Golf ball cover compositions containing high levels of metal stearates

• US 5,312,857 A
• Filed: 01/09/1992
• Issued: 05/17/1994
• Est. Priority Date: 01/09/1992
• Status: Expired due to Term

• Current Assignee: Callaway Golf Company (Topgolf Callaway Brands Corp.)
• Original Assignee: Lisco Incorporated
• Inventors: Sullivan, Michael J.
• Primary Examiner(s): Michl, Paul R.
• Assistant Examiner(s): SZEKELY, PETER A
• Application Number:
  US07/819,108
• Time in Patent Office: 859 Days
• Field of Search: 524/398, 524/399, 524/400, 524/908, 524/394, 273/62, 273/233, 273/234, 273/235 R, 273/DIG. 22
• US Class Current: 524/400
• CPC Class Codes: A63B 2102/32 Golf
• CPC Class Codes: C08K 5/098 Metal salts of carboxylic acids
• CPC Class Codes: C08L 23/025 Copolymer of an unspecified olefin with a monomer other than an olefin
• CPC Class Codes: Y10S 273/22 Ionomer
• CPC Class Codes: Y10S 524/908 Composition having specified shape, e.g. rod, stick, or ball, and other than sheet, film, or fiber

Abstract

The present invention relates to improved cover compositions for golf ball construction. In this regard, it has been found that if high levels (i.e. greater than 10 pph resin) of metal stearates (i.e. zinc stearate, barium stearate, calcium stearate, magnesium stearate, etc.) are added to various ionomer resin formulations utilized in golf ball cover construction, the covers produced thereby exhibit similar or improved coefficient of restitution (C.O.R.) values combined with similar or reduced hardness (i.e. an increase in softness) properties. Moreover, since the metal stearates are significantly cheaper than the ionomer resins and the discovery that the metal stearates can be added at relatively high levels without detracting, and many instances enhancing the physical properties of the overall formulations, the addition of high levels of the metal stearates presents significant cost savings in the production of golf balls.

Claims

1. A golf ball comprising a core and a cover, wherein the cover consists essentially of 100 parts by weight of at least one ionomer resin and from above 25 to about 100 parts by weight of a metal stearate, wherein said ionomer resin is the reaction product of an olefin having from 2 to 8 carbon atoms and an unsaturated monocarboxylic acid having from 3 to 8 carbon atoms.

2. The golf ball of claim 1, wherein said metal stearate is selected from the group consisting of zinc stearate, barium stearate, calcium stearate and magnesium stearate.

3. The golf ball of claim 1, wherein said cover comprises of one of more additional ingredients selected from the group consisting of pigments, dyes, U.V. absorbers and optical brighteners.

4. The golf ball of claim 1, wherein said unsaturated monocarboxylic acid is a carboxylic acid selected from the group consisting of a acrylic acid and methacrylic acid.

5. The golf ball of claim 4, wherein the carboxylic acid groups of the ionomer resin are partially neutralized by sodium ions.

6. The golf ball of claim 4, wherein the carboxylic acid groups of the ionomer resin are partially neutralized by zinc ions.

7. A golf ball comprising a core and a cover, wherein the cover consists essentially of 100 parts by weight of at least one ionomer resin and from about 25 to about 75 parts by weight of a metal stearate, wherein said ionomer resin is the reaction product of an olefin having from 2 to 8 carbon atoms and an unsaturated monocarboxylic acid having from 3 to 8 carbon atoms.

8. The golf ball of claim 7, wherein said metal stearate is selected from the group consisting of zinc stearate, barium stearate, calcium stearate and magnesium stearate.

9. The golf ball of claim 7, wherein said cover comprises of one or more additional ingredients selected from the group consisting of pigments, dyes, U.V. absorbers and optical brighteners.

10. The golf ball of claim 7, wherein said unsaturated monocarboxylic acid is a carboxylic acid selected from the group consisting of acrylic acid and methacrylic acid.

11. The golf ball of claim 10, wherein the carboxylic acid groups of one of the ionomer resin are partially neutralized by sodium ions.

12. The golf ball of claim 10, wherein the carboxylic acid groups of one of the ionomer resins are partially neutralized by zinc ions.

13. A golf ball comprising a core and a cover, wherein the cover consists essentially of 100 parts by weight of one or more ionomer resins and from about 50 parts by weight of a metal stearate, wherein said ionomer resin is the reaction product of an olefin having from 2 to 8 carbon atoms and an unsaturated monocarboxylic acid having from 3 to 8 carbon atoms.

14. The golf ball of claim 13, wherein said metal stearate is selected from the group consisting of zinc stearate, barium stearate, calcium stearate and magnesium stearate.

15. The golf ball of claim 13, wherein said cover comprises of one or more additional ingredients selected from the group consisting of pigments, dyes, U.V. absorbers and optical brighteners.

16. The golf ball of claim 13, wherein the carboxylic acid groups of one of the ionomer resins are partially neutralized by sodium ions.

17. The golf ball of claim 13, wherein the carboxylic acid groups of one of the ionomer resins are partially neutralized by zinc ions.

18. In a golf ball cover composition consisting essentially of at least one ionomer resin, the improvement comprising the addition of from about 25 to about 100 parts by weight resin of a metal stearate, wherein said ionomer resin is the reaction product of an olefin having from 2 to 8 carbon atoms and an unsaturated monocarboxylic acid having from 3 to 8 carbon atoms.

19. The golf ball cover of claim 18, wherein said metal stearate is selected from the group consisting of zinc stearate, barium stearate, calcium stearate and magnesium stearate.