Electrochromic structures and methods

• US 5,321,544 A
• Filed: 09/04/1991
• Issued: 06/14/1994
• Est. Priority Date: 09/04/1991
• Status: Expired due to Term

• Current Assignee: Sage Electrochromics, Inc (Compagnie de Saint-Gobain SA)
• Original Assignee: Sun Active Glass Electrochromics Incorporated
• Inventors: Van Dine, John E., Parkhe, V. D., Trumbore, Forrest A.
• Primary Examiner(s): Ben, Loha
• Assistant Examiner(s): Lester, Evelyn A.
• Application Number:
  US07/754,650
• Time in Patent Office: 1,014 Days
• Field of Search: 359/266, 359/275, 359/273, 359/274, 359/265
• US Class Current: 359/273
• CPC Class Codes: G02F 1/1525 characterised by a particular ion transporting layer, e.g. electrolyte
• CPC Class Codes: G02F 1/157 Structural association of cells with optical devices, e.g. reflectors or illuminating devices
• CPC Class Codes: G02F 2202/20 LiNbO3, LiTaO3

Abstract

A chromogenic device with a chromogenic material facing a conductive layer, in which the transmission of incident radiation through the conductive layer and the chromogenic material is enhanced. The enhancement is achieved by adjusting indices of refraction of layers embracing the conductive layer.

Claims

1. An electrochromic device, comprising

an electrochromic structure including an electrode formed from an electrochromic material, a counterelectrode, and transporting means for transporting ions between said electrode and said counterelectrode,

conductive means including at least one layer of an electrically conductive metal for applying an electric potential across said electrochromic structure,

optical means for enhancing the transmission of optical radiation through said electrochromic structure and said at least one electrically conductive metal layer, and

a first intermediate layer formed from a metal and disposed between said electrochromic structure and said at least one electrically conductive metal layer.

2. An electrochromic device as claimed in claim 1, wherein said metal forming said first intermediate layer is selected from the group consisting of nickel, iron, tungsten, zirconium and titanium.

3. An electrochromic device as claimed in claim 1, wherein said first intermediate layer is thinner than said at least one electrically conductive metal layer.

4. An electrochromic device as claimed in claim 3, wherein said first intermediate layer has a thickness of less than about 50 angstroms.

5. An electrochromic device as claimed in claim 1, wherein said electrically conductive metal is selected from the group consisting of silver, aluminum and copper.

6. An electrochromic device as claimed in claim 1, wherein said at least one electrically conductive metal layer has a thickness of less than about 300 angstroms.

7. An electrochromic device as claimed in claim 1, further comprising a second intermediate layer disposed in surface contact with said at least one electrically conductive metal layer so that said at least one electrically conductive metal layer is sandwiched between said first and second intermediate layers.

8. An electrochromic device as claimed in claim 7, wherein said first and second intermediate layers are each formed from a layer or metal which is thinner than said at least one electrically conductive metal layer.

9. An electrochromic device as claimed in claim 8, wherein said metals forming said first and second intermediate layers are different than said electrically conductive metal.

10. An electrochromic device as claimed in claim 1, wherein said optical means comprises at least one layer of an optically transparent material in surface contact with said at least one electrically conductive metal layer.

11. An electrochromic device as claimed in claim 10 wherein said optically transparent material comprises a transparent oxide.

12. An electrochromic device as claimed in claim 11, wherein said optically transparent material is selected from the group consisting of doped zinc oxide, undoped zinc oxide, tungsten oxide, nickel oxide, cobalt oxide, vanadium oxide, titanium oxide, molybdenum oxide, niobium oxide, indium tin oxide, and mixtures thereof.

13. An electrochromic device as claimed in claim 11, wherein said optically transparent material comprises an electrically conductive oxide.

14. An electrochromic device as claimed in claim 10, wherein said optically transparent material has an index of refraction of about 2.0.

15. An electrochromic device as claimed in claim 1, wherein said transporting means includes at least one layer formed from an ion conducting material sandwiched between said electrode and said counterelectrode.

16. An electrochromic device as claimed in claim 15, wherein said ion conducting material comprises a lithium ion conducting lithium-based ceramic material.

17. An electrochromic device as claimed in claim 16, wherein said ion conducting material is selected from the group consisting of lithium silicate, lithium borate, lithium borosilicate, lithium zirconium silicate, lithium aluminum silicate, lithium niobate, lithium nitride and lithium aluminum fluoride.

18. An electrochromic device as claimed in claim 15, wherein said ion conducting material comprises a hydrogen ion conducting material.

19. An electrochromic device as claimed in claim 18, wherein said ion conducting material is selected from the group consisting of tantalum pentoxide and silicon dioxide.

20. An electrochromic device as claimed in claim 15, wherein said ion conducting material comprises a polymer.

21. An electrochromic device as claimed in claim 15, wherein said ion conducting material includes a second material for enhancing ion conductivity.

22. An electrochromic device as claimed in claim 21, wherein said second material is selected from the group consisting of aluminum and titanium.

23. An electrochromic device as claimed in claim 1, wherein said electrochromic material is selected from the group consisting of tungsten oxide, molybdenum oxide, nickel oxide, iridium oxide and mixed oxides of vanadium, tungsten, titanium and molybdenum.

24. An electrochromic device as claimed in claim 1, wherein said counterelectrode is formed from a material selected from the group consisting of vanadium oxide, niobium oxide, indium oxide, iridium oxide, nickel oxide, cobalt oxide, molybdenum oxide and mixtures thereof.

25. An electrochromic combination, comprising

a transparent substrate, and

an electrochromic device arranged on said transparent substrate, said electrochromic device comprising an electrochromic structure including an electrode formed from an electrochromic material, a counterelectrode, and transporting means for transporting ions between said electrode and said counterelectrode, conductive means including at least one layer of a conductive metal for applying an electric potential across said electrochromic structure, optical means for enhancing the transmission of optical radiation through said electrochromic structure and said at least one electrically conductive metal layer, and an intermediate layer formed from a metal and disposed between said electrochromic structure and said at least one electrically conductive metal layer.

26. An electrochromic combination as claimed in claim 25, further comprising a transparent superstrate, wherein said electrochromic device is sandwiched between said transparent substrate and said transparent superstrate.

27. An electrochromic combination as claimed in claim 26, further comprising a layer of an adhesive material for binding said transparent superstrate to said electrochromic device.

28. An electrochromic combination as claimed in claim 27, wherein said adhesive is selected from the group consisting of ethylene vinylacetate and polyvinyl butyral.