Bleach activators in granular form

• US 5,334,324 A
• Filed: 02/03/1993
• Issued: 08/02/1994
• Est. Priority Date: 08/03/1990
• Status: Expired due to Fees

• Current Assignee: Henkel KGaA (Henkel AG & Co KGaA)
• Original Assignee: Henkel KGaA (Henkel AG & Co KGaA)
• Inventors: Raehse, Wilfried, Jacobs, Jochen, Zeise, Christiane
• Primary Examiner(s): Albrecht, Dennis
• Application Number:
  US07/978,700
• Time in Patent Office: 545 Days
• Field of Search: 252/91, 252/95, 252/174, 252/186.25, 252/186.26, 252/186.31, 252/186.38, 252/182.12, 252/182.23, 252/182.28, 252/182.29, 252/174.13
• US Class Current: 510/513
• CPC Class Codes: C11D 1/143 Sulfonic acid esters
• CPC Class Codes: C11D 1/146 Sulfuric acid esters
• CPC Class Codes: C11D 1/22 derived from aromatic compounds
• CPC Class Codes: C11D 1/28 Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
• CPC Class Codes: C11D 1/72 Ethers of polyoxyalkylene glycols
• CPC Class Codes: C11D 1/83 Mixtures of non-ionic with anionic compounds
• CPC Class Codes: C11D 3/3907 Organic compounds
• CPC Class Codes: C11D 3/3935 granulated, coated or protected

Abstract

A process for preparing free-flowing granules containing a bleach activator and a substantially water-free binder for the bleach activator. The process consists essentially of premixing a mixture of anionic and nonionic surfactants and the bleach activator, homogenizing the resulting mixture to form a paste which is extrudable in strand form, extruding the paste under elevated pressure, and cutting the extrudate into granules.

Claims

1. A composition comprising free-flowing granules containing from about 70 to about 95% by weight of a bleach activator, based on the weight of said granules, and a substantially water-free binder for said bleach activator, said binder consisting of a mixture of anionic and nonionic surfactants which are solid at storage conditions wherein said anionic surfactant is present in the amount of from about 60 to about 95%/wt., based on the weight of said mixture of anionic and nonionic surfactants, said granules having been prepared by premixing said mixture of surfactants and said bleach activator, homogenizing the resulting mixture to form a paste which is extrudable in strand form, extruding said paste under elevated pressure at a temperature of up to 90°

C., cutting the extrudate into granules, and rounding said granules under conditions which prevent said granules from sticking together.

2. A composition prepared as in claim 1 wherein said mixture of surfactants and said bleach activator is substantially anhydrous.

3. A composition prepared as in claim 1 wherein no water is added thereto.

4. A composition prepared as in claim 1 including adding a colorant and from about 0.1 to about 0.5%/wt. of water, based on the weight of said bleach activator, to said mixture of surfactants before premixing it with said bleach activator.

5. A composition prepared as in claim 1 wherein said mixture of surfactants is at least partly liquid at the granulation temperature of said composition.

6. A composition prepared as in claim 1 wherein said mixture of surfactants is partly liquid and partly solid at the granulation temperature of said composition.

7. A composition prepared as in claim 1 wherein said nonionic surfactant comprises a C₁₂ -C₁₈ fatty alcohol ethoxylate having an average ethylene oxide mole content of up to about 10.

8. A composition prepared as in claim 1 having an apparent density of at least about 500 g./l.

9. A composition prepared as in claim 1 wherein said mixture of surfactants and said bleach activator is homogenized and extruded in a pellet press having a pressure roller which is maintained at a predetermined working temperature of up to about 90°

C.

10. A composition prepared as in claim 9 wherein said working temperature is from about 45°

C. to about 70°

C.

11. The process of preparing free-flowing granules containing from about 70 to about 95% by weight of a bleach activator, based on the weight of said granules, and a substantially water-free binder for said bleach activator, said binder consisting of a mixture of anionic and nonionic surfactants which are solid at storage conditions wherein said anionic surfactant is present in the amount of from about 60 to about 95% by weight, based on the weight of said mixture of anionic and nonionic surfactants, said process consisting essentially of premixing said mixture of said anionic and nonionic surfactants and said bleach activator, homogenizing the resulting mixture to form a paste which is extrudable in strand form, extruding said paste under elevated pressure at a temperature of up to 90°

C., cutting the extrudate into granules, and rounding said granules under conditions which prevent said granules from sticking together.

12. A process as in claim 11 wherein said mixture of surfactants and said bleach activator is substantially anhydrous.

13. A process as in claim 11 wherein no water is added to said composition.

14. A process as in claim 11 including adding a colorant and from about 0.1 to about 0.5%/wt. of water, based on the weight of said bleach activator, to said mixture of surfactants before premixing it with said bleach activator.

15. A process as in claim 11 wherein said mixture of surfactants is at least partly liquid at the granulation temperature of said composition.

16. A process as in claim 11 wherein said mixture of surfactants is partly liquid and partly solid at the granulation temperature of said composition.

17. A process as in claim 11 wherein said nonionic surfactant comprises a C₁₂ -C₁₈ fatty alcohol ethoxylate having an average ethylene oxide mole content of up to about 10.

18. A process as in claim 11 wherein said granules have an apparent density of at least about 500 g./l.

19. A process as in claim 11 including homogenizing and extruding said mixture of surfactants and said bleach activator in a pellet press having a pressure roller which is maintained at a predetermined working temperature of up to about 90°

C.

20. A process as in claim 19 wherein said working temperature is from about 45°

C. to about 70°

C.