Sheet or web material having antistatic properties

• US 5,312,681 A
• Filed: 01/05/1993
• Issued: 05/17/1994
• Est. Priority Date: 04/27/1989
• Status: Expired due to Term

• Current Assignee: Agfa-Gevaert N.V.
• Original Assignee: Agfa-Gevaert N.V.
• Inventors: Jonas, Friedrich, Muys, Bavo
• Primary Examiner(s): Ryan, Patrick J.
• Assistant Examiner(s): Macholl, Marie R.
• Application Number:
  US08/000,683
• Time in Patent Office: 497 Days
• Field of Search: 428/537.5, 428/201, 428/204, 428/206, 428/327, 428/480, 428/483, 428/323, 428/411.1, 430/62, 430/64, 430/75, 430/523, 430/527, 430/529, 524/910, 524/911, 526/256
• US Class Current: 428/323
• CPC Class Codes: C08G 61/126 with a five-membered ring containing one sulfur atom in the ring
• CPC Class Codes: C09K 3/16 Anti-static materials
• CPC Class Codes: G03C 1/89 Macromolecular substances therefor
• CPC Class Codes: G03C 1/93 Macromolecular substances therefor
• CPC Class Codes: H01B 1/127 comprising five-membered aromatic rings in the main chain, e.g. polypyrroles, polythiophenes
• CPC Class Codes: Y10T 428/25 Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
• CPC Class Codes: Y10T 428/254 Polymeric or resinous material
• CPC Class Codes: Y10T 428/31504 Composite [nonstructural laminate]
• CPC Class Codes: Y10T 428/31786 Of polyester [e.g., alkyd, etc.]
• CPC Class Codes: Y10T 428/31993 Of paper

Abstract

A sheet or web material comprising a hydrophobic resin support or paper support coated with at least one hydrophobic resin layer wherein said resin support or resin layer is coated with a transparent antistatic layer containing as an essential component a polythiophene with conjugated polymer backbone in the presence of a polymeric polyanion compound, characterized in that said antistatic layer is coated with an overlying adhering barrier layer applied from an aqueous polymer dispersion wherein the dispersed polymer has hydrophilic functionality sufficient to render said overlying layer adherent to a thereon coated hydrophilic colloid-containing layer.

Claims

1. A sheet or web material comprising a hydrophobic resin support or a paper support coated with at least one hydrophobic resin layer wherein said resin support or resin layer is coated with an antistatic layer applied from a polymer dispersion containing a polythiophene with conjugated polymer backbone and a polymeric polyanion compound, with the size of the polymer particles in said dispersion being from 5 nm to 1 μ

m, and wherein said antistatic layer is coated with an overlying adhering barrier layer applied from an aqueous polymer dispersion wherein the polymer of said barrier layer has hydrophilic functionality and said overlying adhering barrier layer is adhered to a hydrophilic colloid-containing layer.

2. The sheet or web material according to claim 1 wherein said hydrophilic colloid-containing layer is a gelatin-silver halide emulsion layer.

3. The sheet or web material according to claim 1 wherein said polythiophene is made up of structural units corresponding to the following general formula (I):

##STR3## in which;

each of R¹ and R² independently represents hydrogen or a C_1-4 alkyl group or together represent a C_1-4 alkylene group.

4. The sheet or web material according to claim 1 wherein said polythiophene has been prepared in the presence of said polymeric polyanion compound by oxidative polymerization of 3,4-dialkoxythiophenes or 3,4-alkylenedioxythiophenes according to the following general formula (II):

##STR4## in which;

R¹ and R² independently represent hydrogen or a C_1-4 alkyl group or together represent a C_1-4 alkylene group.

5. The sheet or web material according to claim 1 wherein said polymeric polyanion compound is a polymeric carboxylic acid or polymeric sulfonic acid or such acid in salt form.

6. The sheet or web material according to claim 5 wherein said polymeric polyanion compound is a polymer comprising styrene sulfonic acid units.

7. The sheet or web material according to claim 1 wherein said polymer in the barrier layer is a copolymer of (1) one or more polymerizable monomers selected from the group consisting of styrene, vinylidene chloride, acrylonitrile, alkyl acrylates and alkyl methacrylate with (2) one or more substituted polymerizable co-monomers selected from the group consisting of styrenes, alkyl acryaltes and alkyl methacrylates each of which have been substituted with an aminoalkyl salt group, an hydroxyalkyl group, or a carboxylic acid group.

8. The sheet or web material according to claim 1 wherein the group (1) monomers are selected from the group consisting of ethyl acrylate, ethyl methacryalte, butyl acrylate and butyl methacrylate, and the group (2) monomers are selected from the group consisting of 2-aminoethyl methacrylate hydrochloride, 2-hydroxyethyl acrylate, 2-hydroxyethyl methacrylate, N(3-aminopropyl)methacrylate hydrochloride, p-aminostyrene hydrochloride acrylic acid, and itaconic acid.

9. The sheet or web material according to claim 7 wherein the polymer present in said barrier layer is a copolymer containing at least 50 mol % vinylidene chloride repeating units and repeating units with a carboxyl functional group.

10. The sheet or web material according to claim 1 wherein said material is a photographic material containing at one side of said support at least one silver halide emulsion layer and at the side free from said at least one silver halide emulsion layer, in sequence, said antistatic layer, said barrier layer and a hydrophilic colloid anti-curl layer.