Process for preparing a hydrolysed lingnocellulosic material

• US 5,328,562 A
• Filed: 05/09/1990
• Issued: 07/12/1994
• Est. Priority Date: 05/11/1989
• Status: Expired due to Fees

• Current Assignee: Convertech Group Limited
• Original Assignee: Convertech Group Limited
• Inventors: Scott, Kenneth E., Rafferty, Andrew J.
• Primary Examiner(s): Jones, W. Gary
• Assistant Examiner(s): NGUYEN, TAN D
• Application Number:
  US07/520,198
• Time in Patent Office: 1,525 Days
• Field of Search: 162/68, 162/21, 162/247, 162/47, 241/5, 127/36, 127/37
• US Class Current: 162/21
• CPC Class Codes: B27N 1/00 Pretreatment of moulding material
• CPC Class Codes: C08H 8/00 Macromolecular compounds derived from lignocellulosic materials pretreatment thereof B27N
• CPC Class Codes: C08L 97/02 Lignocellulosic material, e.g. wood, straw or bagasse manufacture of articles made from lignocellulosic material by dry processes B27N
• CPC Class Codes: D21B 1/36 Explosive disintegration by sudden pressure reduction
• CPC Class Codes: D21C 1/02 with water or steam
• CPC Class Codes: D21C 1/10 Physical methods for facilitating impregnation

Abstract

An energy efficient process for hydrolyzing lignocellulosic materials which comprises using a primary system by providing a start-up energy input to operating saturated steam conditions and thereafter operating the primary system with substantially constant energy input, the condition of the hydrolysing saturated steam being controlled by water injection and/or steam bleeding from the primary system. The dwell time of the solids stream in the primary system is controlled by controlling its passage with flashing off of steam into a secondary system where drying occurs together with some small measure of hydrolysis in a lower pressure superheated steam environment, there being an energy input into the secondary system using steam bled from the primary system. The output solids material stream is preferably capable of being self polymerized into a formed shape eg a board.

Claims

1. A process for the production of substantially dry, hydrolyzed lignocellulosic material from a source thereof which comprises:

providing and maintaining a primary hydrolysis reaction zone at a temperature and a pressure sufficient to cause and support the hydrolysis of lignocellulosic material therein;

providing saturated steam at said temperature and pressure in said primary hydrolysis zone;

feeding hydrolyzable lignocellulosic material to said primary hydrolysis zone and bringing said lignocellulosic material to said hydrolysis conditions therein;

hydrolyzing said lignocellulosic material in said primary hydrolysis zone by contact with said saturated steam at a sufficient residence time to form a stream comprising steam and hydrolysis products;

bringing said stream to an outlet of said primary hydrolysis zone;

separating substantially hydrolyzed products of said lignocellulose from steam at said outlet, and feeding heated hydrolysis products, substantially separated from steam, to a secondary zone;

maintaining said secondary zone at a pressure lower than the pressure in said primary zone;

providing superheated steam bled from said primary zone in said secondary zone at a temperature and a pressure sufficient to dry said hydrolysis products;

allowing said heated hydrolysis products to flash upon introduction into said lower pressure secondary zone, in effective contact with said superheated steam, whereby reducing the water content of said hydrolysis products and increasing the water content of said superheated steam; and

recovering dried hydrolysis products of said lignocellulose material.

2. A process as claimed in claim 1 including adjusting the saturated steam conditions in said primary hydrolysis zone by at least one means selected from the group consisting of:

controlling the amount of lignocellulosic material fed thereto;

controlling the moisture content of said fed lignocellulosic solids;

providing separate water feed to said primary hydrolysis zone; and

bleeding off excess steam from said primary hydrolysis zone.

3. A process as claimed in claim 1 including starting up said process by feeding water to said primary hydrolysis zone, preheating and pressurizing said water to said saturated steam;

and then feeding said hydrolyzable lignocellulosic solids to said heated and pressurized primary hydrolysis zone containing saturated steam.

4. The process as claimed in claim 1 including passing said stream comprising said hydrolysis product from said primary hydrolysis zone to said secondary drying zone through a variable speed, closed screw means.

5. The process as claimed in claim 4 including at least partially controlling the residence time of said lignocellulosic solids in said priamry zone by controlling the speed of rotation of said screw means.

6. The process as claimed in claim 1 including bleeding steam from said primary hydrolysis zone, and at least partially heating said secondary drying zone with said bled steam.

7. The process as claimed in claim 6 including heating said secondary zone solely by means of heat introduced in said hydrolysis product being fed thereto and by means of said bled steam.

8. The process as claimed in claim 1 including separating steam from solid hydrolysis products in said stream by feeding said stream to a cyclone separation means, and feeding the solid products of said cyclonic separation to said screw transfer

9. The process as claimed in claim 1 including passing the product exiting from said screw means through a pressure reducing means prior to feeding said exiting to said secondary drying zone.

10. The process as claimed in claim 1 including recovering said dried hydrolysis product by feeding the product produced by said drying to a cyclone separation means, and therein separating solid dried hydrolysis products from steam.

11. The process as claimed in claim 1 including the further step of pressing the product recovered from said secondary drying zone, comprising dried solid hydrolysis product of lignocellulose, at a temperature which supports the polymerization of components of said dried solid hydrolysis product, into a polymerized shaped article.

12. The process as claimed in claim 11 including adding substantially nothing to said dried hydrolysis product before and during polymerization thereof.

13. The process as claimed in claim 12 wherein said polymerization produces a shaped article which consists essentially of said dried hydrolysis product.

14. The process as claimed in claim 1 including blowing the materials in said primary hydrolysis zone by fan means.

15. The process as claimed in claim 1 including blowing the materials in said secondary drying zone by fan means.

16. In the process for the production of substantially dry, hydrolyzed lignocellulosic material from a source thereof which comprises:

providing and maintaining a primary hydrolysis reaction zone at a temperature and a pressure sufficient to cause and support the hydrolysis of lignocellulosic material therein;

providing saturated steam at said temperature and pressure in said primary hydrolysis zone;

feeding hydrolyzable lignocellulosic material to said primary hydrolysis zone and bringing said lignocellulosic material to said hydrolysis conditions therein;

hydrolyzing said hydrolyzable lignocellulosic material in said primary hydrolysis zone by contact with said saturated steam at a sufficient residence time to form a stream comprising steam and hydrolysis products;

bringing said stream to an outlet of said primary hydrolysis zone;

separating substantially hydrolyzed products of said lignocellulose from steam at said outlet, and feeding heated hydrolysis products, substantially separated from steam, to a secondary zone;

maintaining said secondary zone at a pressure lower than the pressure in said primary zone;

providing superheated steam bled from said primary zone in said secondary zone in effective contact with said flashed hydrolysis products at a temperature and a pressure sufficient to substantially dry said hydrolysis products;

allowing said heated hydrolysis products to flash upon introduction into said lower pressure secondary zone, whereby reducing the water content thereof and increasing the water content of said superheated steam;

recovering said dried hydrolysis products of lignocellulose;

the method of controlling the energy in the system which comprises;

introducing heat into said primary hydrolysis zone by heat exchange with a heat transfer fluid which has been externally heated;

preheating said primary hydrolysis zone by contact with said externally heated fluid for a time sufficient to bring said primary zone to a temperature and a pressure sufficient to support and maintain the hydrolysis of hydrolyzable solid lignocellulosic material;

after introduction of said hydrolyzable lignocellulosic material to said primary hydrolysis zone, maintaining said primary hydrolysis zone in substantial energy steady state by at least one of the following means;

contact with further quantities of externally heated heat transfer fluid, addition of liquid water to said primary hydrolysis zone, bleeding steam from said primary hydrolysis zone, and removing solid, hot, hydrolyzed lignocellulosic material from said primary hydrolysis zone;

providing at least part of said superheated steam in said second drying zone by flashing steam from the product of said primary hydrolysis zone during transfer thereof from said primary to said secondary zone; and

at least partially maintaining the steam in said secondary drying zone in a superheated condition by heating such with a heat exchange fluid, and bleeding superheated steam from said secondary drying zone.

17. The system as claimed in claim 16 wherein said heat exchange fluid in contact with said second drying zone is steam bled from said primary hydrolysis zone.

18. The system as claimed in claim 17 including bleeding sufficient steam from said primary hydrolysis zone to use only a portion thereof as said heat exchange fluid heating said second drying zone.

19. The process as claimed in claim 16 including the further step of pressing the product recovered from said secondary drying zone, comprising dried solid hydrolysis product of said lignocellulosic material, at a temperature which supports the polymerization of components of said dried solid hydrolysis product, and thereby polymerizing said components into a polymerized shaped article.

20. The process as claimed in claim 19 including adding substantially nothing to said dried hydrolysis product before and during polymerization thereof.