Method and apparatus for the manufacture of large optical grade SiO.sub.2 glass preforms

• US 5,312,471 A
• Filed: 12/02/1991
• Issued: 05/17/1994
• Est. Priority Date: 12/02/1991
• Status: Expired due to Fees

• Current Assignee: Lothar Jung
• Original Assignee: Lothar Jung
• Inventors: Jung, Lothar
• Primary Examiner(s): WOODARD, JOYE L
• Application Number:
  US07/800,941
• Time in Patent Office: 897 Days
• Field of Search: 65/18.2, 65/71, 65/302, 65/335, 65/DIG. 4, 65/DIG. 8, 65/29, 373/20, 373/22, 373/27, 373/63, 373/18, 219/121.47
• US Class Current: 65/17.4
• CPC Class Codes: C03B 19/095 by centrifuging, e.g. arc discharge in rotating mould crucibles for crystal pulling in general C30B15/10, C30B35/002
• CPC Class Codes: C03B 37/01271 by centrifuging
• CPC Class Codes: C03B 37/01294 by delivering pulverulent glass to the deposition target or preform where the powder is progressively melted, e.g. accretion
• CPC Class Codes: C03B 5/025 by arc discharge or plasma heating
• CPC Class Codes: C03B 5/14 in revolving cylindrical furnaces C03B5/02 takes precedence
• CPC Class Codes: C03B 5/2255 by centrifuging
• CPC Class Codes: H05H 1/3431 Coaxial cylindrical electrodes
• CPC Class Codes: H05H 1/48 using an arc H05H1/26 takes precedence
• CPC Class Codes: Y02P 40/57 Improving the yield, e-g- reduction of reject rates
• CPC Class Codes: Y10S 65/08 Quartz

Abstract

The disclosed process involves the feeding of particulate SiO₂ into a rotating cylindrical furnace in which a gas plasma arc has been established, for melting the feed at a temperature of at least 2400° C. The feed rate is regulated so that the rate of growth of the radius of the ingot melt will not exceed the rate at which bubbles move through the melt to the inner cylindrical surface. The preferred apparatus is a rotating horizontal furnace having a pair of opposing hollow electrodes mounted in its opposing end surfaces for establishment of an arc therebetween. A feeding device introduces the SiO₂ feed through the open bore of one of the electrodes for melting by the plasma arc.

Claims

1. A process for producing an optical quality SiO₂ glass ingot comprising:

rotating a cylindrical horizontal furnace about its central axis, said furnace having spaced electrodes extending along said central axis into the furnace interior;

establishing a gas plasma arc between said electrodes to heat the furnace;

feeding SiO₂ into said furnace and melting said SiO₂, within said furnace at a temperature of at least 2400°

C. to form a hollow cylindrical melt by centrifugal force generated by said rotating, while controlling the rate of said feeding to provide a rate of decrease of the inner radius of said cylindrical melt no greater than the escape rate toward the inner cylindrical surface of said melt at said temperature for the smallest bubble compatible with the desired optical quality of the glass ingot product, said rate of said feeding being decreased in proportion to the rate of change of surface area of the inner surface of the hollow cylindrical melt.

2. The process of claim 1 employing electrodes with central bores and wherein said particulate SiO₂ is blown into said furnace with introduction of the gas forming the plasma through one of said electrodes while bleeding gas out of said furnace through the other of said electrodes.

3. The process of claim 1 wherein the speed of rotation of the furnace is increased simultaneously with and in proportion to the rate of decrease of the surface area of the inner surface of the cylindrical melt.

4. The process of claim 1 wherein said temperature is at least 3000°

C.

5. The process of claim 1 wherein said gas plasma arc is established by continuously introducing a plasma forming gas into the furnace.

6. The process of claim 5 wherein said plasma forming gas is argon.

7. The process of claim 1 wherein said SiO₂ is fed into the furnace in granular form.

8. The process of claim 1 wherein said SiO₂ is fed into the furnace in the form of slugs.

9. Apparatus for producing an optical grade SiO₂ glass ingot, said apparatus comprising:

a cylindrical furnace housing closed by a flange at each end to define a sealed furnace interior;

a loose granular refractory lining the interior surface of said furnace housing and held in place by centrifugal force generated by rotation of said cylindrical furnace housing;

means for rotating said furnace housing about its central longitudinal axis with said axis approximately horizontal;

a pair of electrodes, said electrodes having axial bores and extending through said flanges into said furnace interior;

power supply means for supplying power to said electrodes to establish a plasma arc therebetween; and

means for introducing a SiO₂ feed through a bore of one of said electrodes for melting by said plasma arc and for controlling the rate of said feed to decrease in proportion to rate of change of surface area of the inner surface of a hollow cylindrical melt formed by melting the feed and to provide a rate of decrease of the inner radius of said cylindrical melt no greater than the escape rate toward the inner cylindrical surface of said melt of the smallest bubble compatible with the desired optical quality of the glass ingot product.

10. The apparatus of claim 9 further comprising means for moving at least one of said electrodes relative to the other of said electrodes to facilitate establishment of said plasma arc therebetween.

11. The apparatus of claim 9 further comprising means for continuously introducing a plasma forming gas into said furnace.