Thermoplastic composition based on polyphenylene ether and polyamide

• US 5,338,796 A
• Filed: 02/09/1993
• Issued: 08/16/1994
• Est. Priority Date: 03/22/1990
• Status: Expired due to Fees

• Current Assignee: Montedipe SPA
• Original Assignee: Montedipe SPA
• Inventors: Longo, Aldo, Benetton, Armando, Moro, Alessandro, Pippa, Roberto, Vianello, Domenico
• Primary Examiner(s): Seidleck, James J.
• Assistant Examiner(s): Hamilton, III, Thomas
• Application Number:
  US08/015,106
• Time in Patent Office: 553 Days
• Field of Search: 525/68, 525/66, 525/133, 525/397, 525/905, 524/504, 524/508, 524/514
• US Class Current: 525/66
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 2666/22 Macromolecular compounds not provided for in C08L2666/16 - C08L2666/20
• CPC Class Codes: C08L 2666/24 Graft or block copolymers according to groups C08L51/00, C08L53/00 or C08L55/02; Derivatives thereof
• CPC Class Codes: C08L 51/06 grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
• CPC Class Codes: C08L 51/08 grafted on to macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds
• CPC Class Codes: C08L 71/126 modified by chemical after-treatment
• CPC Class Codes: C08L 77/00 Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain of polyhydrazides C08L79/06; of polyamideimides or polyamide acids C08L79/08; Compositions of derivatives of such polymers
• CPC Class Codes: Y10S 525/905 Polyphenylene oxide

Abstract

A thermoplastic composition having a good balance of mechanical and thermal properties, an improved impact strength and a good processability includes a functionalized polyphenylene ether, a polyamide, and an olefinic elastomer containing a vinylaromatic monomer grafted thereon.

Claims

1. A thermoplastic composition comprising:

100 parts by weight of a resinous composition comprising;

(A) 5-95% by weight of a polyphenylene ether functionalized with a compound containing in its molecular structure at least a double or triple carbon-carbon bond and at least a carboxylic acid, anhydride, amide, imide, ester, amino, or hydroxyl group;

(B) 95-5% by weight of a polyamide; and

(C) 1-100 parts by weight, for 100 parts by weight of mixture A+B, of an olefinic elastomer containing, grafted thereon, a vinylaromatic monomer,

wherein the olefinic elastomer is an ethylene/propylene/non-conjugated diene terpolymer, wherein the diene content is approximately from 2 to 20% by weight calculated on the terpolymer, said terpolymer having a Mooney viscosity, ML-4, at 100°

C. ranging from 30 to 90, and an iodine number greater than 5,

wherein the vinylaromatic polymer, formed during the graft polymerization of the vinylaromatic monomer, molecular weight (Mw) ranges from about 600,000 to about 1,700,000,

wherein the vinylaromatic monomer content is greater than 1% by weight calculated on the grafted polymer, and

wherein the vinylaromatic polymer is partially grafted on the rubber-like substrate and partially forms a polymer in physical admixture with the grafter polymer.

2. The thermoplastic composition according to claim 1, wherein the proportions of components A, B and C calculated on the total composition are:

A. from 25 to 70% by weight of a functionalized polyphenylene ether;

B. from 25 to 70% by weight of a polyamide, and

C. from 5 to 50% by weight of an olefinic elastomer containing, grafted thereon, a vinylaromatic monomer;

the sum of the three components A, B and C being equal to 100.

3. The thermoplastic composition according to claim 1, wherein the polyphenylene ether is a polymer or a copolymer containing a plurality of structural units of formula:

##STR4## wherein R₁, R₂, R₃ and R₄ represent, independently of one another, a substituted or non substituted C₁ -C₁₈ hydrocarbon radical, an atom of halogen or hydrogen.

4. The thermoplastic composition according to claim 3, wherein polyphenylene ether has the formula:

##STR5## wherein R'"'"'₁, R'"'"'₂, independently of each other, are an alkyl radical containing from 1 to 4 carbon atoms and n is at least 50.

5. The thermoplastic composition according to claim 1, wherein the polyphenylene ether is poly(2,6-di-methyl1,4-phenylene)ether having a number average molecular weight ranging from 5,000 to 120,000 and an intrinsic viscosity greater than 0.1 dl/g, measured in chloroform at 23°

C.

6. The thermoplastic composition according to claim 1, wherein the functionalizing compound is selected from maleic anhydride, maleimide and fumaric acid.

7. The thermoplastic composition according to claim 1, wherein the functionalizing compound content ranges from 0.01 to 5 parts by weight for 100 parts by weight of polyphenylene ether.

8. The thermoplastic composition according to claim 1, wherein the polyamide is nylon 6 or nylon 6,6.

9. The thermoplastic composition according to claim 1, wherein the vinylaromatic monomer has formula:

##STR6## wherein;

X represents hydrogen or an alkyl radical having from 1 to 4 carbon atoms;

Y represents hydrogen, a halogen or an alkyl radical having from 1 to 4 carbon atoms, and

n is 0 or an integer ranging from 1 to 5.

10. The thermoplastic composition according to claim 1, wherein the vinylaromatic polymer molecular weight (Mw) is between about 900,000 and about 1,300,000.

11. The thermoplastic composition according to claim 1, wherein the amount of grafted vinylaromatic monomer ranges from 10 to 50% by weight and the amount of free polymer ranges from 20 to 50% by weight.

12. The thermoplastic composition according to claim 1, further containing, in addition, reinforcing additives, antiflame agents, dyestuffs, pigments, stabilizers and/or lubricants.

13. The thermoplastic composition according to claim 12, wherein the reinforcing additive is selected from glass fibers, carbon fibers, organic and inorganic high-modulus fibers and metal fibers in an amount not greater than 50% by weight calculated on the total composition.

14. The thermoplastic composition according to claim 1, wherein the vinyl aromatic monomer content in the olefinic elastomer ranges from 30 to 60% by weight calculated on the grafted polymer.

15. The thermoplastic composition according to claim 4, wherein n range from 60 to about 600.

16. The thermoplastic composition according to claim 5, wherein the intrinsic viscosity ranges from 0.30 to 0.90 dl/g.

17. The thermoplastic composition according to claim 7, wherein the functionalizing compound content ranges from 0.01 to 3.

18. The thermoplastic composition according to claim 1, wherein the other copolymerizable polyene monomer is a non-conjugated diene.

19. The thermoplastic composition according to claim 1, wherein the diene content is from 8 to 18%.

20. The thermoplastic composition according to claim 1, wherein the iodine number ranges from 10 to 40.

21. The thermoplastic composition according to claim 13, wherein the reinforcing additive is not greater than 30%.