structure of claim 1.

11. The laminated structure of claim 10 wherein the substrate is polymeric.

12. A process for producing a coextruded multilayer film product adapted to be adhered as a weatherable surface coating onto a substrate in a separate process operation, comprising:

coextruding at least a first thermoplastic surface layer of a weatherable polymer with at least a first underlying layer adjacent to the weatherable polymer layer, said first surface layer comprising (a) AES, ASA, SAN or mixtures thereof of (b) any of the polymers of (a) blended with PVC, CPE, aliphatic polyurethanes or saturated styrenic block copolymers, said first surface layer having a 1% secant modulus of greater than about 100,000 psi, said first surface layer having a thickness of about 20 mils or less, said first underlying layer intimately adherable to and compatible with the weatherable polymer layer, said first underlying layer having a 1% secant modulus of less than about 200,000 psi, said first underlying layer having a thickness of about 20 mils or less; and

said first underlying layer adapted to be intimately adherable to and compatible with a substrate.