Optical fibers and core - forming compositions

• US 5,314,979 A
• Filed: 12/09/1991
• Issued: 05/24/1994
• Est. Priority Date: 12/10/1990
• Status: Expired due to Term

• Current Assignee: Hitachi Cable Limited (Proterial Ltd.)
• Original Assignee: Hitachi Cable Limited (Proterial Ltd.), Shin-Etsu Chemical Company Limited
• Inventors: Kozakai, Shohei, Abe, Tomiya, Okinoshima, Hiroshige
• Primary Examiner(s): DEAN JR, RALPH H
• Application Number:
  US07/803,552
• Time in Patent Office: 897 Days
• Field of Search: 385/123, 528/15, 528/25, 528/26, 528/31, 528/24, 528/21, 525/479
• US Class Current: 528/15
• CPC Class Codes: C08G 77/12 containing silicon bound to hydrogen C08G77/045 takes precedence
• CPC Class Codes: C08G 77/16 to hydroxyl groups
• CPC Class Codes: C08G 77/20 containing silicon bound to unsaturated aliphatic groups C08G77/045 takes precedence
• CPC Class Codes: C08L 2666/44 Silicon-containing compounds
• CPC Class Codes: C08L 83/00 Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 83/04 Polysiloxanes
• CPC Class Codes: G02B 1/046 characterised by the core material

Abstract

A composition comprising (A) an organopolysiloxane having a unit of the formula: R¹ SiO_3/2 wherein R¹ is methyl, phenyl or vinyl in its molecule and having at least 0.05 alkenyl groups each directly attached to a silicon atom per silicon atom, (B) an organohydrogenpolysiloxane having at least 2 hydrogen atoms each directly attached to a silicon atom per molecule, (C) a platinum catalyst, and (D) an organosilane or organopolysiloxane of the formula: R²_a (R³ O)_b SiO.sub.(4-a-b)/2 wherein R² and R³ are hydrogen, methyl, phenyl or vinyl maintains good light transmission in cured form when exposed to humidity and is thus suitable for forming cores of optical fibers. Similar benefits are obtained with a composition comprising components (A) and (B), (C'"'"') a platinum catalyst and/or a radical polymerization initiator, and (E) a carboxylate.

Claims

1. A composition for forming optical fiber cores, comprising

(A) an organopolysiloxane having a unit of formula (1):

space="preserve" listing-type="equation">R.sup.1 SiO.sub.3/2 (

     1)

wherein R¹ is an unsubstituted monovalent hydrocarbon group having 1 to 10 carbon atoms in its molecule or a halogenated derivative thereof and has at least 0.05 alkenyl groups, each directly attached to a silicon atom, per silicon atom,

(B) an organopolysiloxane having at least 2 hydrogen atoms each directly attached to a silicon atom per molecule,

(C'"'"') a platinum catalyst or a radical polymerization initiator or both, and

(E) a carboxylate of formula (3);

##STR6## wherein R_A a hydrogen or a methyl group and R_B is hydrogen an unsubstituted monovalent hydrocarbon group having 1 to 18 carbon atoms or a halogenated monovalent hydrocarbon group having 1 to 18 carbon atoms;

wherein said carboxylate (E) is contained in an amount of about 0.5 to about 50% by weight based on the total weight of the composition.

2. The composition according to claim 1, wherein the organopoly-siloxane as component (A) further has a silanol group, and the silanol group in said organopolysiloxane is present in an amount of at least 0.02 mol per 100 grams of the total weight of components (A) and (B).

3. The composition according to claim 1, wherein said carboxylate (E) is contained in an amount of about 1 to 30% by weight based on the total weigh of the composition.

4. The composition according of claim 1, wherein R_B is a member selected from the group consisting of methyl, ethyl, propyl, vinyl, allyl, hexenyl, cyclohexyl, phenyl, tolyl, xylyl, benzyl, penyltheyl, tetrachlorophenyl, chlorophenyl, chloromethyl, partafluorobutyl and trifluoropeopyl.

5. The composition according to claim 1, wherein said carboxylate of formula (3) is selected from the group consisting of methyl methacrylate, benzylmethacrylate, ethyl methacrylate, 2,2,2-trifluoroethyl methacrylate, and n-butyl acrylate.

6. The composition according to claim 1, wherein said component (C'"'"') comprises a platinum catalyst selected from platinum black or chloroplatinic acid.

7. The composition according to claim 1, wherein said component (C'"'"') comprises a radical polymerization initiator selected from eh group consisting of benzoyl peroxide, dicumyl peroxide, lauroyl peroxide, asobis-isobutyronitrile, and azxobis (2,4-dimethylvaleronitrile).

8. The composition according to claim 1, wherein said radical polymerization initiator of component (C'"'"') is contained in an amount of about 0.01 to about 5 parts by weight per 100 parts by weight of the total of components (A), (B), and (E).

9. The composition according to claim 1, wherein component (C'"'"') comprises both a platinum catalyst and a radical polymerization initiator.

10. The composition according to claim 1, wherein the molar ratio of said alkenyl groups in the organopolysiloxane of component (A) to the hydrogen atoms directly bonded to silicon atoms in the organopolysiloxane of component (B) is in the range of 10:

1 to 1;

10.

11. The composition according to claim 10, wherein said molar ratio is in the range of 5:

1 to 1;

5.

12. The composition according of claim 1, wherein said organopolysiloxane of component (A) is comprised of about 30 to 80 mol % of said units of formula (1).

13. The composition according to claim 1, wherein said organopolysiloxane of component (A) is comprised of about 40 to 70 mol % of said units of formula (1).

14. The composition according to claim 1, wherein said alkenyl groups contained in the organopolysiloxane of component (A) are contained in an amount of 0.15 to 0.5 alkenyl groups per silicon atom.

15. The composition according to claim 1, wherein said organopolysiloxane of component (A) further contains a silanol group on an amount of at least 0.04 mol per 100 grams of the total weight of components (A) and (B).

16. An optical fiber comprising a core and a clad thereon, wherein said core comprises the cured product of the composition as set forth in claim 1 or 2.

17. An optical fiber comprising a core and a clad thereon, wherein said core comprises the cured product of the composition as set forth in claim 5.

18. An optical fiber comprising a core and a clad thereon, wherein said core comprises the cured product of the composition as set forth in claim 11.

19. An optical fiber comprising a core and a clad thereon, wherein said core comprises the cured product of the composition as set forth in claim 15.