Synergistic pesticidal compositions

• US 5,346,698 A
• Filed: 03/08/1993
• Issued: 09/13/1994
• Est. Priority Date: 01/15/1991
• Status: Expired due to Fees

• Current Assignee: Mycogen Corporation (Corteva, Inc.)
• Original Assignee: Mycogen Corporation (Corteva, Inc.)
• Inventors: Abercrombie, Kenneth D.
• Primary Examiner(s): Page, Thurman K.
• Assistant Examiner(s): Harrison, Robert H.
• Application Number:
  US08/028,041
• Time in Patent Office: 554 Days
• Field of Search: 424/405, 514/30, 514/53, 514/450, 514/68, 514/69
• US Class Current: 424/405
• CPC Class Codes: A01N 2300/00 Combinations or mixtures of active ingredients covered by classes A01N27/00 - A01N65/48 with other active or formulation relevant ingredients, e.g. specific carrier materials or surfactants, covered by classes A01N25/00 - A01N65/48
• CPC Class Codes: A01N 37/02 Saturated carboxylic acids or thio analogues thereof; Derivatives thereof
• CPC Class Codes: A01N 37/06 Unsaturated carboxylic acids or thio analogues thereof; Derivatives thereof
• CPC Class Codes: A01N 43/90 having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system

Abstract

Described and claimed are methods and compositions for the control of pests. According to the subject invention, a fatty acid or mixture of fatty acids can be combined with one or more avermectins or related compounds to achieve synergistic control of pests.

Claims

1. A composition for the control of a pest, said composition comprising a first ingredient which is a monocarboxylic acid having about seven to about twenty carbon atoms, or a salt thereof, or a mixture of said monocarboxylic acids or salts thereof, and a second ingredient which is an avermectin, ivermectin, or milbemycin, wherein said first ingredient is present in a concentration of at least about 0.2% and the second ingredient is present in a concentration between about 3 ppm and about 110 ppm.

2. The composition, according to claim 1, wherein said first ingredient can be represented by the following formula:

space="preserve" listing-type="equation">R.sub.1 Y.sub.1 Y.sub.2 COOR.sub.2

wherein

R₁ =C6 to C19 saturated or unsaturated hydrocarbon, or an epoxide, or cyclopropane thereof

Y₁ =H, C1-C5 hydrocarbon, or hydroxyl at any position along R₁

Y₂ =H, C1-C5 hydrocarbon, or hydroxyl at any position along R₁

R₂ =H, or salt.

3. The composition, according to claim 1, wherein said first ingredient has from about fifteen to about twenty carbons.

4. The composition, according to claim 1, wherein said first ingredient is a mixture of monocarboxylic acids or salts thereof.

5. The composition, according to claim 1, wherein said first ingredient is saturated and unsubstituted.

6. The composition, according to claim 1, wherein said first ingredient is oleic acid or a salt thereof.

7. The composition, according to claim 1, wherein said second ingredient is an avermectin.

8. The composition, according to claim 1, wherein said second ingredient is a milbemycin.

9. The composition, according to claim 1, wherein said second ingredient is an ivermectin.

10. The composition, according to claim 1, wherein said composition is formulated to be a drench product to be applied to livestock or pets.

11. The composition, according to claim 10, wherein said first ingredient has from about seven to about eighteen carbons.

12. The composition, according to claim 11, wherein said first ingredient is decanoic or nonanoic acid or salts thereof.

13. The composition, according to claim 1, wherein said first ingredient is a metal salt of a monocarboxylic acid.

14. A method for the control of a pest, said method comprising the administration to said pest of an effective amount of a composition comprising a first ingredient which is a monocarboxylic acid having about seven to about twenty carbons, or a salt thereof, or a mixture of monocarboxylic acids or salts thereof, and a second ingredient which is an avermectin, ivermectin, or milbemycin, wherein said first ingredient is applied at a rate of at least about 1 lb/acre, and said second ingredient is applied at a rate of about 0.0006 lbs/acre to about 0.02 lbs/acre.

15. The method, according to claim 14, wherein said first ingredient can be represented by the following formula:

space="preserve" listing-type="equation">R.sub.1 Y.sub.1 Y.sub.2 COOR.sub.2

wherein

R₁ =C6 to C19 saturated or unsaturated hydrocarbon, or an epoxide, or cyclopropane thereof

Y₁ =H, C1-C5 hydrocarbon, or hydroxyl at any position along R₁

Y₂ =H, C1-C5 hydrocarbon, or hydroxyl at any position along R₁

R₂ =H, or salt.

16. The method, according to claim 14, wherein said first ingredient has from about fifteen to about twenty carbons.

17. The method, according to claim 14, wherein said first ingredient is oleic acid or a salt thereof.

18. The method, according to claim 14, wherein said second ingredient is an avermectin.

19. The method, according to claim 14, wherein said second ingredient is a milbemycin.

20. The method, according to claim 14, wherein said second ingredient is ivermectin.

21. The method, according to claim 14, wherein said composition is formulated to be a drench product to be applied to livestock or pets.

22. The method, according to claim 14, wherein said first ingredient has from about seven to about eighteen carbons.

23. The method, according to claim 14, wherein said first ingredient is a metal salt of a monocarboxylic acid.

24. The method, according to claim 14, wherein said pest is in a taxonomic family selected from the group consisting of Tetranychidae, Eriophyidae, Tenuipalpidae, Tarsenomidae, Aleyrodidae, Psyllidae, Agromyzidae, Cicadellidae, Membracidae, Coccidae, Pseudococcidae, and Diaspididae.

25. The method, according to claim 14, wherein said pest is selected from the group consisting of Thysanoptera, Hymenoptera, Hemiptera, Cicadellidae, Membracidae, Coccidae, Pseudococcidae, Diaspididae, and Solenopsis.

26. The method, according to claim 14, wherein said pest is selected from the group consisting of mites and whiteflies.

27. The method, according to claim 21, wherein said pest is selected from the group consisting of fleas, ticks, mites, lice, and flies.

28. A method for the control of a pest, said method comprising the sequential application to said pest of a first composition comprising a monocarboxylic acid having about seven to about twenty carbon atoms, or a salt thereof, or a mixture of monocarboxylic acids or salts thereof, and a second composition comprising avermectin, ivermectin, or milbemycin wherein said first ingredient is present in a concentration of at least about 0.2% and the second ingredient is present in a concentration between about 3 ppm and about 110 ppm.

29. The method, according to claim 28, wherein said monocarboxylic acid can be represented by the following formula:

space="preserve" listing-type="equation">R.sub.1 Y.sub.1 Y.sub.2 COOR.sub.2

wherein

R₁ =C6 to C19 saturated or unsaturated hydrocarbon, or an epoxide, or cyclopropane thereof

Y₁ =H, C1-C5 hydrocarbon, or hydroxyl at any position along R₁

Y₂ =H, C1-C5 hydrocarbon, or hydroxyl at any position along R₁

R₂ =H, or salt.

30. The method, according to claim 28, wherein said monocarboxylic acid is oleic acid or a salt thereof.