Method of making a conductive polymer selective species sensor

• US 5,310,507 A
• Filed: 08/13/1992
• Issued: 05/10/1994
• Est. Priority Date: 06/15/1990
• Status: Expired due to Fees

• Current Assignee: Physical Sciences Incorporated
• Original Assignee: Spectral Sciences, Inc.
• Inventors: Zakin, Mitchell R., Moody, Richard A., Bernstein, Lawrence S.
• Primary Examiner(s): Skaling, Linda
• Assistant Examiner(s): KOPEC, MARK T
• Application Number:
  US07/928,529
• Time in Patent Office: 635 Days
• Field of Search: 252/500, 252/512, 252/518, 422/83, 422/88, 422/90, 422/98, 422/82.02, 436/149, 436/151, 427/8, 73/31.01, 73/31.05, 204/290 F, 204/418
• US Class Current: 252/500
• CPC Class Codes: G01N 27/126 comprising organic polymers

Abstract

A selective chemical species detector including a conductive polymer based sensing element having a detectable characteristic, for example, the polymer resistivity, permanently altered on exposure to a first chemical species and not permanently altered on exposure to a second chemical species. The detector then determines a permanent change in the detected characteristic and indicates the presence of a chemical species on detection of a such a permanent characteristic change. Also disclosed is a method of fabricating such a sensing element to achieve the desired selectivity.

Claims

1. A method of fabricating a selective species sensing element for irreversibly detecting the exposure of said sensing element to a first compensating agent in the presence of a second compensating agent, comprising the steps of:

providing a polymer material made conductive with a polymer dopant;

determining the doped material permanent saturation resistivity toward the first and second compensating agents in which the permanent saturation resistivity toward the second compensating agent is lower than that towards the first; and

permanently adjusting, prior to detecting the exposure of said sensing element to said first compensating agent in the presence of said second compensating agent, the doped material resistivity to be at least that of the second compensating agent doped material permanent saturation resistivity and less than the first compensating agent doped material permanent saturation resistivity so that the adjusted material resistivity permanently changes on exposure to the first compensating agent and not on exposure to the second compensating agent for selective detection of the first compensating agent in the presence of the second compensating agent by monitoring of permanent material resistivity change.

3. The method of claim 1 in which the conductive polymer material is selected from the group consisting of polythiophene, polyaniline, polypyrrole, polyacetylene, polydiacetylene, and their derivatives.

5. The method of claim 1 in which the doped polymer resistivity is adjusted with a polymer compensating agent.

2. A method of fabricating a selective species sensing element for irreversibly detecting the exposure of said sensing element to a first dopant in the presence of a second dopant, comprising the steps of:

providing a conductive polymer material made conductive with a polymer dopant;

determining the material permanent saturation conductivity toward the first and second dopants, in which the permanent saturation conductivity toward the second dopant is lower than that toward the first; and

permanently adjusting, prior to detecting the exposure of said sensing element to said first dopant in the presence of said second dopant, the polymer material conductivity to be at least that of the second dopant polymer material permanent saturation conductivity and less than the first dopant polymer material permanent saturation conductivity so that the adjusted material conductivity permanently changes on exposure to the first dopant and not on exposure to the second dopant for selective detection of the first in the presence of the second dopant by monitoring of permanent material conductivity change.

4. The method of claim 2 in which the conductive polymer material is selected from the group consisting of polythiophene, polyaniline, polypyrrole, polyacetylene, polydiacetylene, and their derivatives.

6. The method of claim 2 in which the doped polymer conductivity is adjusted with a polymer dopant.