Energetic binder explosive

• US 5,316,600 A
• Filed: 09/18/1992
• Issued: 05/31/1994
• Est. Priority Date: 09/18/1992
• Status: Expired due to Fees

• Current Assignee: The United States of America As Represented By The Secretary of Agriculture
• Original Assignee: the united states of america as represented by the secretary of the navy
• Inventors: Turner, Alan, Roy, Edward M., Chan, May L.
• Primary Examiner(s): Miller, Edward A.
• Application Number:
  US07/947,009
• Time in Patent Office: 620 Days
• Field of Search: 149/19.4, 149/19.6
• US Class Current: 149/19.4
• CPC Class Codes: C06B 45/105 The resin being a polymer bearing energetic groups or containing a soluble organic explosive

Abstract

A castable, energetic, plastic-bonded explosive containing glycidyl azide lymer (GAP) an energetic polymer binder combined with the energetic plasticizers trimethyloethane trinitrate (TMETN) and trimethylene glycol dinitrate (TEGDN) or bisdinitropropyl formal and acetal mixture (BDNPF/A), and the explosive solid cyclotetramethylene tetranitramine (HMX) or cyclotrimethylene trinitramine (RDX) having the desirable mechanical properties, insensitivity, and excellent aging properties at much higher solids loading and thus explosive performance than previous compositions. The invention uniquely combines the high energy of high solids loading combined with energetic polymers and plasticizers to provide the insensitivity of rubbery explosive compositions.

Claims

1. A castable explosive composition consisting essentially of about 80% by weight of an explosive solid selected from the group consisting of cyclotetramethylene tetranitramine (HMX) and cyclotrimethylene trinitromine (RDX);

8%±

1% weight percent Glycidyl Azide Polymer (GAP);

1.0±

0.5 weight percent of a curative selected from the group consisting of multifunctional isocyanate (N-100), hexamethylene diisocyanate (MHDI), and isophorone diisocyanate (IPDI);

8.05±

1.0 weight percent Trimethylolethane trinitrate (TMETN); and

2.00±

0.5 weight percent of an energetic plasticizer selected from the group consisting of Trimethylene glycol dinitrate (TEGDN), bisdinitropropyl formal and acetal mixture (BDNPF/A).

2. The castable explosive composition of claim 1 further consisting essentially of stabilizer selected from the group consisting of 0.3-0.5 weight percent N-Methyl-4-nitroaniline (MNA) and 0.1-0.2 weight percent 2-Nitrodiphenylamine (2-NDPA).

3. The castable explosive composition of claim 1 further consisting essentially of a cure catalyst selected form the group consisting of 0.05-0.15 weight percent octanoic acid and 0.03 to 0.05 2,5-Dinitrosalicylic acid (DNSA).