Process for absorption of sulfur dioxide and nitric oxide from flue gas

• US 5,320,816 A
• Filed: 10/21/1992
• Issued: 06/14/1994
• Est. Priority Date: 10/21/1992
• Status: Expired due to Fees

• Current Assignee: The Dow Chemical Company (Dow, Inc.)
• Original Assignee: The Dow Chemical Company (Dow, Inc.)
• Inventors: Rhymes, Aubrey J. Jr., Tsai, Susan S., Varjian, Richard D., Bedell, Stephen A., Kirby, Larry H.
• Primary Examiner(s): Niebling, John
• Assistant Examiner(s): STARSIAK, JOHN S
• Application Number:
  US07/964,323
• Time in Patent Office: 601 Days
• Field of Search: 204/130, 204/131, 204/149, 204/151, 204/152, 423/235, 423/243.11, 423/243.07
• US Class Current: 423/235
• CPC Class Codes: B01D 53/60 Simultaneously removing sulfur oxides and nitrogen oxides
• CPC Class Codes: B01D 61/145 Ultrafiltration
• CPC Class Codes: B01D 61/243 Dialysis
• CPC Class Codes: B01D 61/44 Ion-selective electrodialysis

Abstract

The simultaneous abatement of NO and SO₂ in flue gas is provided by an absorption process and apparatus utilizing an absorbent composition comprising an aqueous solution of chelates and sulfite salts. Metal chelates oxidized to an inactive state are electrochemically reduced. In the electrochemical cell, nickel or stainless steel anode materials are stable and may be used in the place of platinum coated anode materials when the anolyte pH is maintained greater than 12. At these conditions, the anode is corrosion resistant with a long operating time between replacement. Ultrafiltration or Donnan dialysis may be used to separate the chelate sorbents from the waste salts to reduce the loss of expensive chelate sorbents. Alternatively, an anionic exchange membrane can be used to electrodialytically separate waste sulfur/nitrogen salts from the absorbent solution.

Claims

1. A process for abating nitric oxide and sulfur dioxide from a flue gas, comprising the steps of;

(a) contacting flue gas with an absorbent solution, in an absorption stream comprising a reduced metal chelate and a sulfite to absorb sulfur dioxide and nitric oxide from said flue gas to form an oxidized chelate absorbent solution;

(b) directing said oxidized chelate absorbent solution to a cathode compartment in an electrochemical cell having a corrosion resistant nickel or stainless steel anode in an anolyte solution having a pH greater than 12 in an anode compartment separated by a cationic membrane from a cathode in said cathode compartment and imposing an electrical potential across said anode and said cathode to reduce said oxidized chelates in said cathode compartment to obtain a regenerated absorbent solution; and

(c) recycling said regenerated absorbent solution to said contacting step.

2. The process of claim 1, wherein a molecular ratio of chelant to metal ion is between about 1.2 to about 10 to 1.

3. The process of claim 2, wherein said ratio of chelant to metal ion is between about 2 to about 5 to 1.

4. The process of claim 1, wherein said anode comprises platinum coated titanium or tantalum.

5. The process of claim 1, wherein said membrane comprises a non-ionic exchange membrane.

6. The process of claim 1, further comprising the steps of removing a side stream of said absorbent solution, separating said chelates from soluble waste sulfur/nitrogen salts to reduce said salt concentration in said absorbent and recycling said separated chelates to said absorbent stream.

7. The process of claim 6, wherein said chelates comprise polymeric chelates and said separating step further comprises contacting said side stream absorbent solution with an ultrafiltration membrane wherein said filtrate has a low concentration of said polymeric chelates.

8. The process of claim 6, wherein said separating step further comprises contacting one surface of an anionic Donnan dialysis membrane with said side stream absorbent solution and contacting an opposite surface of said membrane with a dialyzing solution wherein a dialysate has lower concentration of said waste salts.

9. The process of claim 8, wherein said dialyzing solution comprises an aqueous sulfite solution.

10. The process of claim 1, further comprising adjusting said regenerated absorbent solution to a pH of from about 3 to about 8 for said recycling step.

11. An apparatus for the absorption of SO₂ and NO from flue gases comprising;

(a) an absorber column;

(b) an absorbent solution comprising a metal chelate and sulfites; and

(c) an electrochemical cell comprising a nickel or stainless steel anode, an anolyte solution having a pH greater than 12 and a cationic exchange membrane.

12. The apparatus of claim 11, wherein said chelate comprises a polymeric chelate and said apparatus further comprises a housing and an ultrafiltration membrane.

13. The apparatus of claim 11, further comprising a housing, a strong anionic Donnan dialysis membrane, and a sulfite dialyzing solution for separating waste sulfur/nitrogen salts from said absorbent solution.

14. A process for abating nitric oxide and sulfur dioxide from a flue gas, comprising the steps of;

(a) contacting flue gas with an absorbent solution, in an absorption stream comprising a reduced metal chelate and a sulfite to absorb sulfur dioxide and nitric oxide from said flue gas to form an oxidized chelate absorbent solution;

(b) directing said oxidized chelate absorbent solution to a chathode compartment in an electrochemical cell having a corrosion resistant anode in an anolyte solution in an anode compartment separated by a non-ionic membrane from a cathode in said cathode compartment;

(c) imposing an electrical potential across said anode and said cathode to reduce said oxidized chelates in said cathode compartment to obtain a regenerated absorbent solution; and

(d) recycling said regenerated absorbent solution to said contacting step.