Water soluble or dispersible film covered alkaline composition

• US 5,316,688 A
• Filed: 05/14/1991
• Issued: 05/31/1994
• Est. Priority Date: 05/14/1991
• Status: Expired due to Term

• Current Assignee: Ecolab USA Incorporated (Ecolab, Inc.)
• Original Assignee: Ecolab, Inc.
• Inventors: Copeland, James L., Schulz, Rhonda K., Gladfelter, Elizabeth J., Outlaw, Tina O., Boche, Daniel K., Peterson, Jeff W.
• Primary Examiner(s): LANGEL, WAYNE A
• Application Number:
  US07/699,688
• Time in Patent Office: 1,113 Days
• Field of Search: 252/90, 252/174.23, 252/174, 252/156, 252/DIG. 2, 252/DIG. 3, 134/4, 134/6, 134/42
• US Class Current: 510/224
• CPC Class Codes: C11D 17/0065 Solid detergents containing builders C11D17/06 takes precedence
• CPC Class Codes: C11D 17/044 Solid compositions

Abstract

The invention is an alkaline cleaning system which includes an alkaline detergent composition having a pH greater than 10.5 when diluted to a 1 wt-% aqueous solution, and an alkali stable continuous polymeric film dispersible or soluble in aqueous liquids covering the detergent composition. The invention also includes methods of using the alkaline cleaning system by applying an aqueous diluent automatically (by machine) or manually through partial or complete dissolution of the film covered solid.

Claims

1. A multidose alkaline cleaning article comprising:

(a) a solid detergent composition having a pH greater than 10.5 when diluted to a 1 wt-% aqueous solution said detergent comprising a source of alkalinity, said alkalinity source selected from the group consisting of a silicate, an alkali metal hydroxide, a phosphate, a carbonate, and mixtures thereof; and

(b) a continuous multilayer polymeric film, dispersible or soluble in aqueous liquids, covering the solid detergent composition, said multilayer film comprising an inner alkaline pH stable and aqueous soluble film and an outer layer resistant to aqueous dissolution and effective in providing mechanical strength wherein said multilayer film remains mechanically stable and aqueous soluble or dispersible after exposure to the solid detergent composition.

2. The article of claim 1 wherein said polymeric film covers substantially the entirety of the solid detergent composition.

3. The article of claim 1 wherein said continuous polymeric film comprises a vinyl polymer.

4. The article of claim 1 wherein said polymeric film comprises two or more layers.

5. The article of claim 4 wherein said inner layer and said outer layer are joined by a plurality of randomly distributed film to film bonds.

6. The article of claim 4 wherein said inner layer and said outer layer are joined by coextensive layer to layer lamination.

7. The article of claim 4 wherein said continuous polymeric film comprises an inner alkali stable and aqueous soluble layer, an outer cold water resistant layer, and an intermediate structural layer.

8. The article of claim 1 wherein said polymeric film has a thickness ranging from about 0.6 mil to about 15 mil.

9. The article of claim 1 wherein said hydroxide is selected from the group consisting of sodium hydroxide, potassium hydroxide, and mixtures thereof.

10. The article of claim 9 wherein said alkaline agent comprises sodium hydroxide present at a concentration ranging from about 5 wt-% to about 80 wt-%.

11. The article of claim 1, wherein said alkaline agent comprises a silicate present at a concentration ranging from about 5 wt-% to 80 wt-%.

12. The article of claim 1, wherein said alkaline detergent composition comprises a granular solid.

13. The article of claim 12 wherein said granular solid is contained within said continuous polymeric film and said granular solid is formed into a rigid shaped block, said shape selected from the group consisting of a cubed block, a hexagonal block, a cylindrical block, and a block comprising a cylindrical body and a conical surface.

14. The article of claim 1, wherein said alkaline detergent composition comprises a compressed solid block.

15. The article of claim 1, wherein said alkaline detergent composition comprises a solid block having a mass of at least 800 grams.

16. The article of claim 15 wherein said solid block comprises a shape said shape selected from the group consisting of a cylindrical block, a hexagonal block, a cube, and a cylindrical block comprising a conical surface.

17. The article of claim 15 wherein said solid block comprises a grooved side wall.

18. The article of claim 16 wherein said block comprises a flat surface having grooves.

19. The article of claim 18 wherein said grooves project radially outward across the flat surface.

20. The article of claim 18 wherein said flat surface is circular in shape and comprises a first set of grooves projecting radially outward from the center of the surface and a second set of groves positioned concentrically in relationship to the center of the flat surface wherein said first set of groves and said second set of grooves intersect.

26. The article of claim 20 wherein said continuous polymeric film comprises an inner alkali resistant layer, an outer cold water resistant layer, and an intermediate structural layer.

21. A multidose alkaline cleaning article comprising:

(a) a solid detergent composition comprising from about 5 wt-% to 80 wt-% of an alkalinity source and having a pH greater than 10.5 when diluted to a 1 wt-% aqueous solution said detergent comprising a source of alkalinity, said alkalinity source selected from the group consisting of a silicate, an alkali metal hydroxide, a phosphate, a carbonate, and mixtures thereof; and

(b) a continuous multilayer polymeric film having at least a first inner alkaline stable and aqueous soluble layer and a second outer layer resistant to aqueous dissolution and effective in providing mechanical strength, said film is soluble or dispersible in aqueous liquids and covers the solid detergent composition wherein said film remains aqueous soluble or dispersible and mechanically stable after extended exposure to the solid alkaline detergent.

22. The article of claim 21 wherein said polymeric film covers substantially the entirety of the solid detergent composition.

23. The article of claim 21 wherein said continuous polymeric film has a thickness ranging from about 0.6 mil to 15 mil.

24. The article of claim 21 wherein said inner layer and said outer layer are jointed by a plurality of randomly distributed film to film bonds.

25. The article of claim 21 wherein said inner layer and said outer layer are joined by coextensive layer to layer lamination.

27. The article of claim 21 wherein said hydroxide is selected from the group consisting of sodium hydroxide, potassium hydroxide, and mixtures thereof.

28. The article of claim 27 wherein said pH ranges from about 11.5 to about 12.5.

29. The article of claim 21, wherein said alkaline detergent composition comprises a granular solid.

30. The article of claim 29 wherein said granular solid is contained within said continuous polymeric film and formed into a rigid shaped block, said shape selected from the group consisting of a cubed block, a hexagonal block, a cylindrical block, and a cylindrical block comprising a conical surface.

31. The article of claim 21, wherein said alkaline detergent composition comprises a compressed solid.

32. The article of claim 21, wherein said alkaline detergent composition comprises a solid block having a mass of at least 800 grams.

33. The article of claim 32 wherein said solid block comprises a shape said shape selected from the group consisting of a cylindrical block, a hexagonal block, a cube, and a cylindrical block having a conical surface.

34. The article of claim 32 wherein said solid block comprises a grooved side wall.

35. The article of claim 34 wherein said block comprises at least one flat surface having grooves.

36. The article of claim 35 wherein said grooves project radially outward across the flat surface.

37. The article of claim 36 wherein said flat surface is circular in shape and comprises a first set of grooves projecting radially outward from the center of the surface and a second set of grooves concentrically positioned in relationship to the center of the flat surface wherein said first set of grooves and said second set of grooves intersect.

38. The alkaline detergent composition of claim 21 comprising:

(a) a detergent composition comprising;

(i) at least 30 wt-% of an alkaline hydratable chemical said detergent comprising a source of alkalinity, said alkalinity source selected from the group consisting of a silicate, an alkali metal hydroxide, a phosphate, a carbonate, and mixtures thereof;

(ii) an effective amount of hardness sequestering agent;

(iii) water of hydration, at least a portion of said water of hydration being associated with said alkalinity source wherein the alkalinity source and the hardness sequestering agent are present in amounts sufficient to render the detergent solid; and

(b) a multilayer polymeric film covering the detergent composition, said film comprising an inner layer comprising an alkaline stable and aqueous soluble layer, an intermediate layer comprising a layer providing mechanical stability and the outer layer comprising a film that can remain non-tacky and intact when contacted with cold water.

39. The article of claim 38 wherein said hardness sequestering agent is selected from the group consisting of an alkali metal tripolyphosphate salt, a polyacrylic acid or salt thereof, a phosphonic acid or salt thereof, an aminocarboxylic acid or salt thereof, a polycarboxylic acid or salt thereof, and mixtures thereof.

40. The article of claim 38 additionally comprising a surfactant.

41. The article of claim 38 wherein said alkaline source comprises from about 30 wt-% to about 60 wt-% of the composition.

42. The article of claim 38 comprising from about 5 wt-% to 20 wt-% of a chlorine source.

43. A method of using a multidose alkaline cleaning article comprising:

(a) a solid detergent composition having a pH greater than 10.5 when diluted to a 1 wt-% aqueous solution said detergent comprising a source of alkalinity, said alkalinity source selected from the group consisting of a silicate, an alkali metal hydroxide, a phosphate, a carbonate, and mixtures thereof; and

(b) a continuous multilayer polymeric film, dispersible or soluble in aqueous liquids, said multilayer film covering the solid detergent composition and multilayer film comprising an inner alkali pH stable and aqueous soluble film and an outer layer resistant to aqueous dissolution and effective in providing mechanical strength wherein said film remains aqueous soluble or dispersible and mechanically stable after exposure to the solid alkaline detergent, said method comprising the step of applying water to said article to dissolve or disperse a portion of said polymer film and to contact said solid detergent to create a use-dilution solution.

44. The method of claim 43 wherein said alkaline cleaning article comprises a unit dose.

45. The method of claim 43 wherein said alkaline cleaning article comprises a solid alkaline detergent composition capable of more than one use.

46. The method of claim 43 wherein said alkaline cleaning article is used through an automatic dispensing machine.

47. The method of claim 43 wherein said alkaline cleaning article is applied through the manual application of an aqueous solution to the system.

49. The system of claim 44 wherein said polymeric film covers substantially the entirety of the solid detergent composition.

50. The system of claim 44 wherein said continuous polymeric film comprises a vinyl polymer.

51. The system of claim 44 wherein said inner layer and said outer layer are joined by a plurality of randomly distributed film to film bonds.

52. The system of claim 44 wherein said inner layer and said outer layer are joined by coextensive layer to layer lamination.

54. The system of claim 44 wherein said polymeric film has a thickness ranging from about 0.6 mil to about 15 mil.

48. A cleaning system comprising a dispenser and an alkaline cleaning article, said article comprising:

(a) a solid detergent composition having a pH greater than 10.5 when diluted to a 1 wt-% aqueous solution said detergent comprising a source of alkalinity, said alkalinity source selected from the group consisting of a silicate, an alkali metal hydroxide, a phosphate, a carbonate, and mixtures thereof; and

(b) a continuous multilayer polymeric film, dispersible or soluble in aqueous liquids, covering the solid detergent composition, said multilayer film comprising an inner alkali pH stable and aqueous soluble film and an outer layer resistant to aqueous dissolution and effective in providing mechanical strength wherein said multilayer film remains mechanically stable and aqueous soluble or dispersible after exposure to the solid detergent composition.

53. The system of claim 48 wherein said continuous polymeric film comprises an inner alkali stable and aqueous soluble layer, an outer cold water resistant layer, and an intermediate structural layer.

55. The system of claim 53 wherein said polymeric film comprises three layers.