Pressure-sensitive adhesive tape

• US 5,318,835 A
• Filed: 07/21/1992
• Issued: 06/07/1994
• Est. Priority Date: 07/17/1992
• Status: Expired due to Fees

• Current Assignee: Konishi Company Limited
• Original Assignee: Konishi Company Limited
• Inventors: Sawamoto, Akira, Ito, Kiichi, Komemushi, Masakazu
• Primary Examiner(s): Lesmes, George F.
• Assistant Examiner(s): COPENHEAVER, BLAINE R
• Application Number:
  US07/918,212
• Time in Patent Office: 686 Days
• Field of Search: 428/355, 428/317.3, 428/317.7, 428/319.9, 428/343, 525/101, 525/100
• US Class Current: 428/317.7
• CPC Class Codes: C08L 9/00 Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
• CPC Class Codes: C09J 7/26 Porous or cellular plastics
• CPC Class Codes: C09J 7/385 Acrylic polymers
• CPC Class Codes: Y10T 428/249983 As outermost component
• CPC Class Codes: Y10T 428/249985 Composition of adhesive or bonding component specified
• CPC Class Codes: Y10T 428/2852 Adhesive compositions
• CPC Class Codes: Y10T 428/2891 including addition polymer from alpha-beta unsaturated carboxylic acid [e.g., acrylic acid, methacrylic acid, etc.] Or derivative thereof
• CPC Class Codes: Y10T 428/2896 including nitrogen containing condensation polymer [e.g., polyurethane, polyisocyanate, etc.]

Abstract

Disclosed is a pressure-sensitive adhesive tape comprising: a sheet backing composed of polybutadiene foam having a substantially closed cell foam structure; and a layer of pressure-sensitive adhesive composition provided on a surface of the sheet backing. The pressure-sensitive adhesive composition in the present invention comprises: (A) an acrylic copolymer prepared from a mixuture composing: (i) at least one acrylic ester monomer having an alkyl radical containing, on average, 4 to 12 carbon atoms as an alcohol residue; and (ii) polymerizable unsaturated carboxylic acid monomer; (B) a polymer having a hydrolyzable silicon-containing radical; and (C) a polyfunctional isocyanate compound. The adhesive composition of the present invention needs no silanol condensation catalyst.

Claims

1. A flexible pressure-sensitive adhesive tape that can bear a shearing force, comprising:

a sheet backing comprising polybutadiene foam having a substantially closed cell foam structure and having a density within the range of 0.05 to 0.50 g/cm³ ; and

a pressure-sensitive adhesive composition on a surface of the sheet backing, the pressure-sensitive adhesive composition comprising;

(A) an acrylic copolymer prepared from a mixture comprising;

(i) at least one acrylic ester having an alkyl radical containing, on average, 4 to 12 carbon atoms as an alcohol residue; and

(ii) polymerizable unsaturated carboxylic acid, wherein the content of the polymerizable unsaturated carboxylic acid is within the range of 5 to 15 parts by weight relative to 55 to 95 parts of the acrylic ester;

(B) a polymer having a hydrolyzable silicon-containing radical; and

(C) a polyfunctional isocyanate compound,

wherein said adhesive composition is free of a silanol condensation catalyst that is used for the condensation of said hydrolyzable silicon-containing radical.

2. The pressure-sensitive adhesive tape of claim 1, wherein a closed-cell ratio of the polybutadiene foam is within a range of 80 to 100% by volume.

3. The pressure-sensitive adhesive tape of claim 1, wherein the polybutadiene foam has a density within the range of 0.10 to 0.30 g/cm³.

4. The pressure-sensitive adhesive tape of claim 1, wherein, relative to 100 parts by weight of acrylic copolymer (A), the content of polymer (B) is within a range of 1 to 50 parts by weight, and the content of the isocyanate compound (C) is within a range of 0.1 to 5 parts by weight, in the adhesive composition.

5. The pressure-sensitive adhesive tape of claim 4, wherein the adhesive composition further comprises:

not more than 100 parts by weight of tackifier resin (D) relative to 100 parts by weight of acrylic copolymer (A).

6. The pressure-sensitive adhesive tape of claim 1, wherein the alkyl radical as the alcohol residue of the acrylic ester (i) is selected from the group consisting of n-propyl, iso-propyl, n-butyl, see-butyl, ter-butyl, n-octyl, iso-octyl, 2-ethylhexyl and dodecyl.

7. The pressure-sensitive adhesive tape of claim 1, wherein the polymerizable unsaturated carboxylic acid (ii) is selected from the group consisting of acrylic acid, methacrylic acid, crotonic acid, iso-crotonic acid, itaconic acid, maleic acid and fumaric acid.

8. The pressure-sensitive adhesive tape of claim 1, wherein the mixture for the acrylic copolymer further comprises a component which is selected from the group consisting of methyl acrylate, methyl methacrylate, ethyl acrylate, ethyl methacrylate, stylene, vinyl acetate, acrylonitrile, methacrylonitrile, acrylamide, methacrylamide and vinyl propyonate.

9. The pressure-sensitive adhesive tape of claim 1, wherein the hydrolyzable silicon-containing radical of the polymer (B) is a radical containing a silicon atom which is bonded with an element selected from the group consisting of a hydrogen atom, a halogen atom, an alkoxy radical, an acyloxy radical, a ketoxymate radical, an amino radical, an aminoxy radical, an amide radical, an alkenyloxy radical and a mercapto radical.

10. The pressure-sensitive adhesive tape of claim 1, wherein the polymer (B) has a molecular weight within a range of about 300 to 30,000.

11. The pressure-sensitive adhesive tape of claim 1, wherein the polymer (B) has an alkylene oxide chain.

12. The pressure-sensitive adhesive tape of claim 1, wherein the isocyanate compound (C) is selected from the group consisting of 2,4- and 2,6-tolylene diisocyanate, diphenylmethane-4,4'"'"'-diisocyanate, hexamethylene-1,6-diisocyanate, isophorone diisocyanate, hydrogenated diphenylmethane diisocyanate, hydrogenated xylene diisocyanate, lysine trisisocyanate, adduct compounds thereof and a prepolymer having isocyanate terminals.

13. The pressure-sensitive adhesive tape of claim 1, wherein the adhesive composition further comprises:

tackifier resin (D) selected from the group consisting of rosin ester gum, phenolic resin, xylene resin, xylene phenol resin, terpene phenol resin, aromatic resin, petroleum resin, coumarone-indene resin, low molecular weight polystyrene resin and polyterpene resin.

14. The pressure-sensitive adhesive tape of claim 13, wherein the content of the tackifier resin (D) is not more than 100 parts by weight relative to 100 parts by weight of the acrylic copolymer (A).

15. A pressure-sensitive adhesive tape comprising:

a sheet backing comprising a polybutadiene foam material; and

a pressure-sensitive adhesive composition on a surface of the sheet backing, the pressure-sensitive adhesive composition comprising;

(A) an acrylic copolymer prepared from a mixture comprising;

(i) at least one acrylic ester having an alkyl radical containing, on average, 4 to 12 carbon atoms as an alcohol residue; and

(ii) polymerizable unsaturated carboxylic acid, wherein the content of the polymerizable unsaturated carboxylic acid is within a range of 5 to 15 parts by weight relative to 55 to 95 parts of the acrylic ester;

(B) a polymer having a hydrolyzable silicon-containing radical; and

(C) a polyfunctional isocyanate compound,

wherein said adhesive composition is free of a silanol condensation catalyst that is used for the condensation of said hydrolyzable silicon-containing radical.