Aqueous coating compound, a process for its preparation and its use in processes for multilayered lacquering

• US 5,342,882 A
• Filed: 07/22/1993
• Issued: 08/30/1994
• Est. Priority Date: 07/25/1992
• Status: Expired due to Term

• Current Assignee: Herberts Gesellschaft Mit Beschrankter Haftung
• Original Assignee: Herberts GmbH (Corteva, Inc.)
• Inventors: Gobel, Armin, Doebert, Jurgen, Patzschke, Hans-Peter
• Primary Examiner(s): WELSH JR, MAURICE
• Application Number:
  US08/095,959
• Time in Patent Office: 404 Days
• Field of Search: 524/832, 524/839, 524/840, 427/385.5, 427/388.4
• US Class Current: 524/832
• CPC Class Codes: B05D 7/53 Base coat plus clear coat type
• CPC Class Codes: C08L 2666/14 Macromolecular compounds according to C08L59/00 - C08L87/00; Derivatives thereof
• CPC Class Codes: C08L 51/00 Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds for ABS polymers C08L55/02; Compositions of derivatives of such polymers
• CPC Class Codes: C09D 151/08 grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
• CPC Class Codes: C09D 175/04 Polyurethanes

Abstract

Aqueous coating compound containing a polyurethane resin-based binder of

I) from 60 to 100% by weight of a mixture of

A) from 5-95% by weight of one or more self-emulsifying polyurethane resins in aqueous dispersion having a number average molar mass (Mn) of from 30000 to 300000 and containing carboxyl groups corresponding to an acid number of from 5 to 50, obtainable from a water dispersible polyurethane prepolymer having more than one free isocyanate group per molecule, by chain lengthening with water and

B) from 95 to 5% by weight of one or more acrylated polyesters and/or acrylated polyurethanes having an acid number of from 5 to 50 in aqueous dispersion and

II) from 0 to 40% by weight of one or more formaldehyde condensation resins and/or blocked polyisocyanates,

the percentages by weight being based in each case on the resin solids content. The coating compounds are suitable in particular as basic lacquers for multi-coat lacquering. Coatings with good weather resistance are produced from them.

Claims

1. An aqueous coating composition, containing a binder which comprises

(I) from 60% to 100% wt. of a mixture of

(i) from 5% to 95% wt. solids basis based on(I) of an aqueous dispersion of one or more self-emulsifying polyurethane resins having a number average molecular weight of from 30,000 to 300,000 and containing carboxyl groups corresponding to an acid number of from 5 to 50, said resins having been obtained by chain lengthening in water a water-dispersible polyurethane prepolymer having more than one free isocyanate group per molecule, and

(ii) from 95% to 5% wt. solids basis based on (I) of an aqueous dispersion of at least one acrylated polyester, or at least one acrylated polyurethane, or at least one acrylated polyester and at least one acrylated polyurethane, and

(II) from 0 to 40% wt. of one or more formaldehyde condensation resin, one or more blocked polyisocyanate, or one or more formaldehyde condensation resin and one or more blocked polyisocyanate.

2. Aqueous coating compound according to claim 1, characterised in that binder component A) is obtainable by the preparation of the polyurethane prepolymer by the reaction of

a) one or more polyisocyanates with

b) one or more polyether diols and/or polyester diols each having a number average molar mass of from 500 to 5000, up to 30% by weight of which may be replaced by one or more low molecular weight polyhydroxyl compounds having a molar mass of from 60 to 400 and

c) one or more dihydroxy, diamino and/or hydroxyaminoalkanes containing anionic groups

in an NCO/OH equivalent ratio of from 1.0:

1 to 2.0;

1, preferably from 1.1;

1 to 1.9;

1, followed by chain lengthening of the polyurethane prepolymer with water.

3. Aqueous coating compound according to claim 2, characterised in that the subsequent chain lengthening of the polyurethane prepolymer with water is carried out in the organic phase in a ratio of two free isocyanate groups to from 0.5 to 3.0 mol of water.

4. Aqueous coating compound according to claim 1, characterised in that the formaldehyde condensation resins of component II) contained therein consist of one or more fully etherified amine-formaldehyde condensation resins.

8. A process for preparing multilayers lacquer, which comprises applying the composition of claim 1 as a lacquer base coat or a lacquer top coat to a substrate which is optionally coated with one or more layers, optionally partially drying said base or top lacquer coat, applying a clear lacquer coat to said base or top lacquer coat, and hardening the coats.

9. The process of claim 8, wherein said substrate is a part of a motor vehicle.

5. A process for the preparation of a binder for aqueous coating compounds by the reaction of

a) one or more polyisocyanates,

b) one or more polyether diols and/or polyester diols, each having a number average molar mass of from 500 to 5000, up to 30% by weight of which may be replaced by one or more low molecular weight polyhydroxyl compounds having a molar mass of from 60 to 400, and

c) one or more dimethylol alkane carboxylic acids in an NCO/OH equivalent ratio of from 1.0:

1 to 2.0;

1, preferably from 1.1;

1 to 1.9;

1, followed by chain lengthening of the polyurethane prepolymer with water.

6. A process according to claim 5, characterised in that the chain lengthening of the polyurethane prepolymer with water is carried out in the organic phase in a ratio of two free isocyanate groups to 0.5 to 3.0 mol of water.

7. A process for the preparation of aqueous coating compounds, characterised in that

I) from 60 to 100% by weight of a mixture of

A) from 5-95% by weight of one or more of the polyurethane resins obtained according to claim 5 with

B) from 95-5% by weight of one or more acrylated polyesters and/or acrylated polyurethanes having an acid number of from 5 to 50 in aqueous dispersion is mixed with

(II) from 0 to 40% by weight of one or more formaldehyde condensation resins and/or blocked polyisocyanates,

the percentages by weight being in each case based on the solids content of the resin.