Multilayer laminated film having an improved gas barrier action

• US 5,324,572 A
• Filed: 07/10/1992
• Issued: 06/28/1994
• Est. Priority Date: 07/12/1991
• Status: Expired due to Fees

• Current Assignee: Hoechst Aktiengesellschaft (Sanofi )
• Original Assignee: Hoechst Aktiengesellschaft (Sanofi )
• Inventors: Kuechler, Manfred, Reinhard, Guenter
• Primary Examiner(s): Buffalow, Edith
• Application Number:
  US07/911,913
• Time in Patent Office: 718 Days
• Field of Search: 428/515, 428/518, 428/215, 428/520, 428/473.5, 428/911 O
• US Class Current: 428/215
• CPC Class Codes: B32B 1/00 Layered products having a non-planar shape
• CPC Class Codes: B32B 2307/718 Weight, e.g. weight per square meter
• CPC Class Codes: B32B 2307/7242 Non-permeable
• CPC Class Codes: B32B 2307/7246 Water vapor barrier
• CPC Class Codes: B32B 2307/746 Slipping, anti-blocking, low friction
• CPC Class Codes: B32B 2309/02 Temperature
• CPC Class Codes: B32B 2309/105 Thickness
• CPC Class Codes: B32B 27/08 of synthetic resin
• CPC Class Codes: B32B 27/18 characterised by the use of special additives
• CPC Class Codes: B32B 27/30 comprising vinyl (co)polymers; comprising acrylic (co)polymers
• CPC Class Codes: B32B 27/306 comprising vinyl acetate or vinyl alcohol (co)polymers
• CPC Class Codes: B32B 7/12 using interposed adhesives or interposed materials with bonding properties
• CPC Class Codes: Y10S 428/91 Product with molecular orientation
• CPC Class Codes: Y10T 428/24967 Absolute thicknesses specified
• CPC Class Codes: Y10T 428/31721 Of polyimide
• CPC Class Codes: Y10T 428/31909 Next to second addition polymer from unsaturated monomers
• CPC Class Codes: Y10T 428/3192 Next to vinyl or vinylidene chloride polymer

Abstract

Production or multilayer laminated films which can be subjected to thermoplastic shaping and have an improved gas barrier action, consisting of at least one gas barrier film based on highly hydrolyzed, plasticizer-containing polyvinyl alcohol with, on one side or both sides, covering films of plastic which are insoluble in water, impermeable to water and water vapor and if appropriate insoluble in organic solvents and which are laminated to the gas barrier film over the entire surface by means of special adhesive layers which have pressure-sensitive adhesive properties. The adhesive layers consist of copolymers having a glass transition temperature T_G in the range from -50° to -10° C. The gas barrier film can be produced by extrusion blow molding. The blown film bubble is cut open and coated, at room temperature as a flat film, with the adhesive layer on both sides via applicator rolls, dried and deshrunk by conditioning. The resulting self-adhesive gas barrier film is then laminated with covering films of plastic by means of laminating rolls or on a calender to give a multilayer film laminate which is practically impermeable to water and gas and if appropriate solvent-tight.

Use of the multilayer laminated films for water- and gas-tight, in particular oxygen-tight, water vapor-tight, aroma-tight and if appropriate solvent-tight packaging or wrapping of various products.

Claims

1. A multilayer laminated film which can be subjected to thermoplastic shaping and has an improved gas barrier action, consisting of at least one gas barrier film based on polyvinyl alcohol (PVAL) which is laminated on at least one side with a polymer film which is water-insoluble and optionally insoluble in organic solvents as a barrier layer against water and water vapor, optionally for the multilayer laminated film to comprise several identical or different gas barrier films having intermediate layers of polymer films which block water and water vapor, wherein the gas barrier film comprises highly hydrolyzed PVAL and is laminated on at least one side with the polymer film(s) which block(s) water and water vapor and is/are water-insoluble and optionally insoluble in organic solvents via an adhesive layer which has pressure-sensitive adhesive properties and is impermeable to water and water vapor.

2. A multilayer laminated film as claimed in claim 1, wherein the gas barrier film has a layer thickness in the range from 10 to 100 μ

m and comprises PVAL which has an ester number of <

10 mg of KOH/g, a degree of hydrolysis of >

98 mol %, a residual acetyl group content of <

1% by weight and an average DP_W of >

1500, in each case based on the PVAL.

3. A multilayer laminated film as claimed in claim 1, which contains, as gas barrier films, plasticizer-containing PVAL extruded blown films which have been produced from preplasticized, plasticizer-containing PVAL dry blends by extrusion and have contents of 5 to 50% by weight of aliphatic C₂ - to C₆ -polyols or oligomeric poly(C₂ -C₆)-alkylene glycol ether-polyols as plasticizer and up to 5% by weight of water and up to 12% by weight of flow auxiliary and up to 1% by weight of antiblocking agent, in each case based on the PVAL.

4. A multilayer laminated film as claimed in claim 1, in which the pressure-sensitive adhesive layers are applied, before production of the film laminate, to at least one side of the gas barrier films as a solution in an organic solvent or as an aqueous dispersion by spraying, rolling or knife-coating, or in bulk by the hot melt process, and are dried and the gas barrier films are deshrunk by heat treatment at not less than 80°

C.

5. A multilayer laminated film as claimed in claim 1, which comprises as pressure-sensitive adhesive layers, at least one member of the group consisting of pure acrylate copolymers and vinyl ester/acrylate copolymers, the glass transition temperature T_g of which is in each case in the range from -50 to -10°

C.

6. A multilayer laminated film as claimed in claim 1, which comprises, as the water-insoluble polymer films which block water and water vapor, polypropylene films, which can be oriented biaxially and insoluble in organic solvents at room temperature, polyvinylidene chloride films or polyamide films.

7. A multilayer laminated film as claimed in claim 1, in which the total thickness is in the range from 100 to 500 μ

m and which can be transparent to opaque, and pigmented or dyed or printed in a translucent or opaque manner.

8. A multilayer laminated film as claimed in claim 1, which has an oxygen permeability, measured in accordance with DIN 53380, at 93% relative atmospheric humidity of >

2 cm³ /m².d.bar.