Removable sample testing member for use in measuring ion concentration

• US 5,310,473 A
• Filed: 08/04/1993
• Issued: 05/10/1994
• Est. Priority Date: 03/19/1986
• Status: Expired due to Fees

• Current Assignee: Horiba Limited
• Original Assignee: Horiba Limited
• Inventors: Kojima, Junji, Mototsune, Akemi, Tomita, Katsuhiko
• Primary Examiner(s): Niebling, John
• Assistant Examiner(s): Bell, Bruce F.
• Application Number:
  US08/102,092
• Time in Patent Office: 279 Days
• Field of Search: 204/414, 204/420, 204/416, 204/433, 204/435
• US Class Current: 204/414
• CPC Class Codes: G01N 27/307 Disposable laminated or multilayered electrodes G01N27/3272 takes precedence
• CPC Class Codes: G01N 27/4035 Combination of a single ion-sensing electrode and a single reference electrode G01N27/406 and G01N27/413 take precedence
• CPC Class Codes: G01N 27/4165 for pH meters

Abstract

An improved compact ion-concentration measuring apparatus having a removable sample testing module with gelatinized electrodes. The gelatinized portion of the electrodes can be formed with a jelly containing an acrylic polymer with sodium.

Claims

1. A removable sample testing member for use with a compact ion-concentration measuring apparatus which provides an indication of an ion-concentration of a sample, comprising:

a nonconductive nonapertured planar substrate having an outer edge and an upper surface;

first and second lead portions carried by the upper surface of said substrate from the outer edge of said substrate to first and second internal positions, respectively;

first and second internal electrode portions formed at the first and second internal positions of said first and second lead portions, respectively;

a nonconductive support layer having a lower surface and an upper surface, the lower surface of said support layer adhered to the upper surface of said substrate and thereby sandwiching said first and second lead portions between said substrate and said support layer, said support layer having an exterior edge which terminates before the outer edge of said substrate to expose a part of said substrate and a part of the lead portions of said first and second lead portions for physical and electrical connection to the ion-concentration measuring apparatus;

first and second holes provided in said support layer spatially corresponding to said first and second internal electrode portions whereby said internal electrode portions are respectively accessible through said holes;

a glass electrode portion comprised of a first gelatinized member located in said first hole and contacting said first internal electrode portion, the gelatinized member being of a thickness to project an upper surface thereof slightly above the upper surface of said support layer, and a PH-responsive glass membrane overlaying said first hole, said PH-responsive glass membrane contacting the upper surface of said first gelatinized member and hermetically sealing said first gelatinized member in said first hole; and

a reference electrode portion comprised of a second gelatinized member located in said second hole and contacting said second internal electrode portion.

2. The removable sample testing member of claim 1 wherein the gelatinized members are formed with an acrylic polymer with sodium.

3. The removable sample testing member of claim 1 wherein said gelatinized members have a thickness of less than 1 mm.

4. The removable sample testing member of claim 1 wherein said first and second lead portions are respectively comprised of an electrically conductive substance silkscreened onto the upper surface of said substrate.

5. The removable sample testing member of claim 1 wherein said first and second gelatinized members are respectively comprised of an internal solution silkscreened into said first and second holes.

6. The removable sample testing member of claim 1 wherein said second gelatinized member is of a thickness to project an upper surface thereof slightly above the upper surface of said support layer, and further comprising:

a liquid junction membrane overlaying the second hole and contacting the upper surface of said second gelatinized member.

7. The removable sample testing member of claim 1 further comprising:

third and fourth lead portions located on the upper surface of said substrate from the outer edge of said substrate to third and fourth internal positions, respectively; and

a temperature-compensating electrode portion formed across the third and fourth internal positions of said third and fourth lead portions.

8. The removable sample testing member of claim 7 wherein said third and fourth lead portion are comprised of an electrically conductive substance silkscreened onto the upper surface of said substrate.