Vermiculite composition with improved thermal expansion properties

• US 5,340,558 A
• Filed: 06/14/1993
• Issued: 08/23/1994
• Est. Priority Date: 06/14/1993
• Status: Expired due to Term

• Current Assignee: GCP Applied Technologies Inc. (Compagnie De Saint-Gobain S.A.)
• Original Assignee: W R Grace & Company - CONN (Standard Industries Holdings, Inc.)
• Inventors: Ou, Chia-Chih, Spotnitz, Robert M., Friedman, Semyon D., Wu, Shaohai, McKinney, Robert W.
• Primary Examiner(s): GREEN, ANTHONY J
• Application Number:
  US08/076,663
• Time in Patent Office: 435 Days
• Field of Search: 252/378 R, 252/606, 423/328.1, 106/675, 106/DIG. 3, 428/920, 428/313.7, 241/4, 241/68, 209/4
• US Class Current: 423/328.1
• CPC Class Codes: C04B 14/202 Vermiculite
• CPC Class Codes: C04B 20/0024 expanded in situ, i.e. the material is expanded or made hollow after primary shaping of the mortar, concrete or artificial stone mixture C04B16/085 takes precedence
• CPC Class Codes: C04B 30/00 Compositions for artificial stone, not containing binders
• CPC Class Codes: C04B 40/0263 Hardening promoted by a rise in temperature C04B40/024 takes precedence
• CPC Class Codes: Y10S 106/03 Mica
• CPC Class Codes: Y10S 428/92 Fire or heat protection feature

Abstract

A vermiculite composition capable of exhibiting a high degree of volume increase upon subjection to thermal exfoliation composed of vermiculite mineralogical species having specific gravity of from 2.5 g/cm³ to 2.9 g/cm³. Further, intumescent sheets formed with said vermiculite composition exhibit low initial expansion temperature and very high maximum expansion properties.

Claims

1. A vermiculite composition having the capability of exhibiting enhanced volume increase upon subjection to thermal exfoliation consisting essentially of a vermiculite ore concentrate material having at least 90% of at least one unexpanded vermiculite mineralogical specie or mixtures thereof having a specific density in the range of from 2.5 g/cm³ to 2.9 g/cm³.

2. The vermiculite composition of claim 1 wherein the specific density is in the range of from 2.6 g/cm³ to 2.8 g/cm³.

3. The vermiculite composition of claim 1 wherein the composition is composed of at least 95% by weight of said vermiculite mineralogical species.

4. The vermiculite composition of claim 2 wherein the composition is composed of at least 95% by weight of said vermiculite mineralogical species.

5. The vermiculite composition of claim 1 which is treated by cation exchange with potassium cations.

6. A process of forming a vermiculite composition capable of exhibiting enhanced volume increase upon subjection to thermal exfoliation comprising:

i. beneficiating vermiculite ore to form vermiculite ore concentrate having a substantial portion of gangue material removed therefrom;

ii. treating the ore concentrate to density classification to separate out a vermiculite ore concentrate composition composed of at least 90 weight percent of vermiculite mineralogical species having specific density in the range of from 2.5 g/cm³ to 2.9 g/cm³ ; and

iii. recovering the vermiculite composition.

7. The process of claim 6 wherein the ore concentrate is treated to density classification to provide a vermiculite composition having at least 90 weight percent of at least one vermiculite mineralogical species or mixtures thereof having a density of 2.6 g/cm³ to 2.8 g/cm³.

8. The process of claim 6 wherein the recovered vermiculite composition is composed of at least 95% by weight of said vermiculite mineralogical species.

9. The process of claim 7 wherein the recovered vermiculite composition is composed of at least 95% by weight of said vermiculite mineralogical species.

10. The process of claim 6 wherein the density classification comprises mixing a vermiculite ore concentrate with a low density fluid media having a specific density substantially equal to 2.5 g/cm³, separating and recovering vermiculite material having a higher density than 2.5 g/cm³ from the low-density fluid media, further mixing the recovered material with a high density fluid media having a specific density substantially equal to 2.9 g/cm³ and separating and recovering material having a lower density than 2.9 g/cm³ from the high-density fluid media.

11. The process of claim 7 wherein the density classification comprises mixing a vermiculite ore concentrate with a low density fluid media having a specific density substantially equal to 2.6 g/cm³ separating and recovering vermiculite material having a higher density than 2.6 g/cm³ from the low-density fluid media, further mixing the recovered material with a high density fluid media having a specific density substantially equal to 2.8 g/cm³ and separating and recovering material having a lower density than 2.8 g/cm³ from the high-density fluid media.

12. A flexible intumescent sheet product comprising from about 25% to 50% by weight of inorganic fibrous material, from about 5% to 15% of a binder and from about 40% to 65% by weight of at least one vermiculite mineralogical species having a specific density of from 2.5 g/cm³ to 2.9 g/cm³.

13. The sheet product of claim 12 wherein the vermiculite mineralogical species have a specific density of from 2.6 g/cm³ to 2.8 g/cm³.

14. The sheet product of claim 12 wherein the vermiculite mineralogical species is treated to cationic exchange with ammonium or potassium cations.

15. The sheet product of claim 13 wherein the vermiculite mineralogical species of said vermiculite composition is treated to cationic exchange with ammonium or potassium cations.