Sorting plastic bottles for recycling

• US 5,314,072 A
• Filed: 09/02/1992
• Issued: 05/24/1994
• Est. Priority Date: 09/02/1992
• Status: Expired due to Fees

• Current Assignee: Rutgers University
• Original Assignee: Rutgers University
• Inventors: Whitlock, Jonathan B., Miroshnichenko, Sergey, Frankel, Henry
• Primary Examiner(s): Dayoan, D. Glenn
• Assistant Examiner(s): REICHARD, DEAN ALAN
• Application Number:
  US07/939,304
• Time in Patent Office: 629 Days
• Field of Search: 209/12, 209/44.1, 209/524, 209/522, 209/577, 209/580, 209/581, 209/582, 209/585, 209/588, 209/589, 209/938
• US Class Current: 209/44.1
• CPC Class Codes: B07C 5/3408 for bottles, jars or other glassware according to size B07C5/122
• CPC Class Codes: B07C 5/3416 according to radiation transmissivity, e.g. for light, x-rays, particle radiation detecting hidden objects G01V
• CPC Class Codes: B07C 5/365 using a single separation means
• CPC Class Codes: G01N 2033/0081 containers; packages; bottles

Abstract

An apparatus and method for sorting plastic bottles for recycling wherein if it is first determined that a bottle is clear, the bottle will be ejected. If the bottle is not determined as being clear, the apparatus or method next determines if the bottle is colored. If the bottle is colored, the bottle will be ejected. The above method may also be accomplished by use of a truth table which analyzes the characteristics of a bottle. Also provided is a detector for detecting the presence of chlorine in a plastic bottle by means of X-ray fluorescence. A sorter device sorts the bottles into small diameter and large diameter bottles.

Claims

1. A method of sorting bottles for recycling comprising the steps of

conveying a bottle via a conveying means to a first sensing area, determining whether said bottle is clear while said bottle is in said first sensing area and removing said bottle from said conveying means to a pile of clear bottles if said bottle is clear, and

if said bottle is not removed in said first sensing area, conveying the bottle via said conveying means to a second, separate sensing area, determining whether said bottle is colored while said bottle is in said second sensing area and removing said bottle from said conveying means to a pile of colored bottles if said bottle is colored.

2. The method of claim 1 further comprising the steps of

if said bottle is not removed in either said first or said second sensing area, conveying the bottle via said conveying means to a third, separate sensing area, determining whether said bottle is translucent while said bottle is in said third sensing area and removing said bottle from said conveying means to a pile of translucent bottles if said bottle is translucent.

3. The method of claim 1 wherein said step of determining whether said bottle is clear comprises disposing the bottle between a light emitter and a light detector, emitting red light and passing such light through the bottle, and determining if the magnitude of such light has been diminished by passage through the bottle.

4. The method of claim 3 wherein said step of determining whether the bottle is colored includes the steps of determining whether the bottle is of a particular color by emitting a light of a wavelength corresponding to such particular color, passing such light through the bottle and determining if the magnitude of such light has been diminished by passage through the bottle.

5. The method of claim 4 wherein said particular color is green.

6. The method of claim 2 wherein said step of determining whether said bottle is translucent comprises disposing the bottle between a light emitter and a light detector, emitting high intensity red or infrared light and passing such light through the bottle, and determining if the magnitude of such light has been diminished by passage through the bottle.

7. The method of claim 1 or claim 2 further comprising the steps of conveying the bottle via said conveying means to a separate polarization sensing area before the bottle is conveyed to the first, second or third sensing areas, determining whether said bottle is glass, or one or more of a group of materials comprising polyvinyl chloride (PVC) or polyvinylidine chloride (PVDC) while said bottle is in said polarization sensing area and removing said bottle from said conveying means to a pile of glass, PVC or PVDC bottles if said bottle is glass, PVC or PVDC.

8. The method of claim 7 wherein said step of determining whether said bottle is glass or one or more of a group of materials comprising polyvinyl chloride (PVC) or polyvinylidine chloride (PVDC) comprises disposing the bottle between a polarized light emitter and a polarized light detector, emitting polarized light and passing such light through the bottle, and determining whether such light has changed polarization by passage through the bottle.

9. The method of claim 8 wherein said polarized light is circularly polarized light.

10. The method of claim 1 or claim 2 further comprising conveying a bottle via said conveying means to a separate X-ray sensing area before the bottle is conveyed to the first, second or third sensing areas, determining whether said bottle contains chlorine while said bottle is in said X-ray sensing area and removing said bottle from said conveying means to a pile of chlorine-containing bottles if said bottle contains chlorine.

11. The method of claim 10 wherein said step of determining whether said bottle contains chlorine comprises irradiating said bottle with X-rays, determining whether the bottle emits secondary radiation associated with the presence of chlorine upon such irradiation.

12. A method of determining whether plastic bottles for recycling contain chlorine comprising

irradiating the plastic bottles with X-rays, and

detecting any secondary X-ray florescence associated with the presence of chlorine.

13. The method of claim 12 wherein said irradiating step includes the step of conveying a plurality of said plastic bottles along a conveying means to a X-ray sensing area, and irradiating each such bottle with said X-rays while such bottle is in said X-ray sensing area, the method further comprising the step of removing a particular bottle from said conveying means if said secondary X-ray florescence associated with the presence of chlorine is detected while such bottle is in said X-ray sensing area.

14. The method of claim 12 wherein said step of irradiating comprises irradiating said bottles with X-rays of about 6 kiloelectron volts (KEV) energy, and

said step of detecting comprises detecting secondary radiation having energy equal to about 2.8 KEV.

15. The method of claim 14 wherein said irradiating step includes the step of directing X-rays from a sample of Fe-55 to said X-ray sensing area.

16. The method of claim 13 wherein said step of detecting comprises detecting the presence of polyvinyl chloride or polyvinylidine chloride.

17. The method of claim 12 wherein said step of detecting comprises

measuring said secondary X-ray florescence of said bottles at predetermined intervals of time during said irradiating step such that a plurality of measurements are performed with respect to each bottle, and

signalling that a said bottle contains chlorine if the secondary X-ray fluorescence measured by at least one of said measurements is associated with the presence of chlorine.

18. A method of determining whether bottles are composed of glass, or one or more of a group of materials comprising polyvinyl chloride (PVC) or polyvinylidine chlorine (PVDC) comprising

disposing a bottle between a first polarized light emitter and a first polarized light detector,

emitting circularly polarized light and passing such light through the bottle, and

determining whether such light has changed polarization by passage through the bottle.

19. The method of claim 18 further comprising the steps of

conveying one bottle between said emitter and said detector from a line of bottles,

diverting said one bottle from said line of bottles to a pile of glass bottle if the change in polarization indicates said one bottle is glass, and

diverting said one bottle from said line of bottles to a pile of polyvinyl chloride (PVC) or polyvinylidine chloride (PVDC) bottles if the change in polarization indicates said bottle is composed of PVC or PVDC.

20. The method of claim 18 further comprising the steps of

conveying one bottle between said emitter and said detector from a line of bottles,

if the change in polarization indicates said one bottle is glass, diverting said one bottle from said line of bottles to a pile of glass bottles,

if said one bottle is not diverted, disposing said one bottle between a second polarized light emitter and a second polarized light detector, emitting circularly polarized light and passing such light through said one bottle, determining whether such light has changed polarization by passage through the bottle, and diverting said one bottle to a pile of PVC or PVDC bottles if the change in circularly polarized light from said second polarized light emitter indicates said bottle is composed of PVC or PVDC.

21. The method of claims 19 or 20, wherein

said step of emitting polarized light comprises emitting light of random polarization, passing said random light through a linear polarizing filter, and passing the linearly polarized light through a first quarterwave plate to produce said circularly polarized light of a first-handedness, and

wherein said step of determining the change in polarization comprises passing the light exiting the bottle through a second quarterwave plate followed by a second linear polarizing filter, the relative orientation of said second quarter wave plate with respect to said second linear polarizing filter being such to block light that is circularly polarized with said first handedness.

22. The method of claim 19 or 20 further comprising the step of:

emitting nonpolarized light of substantially equivalent wave length to said circularly polarized light through the bottle,

determining the attenuation of said nonpolarized light through the bottle, comparing said change in polarization of said polarized light after passage through said bottle with the attenuation of said nonpolarized light after passage through said bottle.

23. A method of determining the composition of bottles comprising

disposing a bottle between a first polarized light emitter and a first polarized light detector,

emitting circularly polarized light and passing such light through the bottle, and

determining whether such light has changed polarization by passage through the bottle.