Resid hydrotreating catalyst and process

• US 5,322,829 A
• Filed: 03/15/1993
• Issued: 06/21/1994
• Est. Priority Date: 03/15/1993
• Status: Expired due to Term

• Current Assignee: Amoco Corporation (BP PLC)
• Original Assignee: Amoco Corporation (BP PLC)
• Inventors: Artes, David C., Kukes, Simon G.
• Primary Examiner(s): Sneed, Helen M. S.
• Assistant Examiner(s): MC GINTY, DOUGLAS J
• Application Number:
  US08/031,656
• Time in Patent Office: 463 Days
• Field of Search: 502/254, 502/255, 502/256, 502/257, 502/314, 502/315, 502/439
• US Class Current: 502/315
• CPC Class Codes: B01J 23/755 Nickel
• CPC Class Codes: B01J 23/85 Chromium, molybdenum or tungsten
• CPC Class Codes: B01J 35/613 10-100 m2/g
• CPC Class Codes: B01J 35/615 100-500 m2/g
• CPC Class Codes: B01J 35/635 0.5-1.0 ml/g
• CPC Class Codes: B01J 35/638 more than 1.0 ml/g
• CPC Class Codes: B01J 35/647 2-50 nm
• CPC Class Codes: B01J 35/66 Pore distribution
• CPC Class Codes: C10G 45/08 in combination with chromium, molybdenum, or tungsten metals, or compounds thereof

Abstract

A catalyst and process are disclosed for upgrading heavy feedstocks such as resid. The catalyst comprises a porous inorganic oxide support having an incremental pore volume maximum at a pore radius greater than 50 Angstroms bearing between 0.1 to 5.0 weight percent nickel and having at least 0.4 cc/g of pores having a radius less than 125 Angstroms. An ebullated bed hydroconversion process employing the catalyst also is disclosed.

Claims

1. A resid hydroprocessing catalyst for use in an ebullated bed hydroprocessing reactor consisting essentially of

a porous inorganic oxide support having a total surface area of greater than about 150 square meters per gram, a total pore volume of between 0.8 and 1.4 cc/g, a pore volume of greater than 0.4 cc/g of pores having a radius less than 125 Angstroms, and an incremental pore volume maximum at a pore radius greater than about 50 Angstroms;

between 1 and 15 weight percent of a Group VIB metal measured as an oxide deposited on the support; and

between 0.1 and 5 weight percent of nickel measured as an oxide deposited on the support.

2. The catalyst of claim 1 wherein the pore volume of pores having a radius of less than 125 Angstroms is at least 0.6 cc/g.

3. The catalyst of claim 1 wherein the incremental pore volume maximum is located at a radius between 50 Angstroms and 100 Angstroms.

4. The catalyst of claim 1 wherein the incremental pore volume maximum is between about 50 and 60 Angstroms.

5. The catalyst of claim 1 wherein the weight percent of nickel deposited on the support is between 0.4 and 0.9 weight percent.

6. The catalyst of claim 1 wherein the Group VIB metal is molybdenum and the weight percent of the molybdenum deposited on the support is between about 3.0 and 5.2 weight percent and wherein the weight percent of nickel deposited on the support is between about 0.4 and 0.9 weight percent.

7. The catalyst of claim 6 wherein the pore volume of pores having a radius of less than 125 Angstroms is at least 0.6 cc/g.

8. The catalyst of claim 1 wherein the surface area of the catalyst is between about 160 and 210 square meters per gram.

9. A resid hydroprocessing catalyst for use in an ebullated bed hydroprocessing reactor consisting essentially of:

a porous inorganic oxide support having a total surface area of between about 160 and 210 square meters per gram, a total pore volume of between 1.0 and 1.4 cc/g, a pore volume of greater than 0.4 cc/g of pores having a radius less than 125 Angstroms, a pore volume of less than 0.3 cc/g of pores having a radius between 125 and 750 Angstroms, a pore volume between about 0.7 and 0.95 cc/g of pores having a radius less than about 600 Angstroms, a pore volume between about 0.2 and 0.35 cc/g of pores having a radius greater than about 600 Angstroms, and an incremental pore volume maximum at a pore radius of between about 50 and 80 Angstroms;

between 1.0 and 5.2 weight percent of a molybdenum measured as an oxide deposited on the support; and

between 0.4 and 0.9 weight percent of a nickel measured as an oxide deposited on the support.

10. The catalyst of claim 9 wherein the pore volume of pores having a radius of less than 125 Angstroms is at least 0.6 cc/g.

11. The catalyst of claim 9 wherein the pore volume of pores having a radius of less than 125 Angstroms is between about 0.7 and 0.9 cc/g.

12. The catalyst of claim 10 wherein the weight percent of molybdenum deposited on the support is between about 3.0 and 5.2 weight percent.

13. The catalyst of claim 10 wherein the incremental pore volume maximum is between about 50 and 60 Angstroms.