Water dispersible formulations and materials and methods for influencing their water dispersibility

• US 5,346,541 A
• Filed: 11/18/1992
• Issued: 09/13/1994
• Est. Priority Date: 11/18/1992
• Status: Expired due to Fees

• Current Assignee: Net Tech International, Inc.
• Original Assignee: Net Tech International, Inc.
• Inventors: Goldman, Leonard J., Roesch, Susan M.
• Primary Examiner(s): GREEN, ANTHONY J
• Application Number:
  US07/978,219
• Time in Patent Office: 664 Days
• Field of Search: 106/197.1, 106/197.2, 106/198, 106/163.1, 106/169, 106/203, 106/204, 106/169, 536/84, 536/95, 536/97
• US Class Current: 106/162.8
• CPC Class Codes: C08J 2301/00 Characterised by the use of cellulose, modified cellulose or cellulose derivatives
• CPC Class Codes: C08J 3/05 from solid polymers
• CPC Class Codes: C08L 1/00 Compositions of cellulose, modified cellulose or cellulose derivatives
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: D21H 17/26 Ethers thereof

Abstract

The present invention relates to unexpected or surprising discoveries in the field of biodegradable, water-dispersible formulations and materials and methods for influencing their rate of dispersibility in water. In particular, the present invention relates to the unexpected discovery that the inclusion of effective amounts of short length cellulose fibers dispersed throughout a water soluble cellulose ether binder will result in a retardation or slowing of the water dispersibility of the formulation relative to a formulation containing long or long and short cellulose fibers in a cellulose ether binder. In an additional aspect, the present invention relates to the discovery that the inclusion of effective amounts of long length cellulose fibers dispersed throughout a water soluble cellulose ether binder will result in an enhancement or hastening of the water dispersibility of the formulation relative to a formulation containing a cellulose ether binder which does not contain long cellulose fibers. In still a further aspect, the present invention relates to the discovery that the inclusion of effective amounts of a gas-releasing agent increases the rate of water-dispersibility relative to formulations containing only a cellulose ether binder.

Claims

1. A water-dispersible formulation for use in manufacturing water dispersible materials consisting essentially of about 1% to about 90% by weight of a water dispersible cellulose ether binder;

about 10% to about 98.99% by weight cellulose fibers and about 0.01% to about 30% by weight of a gas releasing agent, said cellulose fibers being randomly dispersed throughout said cellulose ether binder.

2. The formulation according to claim 1 wherein said water dispersible cellulose ether is selected from the group consisting of carboxymethylcellulose, hydroxypropylcellulose, hydroxypropylmethylcellulose, hydroxyethylcellulose, methylcellulose, hydroxymethylethylcellulose and carboxymethylhydroxyethylcellulose.

3. The formulation according to claim 2 wherein said cellulose ether binder comprises about 3% to about 62% by weight of said formulation and said gas releasing agent comprises about 0.1% to about 15% by weight of said formulation.

4. The formulation according to claim 1 wherein said cellulose fibers comprise a mixture of long and short fibers, said long fibers being more than about 300 microns in length and said short fibers being less than about 300 microns in length.

5. The formulation according to claim 1 wherein said gas releasing agent is hydrogen peroxide.

6. The formulation according to claim 1 wherein said gas releasing agent is sodium or potassium bicarbonate in combination with a biodegradable organic acid, the molar ratio of bicarbonate to organic acid ranging from about 1:

10 to about 10;

1.

7. The formulation according to claim 1 further including at least one inert filler, plasticizer, crosslinking agent or surfactant.

8. A water-dispersible formulation for use in manufacturing containers consisting essentially of about 1% to about 90% by weight of a water soluble cellulose ether binder;

about 10% to about 98.99% by weight cellulose fibers and about 0.01% to about 30% by weight of a gas releasing agent, said cellulose fibers comprising a mixture of short and long cellulose fibers, said cellulose fibers being randomly dispersed throughout said cellulose ether binder, said long fibers being more than about 300 microns in length and said short fibers being less than about 300 microns in length.

9. The formulation according to claim 8 wherein said short cellulose fibers range in length from about 22 microns to about 280 microns in length.

10. The formulation according to claim 8 wherein said long cellulose fibers range in size from about 300 microns to about 2 mm.

11. The formulation according to claim 8 wherein said long cellulose fibers comprise at least about 50% by weight of said cellulose fibers in said formulation.

12. The formulation according to claim 8 wherein said water dispersible cellulose ether is selected from the group consisting of carboxymethylcellulose, hydroxypropylcellulose, hydroxypropylmethylcellulose, hydroxyethylcellulose, methylcellulose, hydroxymethylethylcellulose and carboxylmethylhydroxyethylcellulose.

13. The formulation according to claim 8 wherein said cellulose ether binder comprises about 2% to about 30% by weight of said formulation.

14. The formulation according to claim 8 wherein said gas releasing agent is selected from the group consisting of peroxides, bicarbonate salts and carbonate salts.

15. The formulation according to claim 14 wherein said gas releasing agent is hydrogen peroxide.

16. The formulation according to claim 8 wherein said gas releasing agent is sodium or potassium bicarbonate in combination with a biodegradable organic acid, the molar ratio of bicarbonate to organic acid ranging from about 1:

10 to about 10;

1.

17. The formulation according to claim 16 wherein said molar ratio is 1:

1.

18. The formulation according to claim 8 wherein said cellulose ether binder is carboxymethylcellulose or carboxymethylhydroxyethylcellulose and said gas releasing agent is hydrogen peroxide, said hydrogen peroxide comprising no greater than about 20% by weight of said binder.

19. The formulation according to claim 8 optionally including at least one inert filler, plasticizer, crosslinking agent or surfactant.

20. A water-dispersible formulation for use in manufacturing water dispersible materials consisting essentially of about 70% to about 99.99% by weight of a water dispersible cellulose ether binder and about 0.01% to about 30% by weight of a gas releasing agent.

21. The formulation according to claim 20 wherein said gas releasing agent is selected from the group consisting of peroxides, bicarbonate salts and carbonate salts.

22. The formulation according to claim 20 wherein said gas releasing agent is hydrogen peroxide.

23. The formulation according to claim 20 wherein said gas releasing agent is sodium or potassium bicarbonate in combination with a biodegradable organic acid, the molar ratio of bicarbonate to organic acid ranging from about 1:

10 to about 10;

1.

24. The formulation according to claim 20 further including at least one inert filler, plasticizer, crosslinking agent or surfactant.

25. A method of increasing the water dispersibility of a formulation used in the manufacture of water dispersible materials, said formulation consisting essentially of about 1% to about 90% by weight of a water dispersible cellulose ether binder and about 10% to about 99% by weight of cellulose fibers comprising a mixture of long and short cellulose fibers, said long fibers being more than about 300 microns in length and said short fibers being less than about 300 microns in length, said cellulose fibers being randomly dispersed throughout said cellulose ether binder, said method comprising adding effective amounts of additional long cellulose fibers to said formulation to increase water dispersibility.

26. The method according to claim 25 wherein said water dispersible cellulose ether is selected from the group consisting of carboxymethylcellulose, hydroxypropylcellulose, hydroxypropylmethylcellulose, hydroxyethylcellulose, methylcellulose, hydroxymethylethylcellulose and carboxylmethylhydroxyethylcellulose.

27. The method according to claim 25 wherein said formulation includes at least one inert filler, plasticizer, crosslinking agent or surfactant.

28. A method of decreasing the water dispersibility of a formulation used in the manufacture of water dispersible materials, said formulation consisting essentially of about 1% to about 90% by weight of a water dispersible cellulose ether binder and about 10% to about 99% by weight of a mixture of long and short cellulose fibers, said long fibers being more than about 300 microns in length and said short fibers being less than about 300 microns in length, said cellulose fibers being randomly dispersed throughout said cellulose ether binder, said method comprising adding effective amounts of additional short cellulose fibers in said mixture of cellulose fibers of said formulation to decrease water dispersibility.

29. The method according to claim 28 wherein said water dispersible cellulose ether is selected from the group consisting of carboxymethylcellulose, hydroxypropylcellulose, hydroxypropylmethylcellulose, hydroxyethylcellulose, methylcellulose, hydroxymethylethylcellulose and carboxymethylhydroxyethylcellulose.

30. The method according to claim 28 wherein said formulation includes at least one inert filler, plasticizer, crosslinking agent or surfactant.

31. A method of increasing the water dispersibility of a formulation used in the manufacture of water dispersible materials, said formulation comprising about 1% to about 90% by weight of a water dispersible cellulose ether binder and about 10% to about 98.98% by weight cellulose fibers comprising a mixture of long and short cellulose fibers, said long fibers being more than about 300 microns in length and said short fibers being less than about 300 microns in length, and at least about 0.01% to about 30% by weight of a gas releasing agent, said cellulose fibers being randomly dispersed throughout said cellulose ether binder, said method comprising adding effective amounts of additional long cellulose fibers to said formulation to increase water dispersibility.

32. A method of increasing the water dispersibility of a formulation used in the manufacture of water dispersible materials, said formulation comprising about 1% to about 90% by weight of a water dispersible cellulose ether binder, about 10% to about 98.99% by weight cellulose fibers said cellulose fibers being selected from the group consisting of long cellulose fibers, short cellulose fibers and mixtures thereof, and an amount of water effective to thoroughly mix said cellulose ether and said cellulose fibers into a dough, said cellulose fibers being randomly dispersed throughout said cellulose ether binder, said method comprising adding about 0.01% to about 30% by weight of a gas releasing agent to said formulation and thereafter subjected said formulation to a mixing action or to heat at a temperature below about 140°

C. to produce a foaming action before drying said formulation to remove said water.

33. The method according to claim 32 wherein said water dispersible cellulose ether is selected from the group consisting of carboxymethylcellulose, hydroxypropylcellulose, hydroxypropylmethylcellulose, hydroxyethylcellulose, methylcellulose, hydroxymethylethylcellulose and carboxylmethylhydroxyethylcellulose.

34. The method according to claim 33 wherein said cellulose ether binder comprises about 3% to about 62% by weight of said formulation.

35. The method according to claim 32 wherein said cellulose ether binder comprises about 2% to about 30% by weight of said formulation.

36. The method according to claim 32 wherein said cellulose fibers comprise a mixture of long and short fibers.

37. The method according to claim 32 wherein said gas releasing agent is selected from the group consisting of peroxides, bicarbonate salts and carbonate salts.

38. The method according to claim 32 wherein said gas releasing agent is hydrogen peroxide.

39. The method according to claim 32 wherein said gas releasing agent is sodium or potassium bicarbonate in combination with a biodegradable organic acid, the molar ratio of bicarbonate to organic acid ranging from about 1:

10 to about 10;

1.

40. The method according to claim 39 wherein said molar ratio is 1:

1.

41. The method according to claim 32 wherein said cellulose ether binder is carboxymethylcellulose or carboxymethylhydroxyethylcellulose and said gas releasing agent is hydrogen peroxide, said hydrogen peroxide comprising no greater than about 20% by weight of said binder.

42. The method according to claim 32 wherein said formulation further includes at least one inert filler, plasticizer, crosslinking agent or surfactant.

43. A method of increasing the water dispersibility of a formulation used in the manufacture of water dispersible materials, said formulation consisting essentially of about 70% to about 99.99% by weight of a water dispersible cellulose ether binder, about 0.01% to about 30% by weight of a gas releasing agent and an amount of water effective to thoroughly mix said cellulose ether binder and said gas releasing agent, said method comprising subjecting said formulation to a mixing action or to heat at a temperature below about 140°

C. to induce said gas releasing agent to release gas before drying said formulation to remove said water.