Method of surface hardening cobalt-chromium based alloys for orthopedic implant devices

• US 5,308,412 A
• Filed: 03/15/1993
• Issued: 05/03/1994
• Est. Priority Date: 03/15/1993
• Status: Expired due to Term

• Current Assignee: Zimmer Technology Incorporated (Zimmer Biomet Holdings, Inc.)
• Original Assignee: Zimmer Incorporated (Zimmer Biomet Holdings, Inc.)
• Inventors: Ottersberg, Walter H., Shetty, H. Ravindranath
• Primary Examiner(s): Roy, Upendra
• Application Number:
  US08/030,912
• Time in Patent Office: 414 Days
• Field of Search: 420/436, 148/238, 623/16, 623/18, 623/23
• US Class Current: 148/238
• CPC Class Codes: A61F 2/30767 Special external or bone-contacting surface, e.g. coating for improving bone ingrowth
• CPC Class Codes: A61F 2/3094 Designing or manufacturing processes
• CPC Class Codes: A61F 2/36 Femoral heads ; Femoral endoprostheses
• CPC Class Codes: A61F 2/3609 Femoral heads or necks; Connections of endoprosthetic heads or necks to endoprosthetic femoral shafts A61F2/3601 takes precedence
• CPC Class Codes: A61F 2/367 Proximal or metaphyseal parts of shafts trochanteric devices connected to said proximal parts A61F2/30739
• CPC Class Codes: A61F 2/3676 Distal or diaphyseal parts of shafts
• CPC Class Codes: A61F 2002/30322 differing in surface structures
• CPC Class Codes: A61F 2002/30685 Means for reducing or preventing the generation of wear particulates
• CPC Class Codes: A61F 2002/3082 Grooves
• CPC Class Codes: A61F 2002/30922 Hardened surfaces
• CPC Class Codes: A61F 2002/30934 Special articulating surfaces
• CPC Class Codes: A61F 2250/0026 differing in surface structures
• CPC Class Codes: A61F 2310/00029 Cobalt-based alloys, e.g. Co-Cr alloys or Vitallium
• CPC Class Codes: A61F 2310/00622 Coating made of chromium oxide or hydroxides
• CPC Class Codes: A61F 2310/00754 Coating made of chromium carbide
• CPC Class Codes: A61F 2310/00886 Coating made of chromium nitride
• CPC Class Codes: A61L 27/045 Cobalt or cobalt alloys
• CPC Class Codes: C23C 8/28 more than one element being applied in one step
• CPC Class Codes: C23C 8/34 more than one element being applied in more than one step
• CPC Class Codes: Y10S 623/923 Bone

Abstract

A method of surface hardening cobalt-chromium based orthopedic implant devices, and a cobalt-chromium orthopedic implant device prepared by the disclosed method. An orthopedic implant device made of a cobalt-chromium or cobalt-chromium-molybdenum alloy, such as ASTM F-75 or ASTM F-799 is exposed to molecular nitrogen gas or ionized nitrogen at a process temperature and for a process time duration sufficient to enhance surface hardness and wear resistance properties, without the formation of a measurable nitrogen layer that tends to increase surface roughness and brittleness and diminish wear resistance properties. The process temperature is in the range of 500° F. to 2400° F., preferably about 1400° F., and the process time duration at the preferred process temperature is approximately 48 hours. The hardened surface of the cobalt-chromium-molybdenum implant occurs primarily due to nitride formation and solid solution hardening of the cobalt-chromium-molybdenum with nitrogen and oxygen, by dissolution.

Claims

1. A method of manufacturing a cobalt-chromium orthopedic implant device having enhanced wear resistance properties, comprising the steps of:

providing a cobalt-chromium substrate in the form of an orthopedic implant device; and

hardening the surface of the cobalt-chromium substrate by exposing the cobalt-chromium substrate to an atmosphere of non-diluted molecular nitrogen gas at a process temperature within the range of 500°

F. to 2400°

F. for a process time duration sufficient to achieve a hardened outer surface layer and a hardened diffusion layer characterized primarily by solid solution hardening of the surface of the cobalt-chromium substrate by dissolution of nitrogen and oxygen in the cobalt-chromium substrate.

2. The method of claim 1 in which the orthopedic implant device is a load bearing member.

3. The method of claim 1 in which the orthopedic implant device makes articulating contact with one of a polymer, a ceramic or a metal.

4. The method of claim 1 in which said hardened surface region exhibits a peak nitrogen concentration within the range of about 5 atomic percent to about 50 atomic percent at a depth between 100 and 5000Å

below the surface of the outer substrate.

5. The method of claim 1 in which said hardened surface region includes a hardened surface layer limited in thickness to a depth of approximately 100 micrometers and a hardened diffusion region underneath said hardened surface layer, said surface layer comprising chromium nitride, chromium oxide, and chromium carbide, and said hardened diffusion region comprising a solid solution of nitrogen, oxygen, and carbon in said cobalt-chromium substrate.

6. The method of claim 3 in which the polymer is ultrahigh molecular weight polyethylene (UHMWPE).

7. A method of manufacturing a cobalt-chromium orthopedic implant device having enhanced surface hardness and wear resistance properties, comprising the steps of:

providing a cobalt-chromium substrate in the form of an orthopedic implant device; and

exposing the cobalt-chromium substrate to an atmosphere of molecular nitrogen gas at a process temperature and for a process time duration sufficient to cause nitrogen dissolution in the cobalt-chromium substrate without a substantial quantity of formation of a substantial quantity of chromium nitride on the surface of said the cobalt-chromium substrate, thereby enhancing the surface hardness and wear resistance properties of the cobalt-chromium substrate by substantially avoiding increased surface roughness and brittleness that would diminish the wear resistance properties.

8. The method of claim 7 in which said cobalt-chromium substrate comprises a cobalt-chromium-molybdenum alloy.

9. The method of claim 7 in which said cobalt-chromium alloy is one of ASTM F-75 and Modified ASTM F-75.

10. The method of claim 7 in which the process temperature is in the range of 500°

F. to 2400°

F.

11. The method of claim 7 in which the process time is approximately forty-eight hours.

12. The method of claim 7 in which the process temperature is approximately 1400°

F. and the process time is approximately forty-eight hours.

13. The method of claim 7 in which said atmosphere of molecular nitrogen gas is provided at a process pressure within the range of 1 psig to 2 psig.

14. The method of claim 9 in which the cobalt-chromium alloy is ASTM F-799.

15. The method of claim 10 in which the process temperature is approximately 1400°

F.

16. A method of increasing the surface hardness and wear resistance properties of an orthopedic implant device that is fabricated from a cobalt-chromium material, comprising the steps of:

providing a substrate of cobalt-chromium material in the form of an orthopedic implant device; and

exposing the substrate to an atmosphere of non-diluted molecular nitrogen gas at a process temperature and for a process time duration sufficient to enhance both surface hardness and wear resistance properties of said substrate by nitrogen dissolution in the substrate by substantially avoiding increased surface roughness and brittleness and thereby diminishing wear resistance properties by the formation of a substantial quantity of chromium nitride on the surface of the substrate.

17. The method of claim 16 including the step of polishing the surface hardened implant device sufficiently to provide an ultrahigh finish to the device, thereby substantially improving the wear resistance of the implant.

18. The method of claim 16 in which the process temperature is in the range of 500°

F. to 2400°

F.

19. A method of manufacturing a cobalt-chromium orthopedic implant device having enhanced wear resistance properties, comprising the steps of:

providing a cobalt-chromium substrate in the form of an orthopedic implant device; and

hardening the surface of the cobalt-chromium substrate by exposing the cobalt-chromium substrate to an atmosphere of ionized nitrogen at a process temperature within the range of 500°

F. to 2400°

F. for a process time duration sufficient to achieve a hardened outer surface layer and a hardened diffusion layer characterized primarily by solid solution hardening of the surface of the cobalt-chromium substrate by dissolution of nitrogen and oxygen in the cobalt-chromium substrate.

20. A method of manufacturing a cobalt-chromium orthopedic implant device having enhanced surface hardness and wear resistance properties, comprising the steps of:

providing a cobalt-chromium substrate in the form of an orthopedic implant device; and

exposing the cobalt-chromium substrate to an atmosphere of ionized nitrogen at a process temperature and for a process time duration sufficient to cause nitrogen dissolution in the cobalt-chromium substrate without formation of a substantial quantity of chromium nitride on the surface of said the cobalt-chromium substrate, thereby enhancing the surface hardness and wear resistance properties of the cobalt-chromium substrate by substantially avoiding increased surface roughness and brittleness that would diminish the wear resistance properties.

21. A method of increasing the surface hardness and wear resistance properties of an orthopedic implant device that is fabricated from a cobalt-chromium material, comprising the steps of:

providing a substrate of cobalt-chromium material in the form of an orthopedic implant device; and

exposing the substrate to an atmosphere of ionized nitrogen at a process temperature and for a process time duration sufficient to enhance both surface hardness and wear resistance properties of said substrate by nitrogen dissolution in the substrate by substantially avoiding increased surface roughness and brittleness and thereby diminishing wear resistance properties by the formation of a substantial quantity of chromium nitride on the surface of the substrate.