Laminate with a styrenic polymer layer

• US 5,318,839 A
• Filed: 02/06/1992
• Issued: 06/07/1994
• Est. Priority Date: 02/07/1991
• Status: Expired due to Fees

• Current Assignee: The Dow Chemical Company (Dow, Inc.)
• Original Assignee: Idemitsu Petrochemical Co., Ltd. (Idemitsu Kosan Company Limited)
• Inventors: Maemura, Eiji, Oki, Yuichi, Funaki, Keisuke, Arai, Yosuke
• Primary Examiner(s): SLUBY, PATRICIA
• Application Number:
  US07/831,840
• Time in Patent Office: 852 Days
• Field of Search: 428/516, 428/910, 428/517, 428/329, 428/332, 428/462, 428/512, 427/391
• US Class Current: 428/329
• CPC Class Codes: B32B 2307/514 Oriented
• CPC Class Codes: B32B 2309/02 Temperature
• CPC Class Codes: B32B 2325/00 Polymers of vinyl-aromatic compounds, e.g. polystyrene
• CPC Class Codes: B32B 27/10 of paper or cardboard
• CPC Class Codes: B32B 27/18 characterised by the use of special additives
• CPC Class Codes: B32B 27/302 comprising aromatic vinyl (co)polymers, e.g. styrenic (co)polymers
• CPC Class Codes: B32B 7/12 using interposed adhesives or interposed materials with bonding properties
• CPC Class Codes: Y10S 428/91 Product with molecular orientation
• CPC Class Codes: Y10T 428/257 Iron oxide or aluminum oxide
• CPC Class Codes: Y10T 428/26 Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
• CPC Class Codes: Y10T 428/31696 Including polyene monomers [e.g., butadiene, etc.]
• CPC Class Codes: Y10T 428/31899 Addition polymer of hydrocarbon[s] only
• CPC Class Codes: Y10T 428/31913 Monoolefin polymer
• CPC Class Codes: Y10T 428/31917 Next to polyene polymer

Abstract

There is disclosed a laminate comprising (a) a layer of a styrenic polymer having a higher degree of syndiotactic configuration and a crystallinity of at least 25%, preferably 35%, (b) a layer of paper and optionally (c) an adhesive layer and (d) a barrier layer. The above laminate is excellent in heat resistance, hydrolytic resistance, tearability, dead foldability and gloss and can find a wide range of effective application.

Claims

1. A laminate which comprises (a) a layer of (i) a styrenic polymer having at least 30% racemic pentad and a crystallinity of at least 25% or (ii) a composition consisting essentially of said styrenic polymer and at least one additive selected from the group consisting of inorganic fine particles, antioxidants, antistatic agents, flame retardants, and other resins than said styrenic polymer, said layer having a thickness of 5 to 50 μ

m and (b) a layer of natural paper.

2. The laminate according to claim 1, wherein said styrenic polymer has a crystallinity of at least 35%.

3. The laminate according to claim 1, wherein said layer (a) is an oriented film.

4. The laminate according to claim 1 which is formed by extrusion lamination.

5. The laminate according to claim 4, wherein said other resin is compatible with a styrenic polymer having syndiotactic configuration.

6. The laminate according to claim 5, wherein said other resin is selected from atactic styrenic polymer, isotactic styrenic polymer and polyphenylene ether.

7. The laminate according to claim 1, wherein said other resin is incompatible with a styrenic polymer having syndiotactic configuration.

8. The laminate according to claim 1, further comprising at least one layer selected from adhesive layer (c) and barrier layer (d).

9. The laminate according to claim 8, wherein said adhesive layer (c) comprises at least one member selected from adhesive and adhesive resin.

10. The laminate according to claim 8, wherein said barrier layer (d) comprises at least one member selected from aluminum foil, metallic vapor deposition film and inorganic-oxide vapor deposition film.

11. The laminate according to claim 8, comprising an adhesive layer (c) interposed between said layer (a) and layer (b).

12. The laminate according to claim 8, comprising a barrier layer (d) interposed between said layer (a) and layer (b).

13. The laminate according to claim 8, comprising a barrier layer (d), one side of which is affixed to said layer (b).

14. The laminate according to claim 8, comprising an adhesive layer (c) interposed between said layer (a),and layer (b), and a barrier layer (d), one side of which is affixed to said layer (b).

15. The laminate according to claim 8, comprising a layer (a), layer (c), layer (d), another layer (c) and layer (b) each being superposed in that order.

16. A laminate further improved in heat resistance and dimensional stability, characterized in that said laminate is produced by heat treating the laminate as claimed in claim 1 at 150°

to 260°

C. for 3 to 120 sec.