Device and method for sensing water and/or acid in the presence of water in non-aqueous media

• US 5,331,287 A
• Filed: 07/31/1992
• Issued: 07/19/1994
• Est. Priority Date: 07/31/1992
• Status: Expired due to Term

• Current Assignee: Hughes Electronics Corporation (AT&T, Inc.)
• Original Assignee: Hughes Aircraft Company (Rtx Corporation)
• Inventors: Van Ast, Camille, Yamagishi, Frederick G., Miller, Leroy J.
• Primary Examiner(s): Strecker, Gerard R.
• Assistant Examiner(s): DO, DIEP N
• Application Number:
  US07/922,899
• Time in Patent Office: 718 Days
• Field of Search: 324/439, 324/446, 324/693, 324/694, 324/698, 324/722, 324/724, 204/421, 73/53.04, 73/61.44, 340/602, 340/604, 340/438, 340/603
• US Class Current: 324/724
• CPC Class Codes: G01N 27/121 for determining moisture content, e.g. humidity, of the fluid moisture content of the tested material G01N27/048
• CPC Class Codes: G01N 27/126 comprising organic polymers
• CPC Class Codes: G01N 33/2847 Water in oils
• CPC Class Codes: G01N 33/2888 Lubricating oil characteristics, e.g. deterioration lubricating properties G01N33/30

Abstract

A sensor for monitoring the water content and the acid content in the presence of water in nonaqueous media can be incorporated into a monitoring system for monitoring the quality of nonaqueous fluids in equipment or vehicles. The sensor comprises an insulating substrate; electrodes formed on the substrate in an interdigitated pattern; and a conductive polymer deposited over the interdigitated electrodes which bridges between adjacent digits of the electrodes. The monitoring system incorporating the sensor comprises a control module for measuring the conductivity of the sensor. The control module is preprogrammed to compare the measured conductivity to a predetermined level indicative of an unacceptable level of degradation. The sensor is made by depositing electrodes on an insulating substrate; depositing a conductive polymer over the electrodes in an amount sufficient to bridge between the electrodes; and neutralizing the conductive polymer to an insulating form. A method of sensing water and acid in the presence of water in nonaqueous media exposes an insulating form of a conductive polymer to a nonaqueous medium and monitors the conductivity of said conductive polymer, as the nonaqueous medium is used. The conductive polymer reversibly increases conductivity in measurable amounts with increasing acid and/or water content due to protonation by the acid or hydration by the water.

Claims

1. A device for sensing water content in a nonaqueous medium comprising:

an insulating substrate;

interdigitated electrodes deposited on said substrate; and

an insulating form of a conductive polymer, the conductive polymer deposited over the interdigitated electrodes to bridge between adjacent digits of the electrodes, wherein the insulating form is converted to its conductive form by hydration with the water to provide a current which is proportional to the amount of water and which is measurable.

2. The device for sensing according to claim 1, wherein the conductive polymer is selected from the group consisting of polyaniline and the alkyl- and alkoxy- substituted derivatives of polyaniline.

3. The device for sensing according to claim 1, wherein the conductive polymer is an insulating form of polyaniline.

4. A device for sensing acid content in the presence of water in a nonaqueous medium comprising:

an insulating substrate;

interdigitated electrodes deposited on said substrate; and

an insulating form of a conductive polymer, the conductive polymer deposited over the interdigitated electrodes to bridge between adjacent digits of the electrodes, wherein the insulating form is converted to its conductive form by protonation with the acid and hydration with the water to provide a current which is proportional to the amount of acid and which is measurable.

5. The device for sensing according to claim 4, wherein the conductive polymer is selected from the group consisting of polyaniline and the alkyl- and alkoxy- substituted derivatives of polyaniline.

6. The device for sensing according to claim 4, wherein the conductive polymer is an insulating form of polyaniline.

7. A method of sensing water content and acid content in the presence of water in nonaqueous media comprising the steps of:

exposing an insulating form of a conductive polymer to a nonaqueous medium, the conductive polymer being deposited over interdigitated electrodes deposited on an insulating substrate, the conductive polymer reversibly increasing conductivity by protonation with the acid and hydration with the water; and

monitoring the conductivity of said conductive polymer.

8. The method of claim 7, wherein the step of exposing comprises:

exposing a conductive polymer selected from the group consisting of polyaniline and alkyl- and alkoxy-substituted derivatives of polyaniline deposited on an insulating substrate over interdigitated electrodes; and

the step of monitoring comprises measuring the conductivity between the interdigitated electrodes.

9. The method of claim 7, wherein the step of exposing comprises exposing an insulating form of polyaniline to the nonaqueous media.

10. A monitoring system for monitoring water content and acid content in the presence of water in nonaqueous media comprising:

a sensor mounted to be exposed to the nonaqueous media comprising;

an insulating substrate;

electrodes formed on the substrate each having an interdigitated portion; and

an insulating form of a conductive polymer, the conductive polymer deposited over the interdigitated portion of the electrodes as a thin film in an amount sufficient to bridge between adjacent digits, the insulating form being converted to its conductive form by protonation with the acid and hydration with the water in the nonaqueous media to provide a current which is proportional to the amount of acid and to the amount of water and which is measurable;

control means for measuring the conductivity of the sensor, the control means being capable of indicating when the conductivity reaches a predetermined level;

warning means for providing an indication when the predetermined level is reached; and

means for interconnecting the sensor and the warning means to the control means.

11. The monitoring system of claim 10, wherein the conductive polymer is selected from the group consisting of polyaniline and alkyl- and alkoxy-substituted derivatives of polyaniline.

12. The monitoring system of claim 10, wherein the conductive polymer is polyaniline.

13. An automotive monitoring system for monitoring water content and acid content in the presence of water in a nonaqueous medium comprising:

a sensor mounted to be exposed to the nonaqueous medium comprising;

an insulating substrate;

electrodes formed on the substrate each having an interdigitated portion; and

an insulating form of a conductive polymer, the conductive polymer deposited over the interdigitated portion of the electrodes as a thin film in an amount sufficient to bridge between adjacent digits, the insulating form being converted to its conductive form by protonation with the acid and hydration with the water in the nonaqueous medium to provide a current which is proportional to the amount of acid and to the amount of water and which is measurable;

control means for measuring the conductivity of the sensor, the control means being capable of indicating when the conductivity reaches a predetermined level;

warning means for providing an indication when the predetermined level is reached; and

means for interconnecting the sensor and the warning means to the control means.

14. The automotive monitoring system of claim 13, wherein the conductive polymer is selected from the group consisting of polyaniline and alkyl- and alkoxy-substituted derivatives of polyaniline.

15. The automotive monitoring system of claim 13, wherein the nonaqueous medium is selected from the group consisting of motor oil and transmission fluid, the control means is incorporated into an engine control module (ECM) of the automobile, and wherein the warning means is a visible indicator displayed on a dashboard of the automobile.

16. An automotive sensor for sensing water content in hydrocarbon-based oil and fluid comprising:

an insulating substrate;

interdigitated electrodes deposited on said substrate; and

an insulating form of polyaniline, said polyaniline deposited over the interdigitated electrodes to bridge between adjacent digits of the electrodes, wherein the insulating form of the polyaniline is converted to its conductive form by hydration with the water in the hydrocarbon-based oil and fluid to provide a current which is proportional to the amount of water and which is measurable.

17. An automotive sensor for sensing acid content in the presence of water in hydrocarbon-based oil and fluid comprising:

an insulating substrate;

interdigitated electrodes deposited on said substrate; and

an insulating form of polyaniline deposited over the interdigitated electrodes to bridge between adjacent digits of the electrodes, wherein the insulating form of the polyaniline is converted to its conductive form by protonation with the acid and hydration with the water in the hydrocarbon-based oil and fluid to provide a current which is proportional to the amount of acid and which is measurable.