Hot melt adhesive composition that melts at relatively low temperatures

• US 5,326,413 A
• Filed: 11/19/1990
• Issued: 07/05/1994
• Est. Priority Date: 11/19/1990
• Status: Expired due to Fees

• Current Assignee: Pearle, Inc. (EssilorLuxottica SA)
• Original Assignee: Pearle, Inc. (EssilorLuxottica SA)
• Inventors: Gumbs, Ronald W., Esemplare, Pascal E.
• Primary Examiner(s): Gallagher, John J.
• Application Number:
  US07/615,613
• Time in Patent Office: 1,324 Days
• Field of Search: 156/154, 156/327, 156/305, 156/344, 156/155, 51/284 R, 51/216 LP, 524/277, 524/487
• US Class Current: 156/154
• CPC Class Codes: B24B 13/0052 Lens block moulding devices
• CPC Class Codes: B29D 11/00932 Combined cutting and grinding thereof
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 2666/04 Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
• CPC Class Codes: C09J 123/08 Copolymers of ethene C09J123/16 takes precedence
• CPC Class Codes: C09J 191/06 Waxes
• CPC Class Codes: Y10T 156/1153 Temperature change for delamination [e.g., heating during delaminating, etc.]

Abstract

Novel lower temperature hot melt adhesive and coating composition that melts at temperatures less than 190° F. (about 87.8° C). This composition has a sufficient modulus to bind ophthalmic lenses to metal blocks during grinding processes. The composition also exhibits low melt viscosity and may be mechanically removed without leaving significant residue. Composition comprises a resin, a tackifier, a wax (generally with a molecular weight less than 600), and an optional stabilizer.

Claims

1. A method of mounting an ophthalmic lens for grinding, which comprises:

mounting the lens on a block such that a cavity results between the block and the lens;

filling the cavity between the lens and the block with a liquid hot melt adhesive at a temperature less than 190°

F. (87.8°

C.), the hot melt adhesive comprising 15-30 weight percent of a resin having a melt index of 300-500 dg/min per ASTM D1238, 15-30 weight percent of a wax having a Ring and Ball softening temperature between about 135°

-160°

F. (about 57°

-71°

C.), and 40-60 weight percent of a tackifier, and wherein the adhesive is strong enough to bind the lens to the block during grinding of the lens;

cooling the adhesive sufficient to bond the lens to the block.

2. The method of claim 1, further comprising the step of grinding the lens.

3. The method of claim 2, further comprising the step of releasing the ground lens from the block and the adhesive.

4. The method of claim 3, wherein no significant residue from the adhesive remains on the lens after it is released.

5. A hot melt adhesive composition, comprising:

15-30 weight percent of a resin having a melt index of 300-50 dg/min per ASTM D1238;

1- 30weight percent of a wax having a Ring and Ball softening temperature between about 135°

-160°

F. (about 57°

-71°

C.), a molecular weight of less than 600, and a melt viscosity of 100-50 cp at 150°

F. (about 66°

C.);

40-60 weight percent of a tackifier; and

the composition being tacky, having a Ring and Ball softening temperature less than 190°

F. (87.8°

C.),

and being sufficiently strong and adhesive to bind an ophthalmic lens to a substrate during grinding of the lens.

6. A composition as in claim 5 wherein aid composition has a Ring and Ball softening temperature of less than 175°

F. (about 79.4°

C.).

7. A composition as in claim 5 wherein said composition has a Ring and Ball softening temperature of less than 165°

F. (about 73.9°

C.).

8. A composition as in claim 5 wherein said composition has a Ring and Ball softening temperature of less than 150°

F. (about 65.6°

C.).

9. A composition as in claim 5 wherein the wax has a molecular weight of less than 450.

10. A composition as in claim 5 wherein said composition has a melt viscosity of between 1,000 and 90,000 centipoise at 150°

F. (about 65.6°

C.).

11. A composition as in claim 5 wherein said composition has a melt viscosity of between 1,000 and 25,000 centipoise at 150°

F. (about 65.6°

C.).

12. A composition as in claim 5 wherein said composition has a melt viscosity of between 5,000 and 15,000 centipoise at 150°

F. (about 65.6°

C.).

13. A composition as in claim 5 wherein said resin comprises a copolymer of ethylene and a second chemical component, and said second component is vinyl acetate, acrylic acid, methacrylic acid, vinyl acetate and acrylic acid mixed together, vinyl acetate and methacrylic acid mixed together, an unsaturated carboxylic acid capable of reacting with ethylene, vinyl acetate and an unsaturated carboxylic acid capable of reacting with ethylene mixed together, itaconic acid, vinyl acetate and itaconic acid mixed together, fumaric acid, fumaric acid and vinyl acetate mixed together, maleic acid, maleic acid and vinyl acetate mixed together, or mixtures thereof.

14. A composition as in claim 13 wherein said second component comprises 18-40 wt. % of said copolymer.

15. A composition as in claim 13 wherein said second component comprises 25-33 wt. % of said copolymer.

16. A composition as in claim 5 wherein the resin comprises a copolymer of ethylene and a vinyl ester of a carboxylic acid having from one to four carbon atoms.

17. A composition as in claim 5 wherein the resin comprises a copolymer of ethylene and an alkyl ester of acrylic or methacrylic acid wherein the alkyl group has one to five carbon atoms.

18. A composition as in claim 5 wherein the resin comprises a terpolymer of ethylene, a vinyl ester of a C_1-4 carboxylic acid, and a mono or di-unsaturated monomer.

19. A composition as in claim 13 wherein 0-50 wt. % of the resin further comprises a terpolymer, and the terpolymer is:

ethylene, vinyl acetate and acrylic acid;

ethylene, vinyl acetate and methacrylic acid;

ethylene, vinyl acetate and an unsaturated carboxylic acid capable of reacting with ethylene;

ethylene, vinyl acetate and fumaric acid;

ethylene, vinyl acetate and maleic acid;

ethylene, vinyl acetate and itaconic acid;

or mixtures thereof.

20. A composition as in claim 5 wherein the wax has a Ring and Ball softening point of between 140°

-155°

F. (about 60°

-68.3°

C.).

21. A composition as in claim 5 wherein the wax has a Ring and Ball softening point of between 140°

-145°

F. (about 60°

-62.8°

C.).

22. A composition as in claim 5 wherein the wax comprises a natural or synthetic wax.

23. A composition as in claim 22 wherein the wax is mineral wax paraffin, microcrystalline, petrolatum, vegetable wax, carnauba, candelilla, Japan, animal wax, spermaceti, insect wax, beeswax, synthetic wax, Fischer-Tropsch hydrocarbon wax, cetyl fatty alcohol, stearyl fatty alcohol, stearic fatty acid, palmitic fatty acid, myristic fatty acid, polyglycols, fatty acids, fatty alcohols, or fully refined mineral wax.

24. A composition as in claim 5 wherein the tackifier is a modifying resin, and the modifying resin is a rosin, a rosin ester, a zinc resinate, a polyterpene, a terpene, a phenolic, an aliphatic hydrocarbons, an aromatic hydrocarbons, coumaroneindene, or a phenolic modified coumarone-indene.

25. A composition as in claim 5 wherein the resin comprises 20-30 wt. % of the composition, the tackifier comprises 48-56 wt. % of the composition, and the wax comprises 20-30 wt. % of the composition.

26. A composition as in claim 5, further comprising a stabilizer.

27. A composition as in claim 26 wherein the stabilizer is an antioxidant.

28. A composition as in claim 26 wherein the stabilizer is a hindered phenol, a phosphite derivative, or butylated hydroxy toluene.

29. A composition as in claim 5 wherein:

the resin comprises an ethylene-vinyl acetate copolymer and the vinyl acetate comprises 25-33 wt. % of the copolymer;

the wax comprises paraffin and;

the tackifier comprises polyterpene resin

30. A method for manufacturing the composition in claim 5 comprising the steps of:

melting the wax;

adding the resin;

adding the tackifier;

mixing; and

pouring into a container and cooling.

31. A method of manufacturing the composition in claim 30, further comprising adding a stabilizer.

32. The composition of claim 5 wherein the composition is mechanically removable from the lens after grinding without substantially distorting the lens.

33. The composition of claim 5 wherein the composition is mechanically removable from the lens after grinding without leaving a significant residue on the lens.

34. A method of using the composition of claim 5 to adhere two substrate together comprising the steps of:

heating the composition until liquid;

applying the composition to at least one of the substrates desired to be adhered together;

contacting the substrates such that the composition contacts both substrate; and

cooling the composition until hardened.

35. The method of claim 34 wherein the substrate are a plastic and a metal.

36. The method of claim 31 wherein the plastic comprises an ophthalmic lens.

37. The method of claim 34, further comprising the step of separating the surfaces by reheating the composition or the surfaces.

38. The method of claim 34, further comprising the step of mechanically separating the surfaces.

39. The method of claim 38 wherein the separation of the surfaces is achieved by applying a force to one of the surfaces while preventing the other surface(s) from moving.

40. The method of claim 34 wherein at lest one of said surfaces comprises at least one ophthalmic lens.

41. A method of mounting a synthetic ophthalmic lens for grinding, which comprises:

mounting the synthetic lens on a block;

filling the cavity between the lens and the block with the hot melt adhesive from claim 5;

cooling the adhesive sufficiently to bond the lens to the block.

42. A hot melt adhesive composition, consisting essentially of:

15-30 weight percent of a resin having a melt index of 300-500 dg/min per ASTM D1238;

15-30 weight percent of a wax having a Ring and Ball softening temperature between about 135°

-160°

F. (about 57°

-71°

C.); and

40-60 weight percent of a tackifier, and wherein the composition has a Ring and Ball softening temperature less than 190°

F. (87.8°

C.), wherein the composition is tacky and sufficiently strong and adhesive to bind an ophthalmic lens to a substrate during grinding of the lens.

43. A composition as in claim 42 wherein the tacky composition may be mechanically removed from the lens without substantial distortion of the lens and without leaving a significant residue on the lens.