Method utilizing a ceramic for temperature measurement

• US 5,338,566 A
• Filed: 05/28/1992
• Issued: 08/16/1994
• Est. Priority Date: 01/05/1990
• Status: Expired due to Fees

• Current Assignee: Alliedsignal Inc. (Honeywell International Inc.)
• Original Assignee: Avco Corporation (Textron Inc)
• Inventors: McCauley, Joseph J. III, Gregory, Otto J.
• Primary Examiner(s): LUSIGNAN, MICHAEL R
• Application Number:
  US07/870,811
• Time in Patent Office: 810 Days
• Field of Search: 427/162, 427/407.1, 427/8
• US Class Current: 427/8
• CPC Class Codes: C03C 8/02 Frit compositions, i.e. in a powdered or comminuted form
• CPC Class Codes: C09D 5/26 Thermosensitive paints
• CPC Class Codes: G01K 11/14 of inorganic materials
• CPC Class Codes: Y10S 428/913 Material designed to be responsive to temperature, light, moisture
• CPC Class Codes: Y10T 428/24802 Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
• CPC Class Codes: Y10T 428/252 Glass or ceramic [i.e., fired or glazed clay, cement, etc.] [porcelain, quartz, etc.]

Abstract

A ceramic thin film applique provided on a substrate effects an optical transition at a predetermined elevated temperature. Below the transition temperature, the applique exhibits distinctive visual and physical characteristics, for example color, opaqueness and/or texture, but when the substrate is heated to the transition temperature, the visual and physical characteristics of the applique change noticeably. The invention encompasses the composition of the applique itself, as well as the methods of making the applique, applying it to the substrate, and using it.

Claims

1. A method of providing on the surface of a substrate a thermally responsive coating capable of at least one of visually and physically indicating an elevated temperature to which the substrate is subjected, said method comprising the steps of:

melting glass forming ceramic material substantially comprising SiO₂ to form a molten mass;

infusing into the molten mass material comprised of at least one colorant metallic oxide in an amount up to approximately 5% by weight of the molten mass;

quenching to the solid state the molten mixture composed of the ceramic material and the colorant metallic oxide;

crushing and classifying the solid state mixture into a powder comprised of particles in the size range of less than approximately 38 microns; and

applying the powder mixture to the surface of the substrate as a film.

2. A method as set forth in claim 1

wherein the film applied to the surface of the substrate has a thickness approximately in the range of 20 micrometers to 100 micrometers.

3. A method as set forth in claim 1 including the step of:

selecting for the infusing step one or more colorant metallic oxides which together cause the film applied to the surface of the substrate to exhibit at least one of a distinctive visual and physical characteristic at temperatures below a transition temperature.

4. A method as set forth in claim 3

wherein the step of selecting one or more colorant metallic oxides includes the step of correlating the distinctive color exhibited by the film with a particular predetermined transition temperature.

5. A method as set forth in claim 1

wherein the step of applying the powder mixture to the surface of the substrate includes the steps of:

transporting the powder mixture to the surface of the substrate supported in a fluid medium; and

bonding the powder mixture to the surface of the substrate to form the film.

6. A method as set forth in claim 5

wherein the step of transporting includes the step of spraying the fluid medium with the powder mixture suspended therein onto the surface of the substrate.

7. A method as set forth in claim 1

wherein the glass forming ceramic material is substantially comprised of SiO₂ and includes glass forming metallic oxides;

wherein a first relative composition of SiO₂ and glass forming metallic oxides result in the thermally responsive coating indicating a first transition temperature; and

wherein a second relative composition of SiO₂ and glass forming metallic oxides result in the thermally responsive coating indicating a second transition temperature.

8. A method of providing on the surface of a substrate a thermally responsive coating capable of at least one of visually and physically indicating to the unaided eye an elevated transition temperature to which the substrate is subjected, said method comprising the step of:

applying to the surface of the substrate a transition layer comprising a mixture of glass forming ceramic material and one or more colorant metallic oxides for indicating an elevated transition temperature to which the substrate is to be subjected.

9. A method as set forth in claim 8 including the step, before the step of applying a transition layer to the surface of the substrate, of:

applying a base coat comprising low melting temperature glassy particles intermediate the transition layer and the substrate for bonding the transition film to the substrate.

10. A method as set forth in claim 8 including the step, after the step of applying a transition layer to the surface of the substrate, of:

applying a polymer over coat overlying the transition film for protection of the transition film and for bonding of the transition film to the substrate at temperatures below the transition temperature.