Electrochemical load management system for transportation applications

• US 5,346,778 A
• Filed: 08/13/1992
• Issued: 09/13/1994
• Est. Priority Date: 08/13/1992
• Status: Expired due to Fees

• Current Assignee: Teledyne Energy Systems, Inc. (Teledyne Technologies Incorporated)
• Original Assignee: Energy Partners, L. C.
• Inventors: Ewan, James M., Misiasxek, Steven M., Alessi, Donald P. Jr.
• Primary Examiner(s): GORGOS, KATHRYN L
• Application Number:
  US07/929,618
• Time in Patent Office: 761 Days
• Field of Search: 429/13, 429/21, 429/24, 429/25, 429/17, 204/DIG. 4, 204/267
• US Class Current: 429/415
• CPC Class Codes: B60L 58/30 for monitoring or controlling fuel cells
• CPC Class Codes: B60L 58/33 by cooling
• CPC Class Codes: C25B 1/04 by electrolysis of water
• CPC Class Codes: C25B 15/02 Process control or regulation
• CPC Class Codes: C25B 9/05 Pressure cells
• CPC Class Codes: H01M 2250/20 Fuel cells in motive systems, e.g. vehicle, ship, plane
• CPC Class Codes: H01M 8/04029 Heat exchange using liquids
• CPC Class Codes: H01M 8/04089 of gaseous reactants
• CPC Class Codes: H01M 8/04156 with product water removal
• CPC Class Codes: H01M 8/04201 Reactant storage and supply, e.g. means for feeding, pipes
• CPC Class Codes: H01M 8/04291 Arrangements for managing water in solid electrolyte fuel cell systems H01M8/04119 takes precedence
• CPC Class Codes: H01M 8/04343 of anode exhausts
• CPC Class Codes: H01M 8/0435 of cathode exhausts
• CPC Class Codes: H01M 8/04358 of the coolant
• CPC Class Codes: H01M 8/04395 of cathode reactants at the inlet or inside the fuel cell
• CPC Class Codes: H01M 8/04425 at auxiliary devices, e.g. reformers, compressors, burners
• CPC Class Codes: H01M 8/04552 of the individual fuel cell
• CPC Class Codes: H01M 8/04559 of fuel cell stacks
• CPC Class Codes: H01M 8/04589 of fuel cell stacks
• CPC Class Codes: H01M 8/04753 of fuel cell reactants
• CPC Class Codes: H01M 8/04798 : of fuel cell reactants
• CPC Class Codes: H01M 8/0656 : by electrochemical means H01M8/065 takes precedence
• CPC Class Codes: H01M 8/186 : by electrolytic decomposition of the electrolytic solution or the formed water product
• CPC Class Codes: H01M 8/249 : comprising two or more groupings of fuel cells, e.g. modular assemblies
• CPC Class Codes: Y02E 60/36 : Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
• CPC Class Codes: Y02E 60/50 : Fuel cells
• CPC Class Codes: Y02T 90/40 : Application of hydrogen technology to transportation, e.g. using fuel cells
• CPC Class Codes: Y10S 204/04 : Electrolysis cell combined with fuel cell

Abstract

A load management system for hydrogen-oxygen fuel cells is provided, for powering vehicles. The load management system operates such that under normal load conditions air is provided as the oxidizing agent for the hydrogen fuel. At high output conditions the air supply is enriched with additional oxygen. The system comprises means responsive to the amperage output from the fuel cell stack to activate valve means for the addition of pure oxygen into the air inlet line. There is also provided means for electrolyzing water to produce pure hydrogen and pure oxygen gas, which may be recyclable to the fuel cell.

Claims

1. A fuel cell power system for a vehicle comprising a fuel cell stack designed to operate using hydrogen gas as fuel and air as the oxidant during periods of normal power output, the system comprising the fuel cell stack;

means for providing hydrogen under pressure to the fuel cell; and

air means for supplying pressurized air as an oxidant gas for the fuel cell stack;

wherein the improvement comprises;

the fuel cell stack being designed to operate at a pressure of not more than about 30 psig above atmospheric pressure, and at a temperature below the boiling point of water at ambient pressure, and further comprising elevated pressure oxygen storage means to store substantially pure oxygen under elevated pressure;

valve means in fluid flow connection between the oxygen storage means and the air means, and means responsive to an amperage output from the fuel cell stack above a set level, for opening the valve so as to add pure oxygen to the supply of pressurized air fed to the fuel cell stack, to enrich the air fed to the fuel cell stack to contain at least 30% but not more than 60% oxygen by volume during periods when the amperage output is above a set level.

2. The fuel cell power system of claim 1, further comprising an electrolyzer for electrolyzing water to produce hydrogen and oxygen;

means to supply an electrolysis current to the electrolyzer; and

conduit means to carry the oxygen from the electrolyzer to the elevated pressure storage means.

3. The fuel cell power system of claim 2, wherein the vehicle is a land vehicle comprising wheels, and wherein the means to supply an electrolysis current to the electrolyzer, comprises regenerative braking power means mechanically connected to the wheels of the vehicle and electrically connected to the electrolyzer.

4. The fuel cell power system of claim 3, further comprising electrical control means electrically connected between the fuel cell stack and the electrolyzer and designed to supply current from the fuel cell stack when power demand for operating the vehicle is below a set level.

5. The fuel cell power system of claim 2, comprising a water reservoir in fluid flow connection between the fuel cell stack and the electrolyzer, and a pressure pump for pressurizing water from the reservoir and feeding the pressurized water to the electrolyzer at a pressure greater than that in the oxygen storage means.

6. The fuel cell power system of claim 2, wherein the electrolyzer is operated at a pressure of at least about 200 psig.

7. The fuel cell power system of claim 2, further comprising means to feed the hydrogen generated by the electrolyzer during normal power operation of the fuel cell stack directly back to the fuel cell stack.

8. The fuel cell power system of claim 1, wherein the fuel cell stack is designed to operate at a temperature in the range of from about 75°

to about 130°

F.

9. The fuel cell power system of claim 8, wherein the fuel cell stack is designed to operate at a pressure of from about 15 to about 25 psig.

10. The fuel cell power system of claim 1, wherein the fuel cell stack comprises an air inlet and an air outlet, and wherein the air passing through the fuel cell stack is subject to a pressure drop between the inlet and outlet, and wherein the fuel cell stack is designed to operate such that at maximum power for air, the pressure drop for air between the inlet to and the outlet from the stack is not greater than about 1.5 psi.

11. The fuel cell power system of claim 1, wherein the system is so designed that the air feed to the fuel cell stack is enriched to not more than about 50% oxygen by volume.

12. The fuel cell power system of claim 1, wherein air is pressurized in compressor means powered by electricity from the fuel cell stack to a pressure in the range of between about 15 and 20 psig, and the pressurized air from the pump is then cooled before being fed to the fuel cell stack.

13. The fuel cell power system of claim 12, wherein the pure oxygen gas admixed with the pressurized air is initially stored at a pressure of at least about 200 psig and is expanded upon admixing with the pressurized air.

14. The fuel cell power system for a vehicle comprising a fuel cell stack which is operated by hydrogen gas fuel and air during normal power intervals and oxygen enriched air to contain at least 30% but not more than 60% oxygen by volume during peak power intervals, a fuel cell stack having a plurality of cells, each cell comprising an anode and a cathode separated by an ion-exchange membrane;

means for providing hydrogen under pressure to the fuel cell stack;

means for supplying air under pressure as an oxidant gas for the fuel cell stack;

the fuel cell stack is designed to operate at an increased pressure of not more than about 30 psig and at a temperature below the boiling point of water at ambient pressure; and

an electrolyzer for electrolyzing water to produce hydrogen and oxygen;

means to supply an electrolysis current to the electrolyzer;

conduit means to carry the oxygen from the electrolyzer to the elevated pressure storage means;

a water reservoir in fluid flow connection between the fuel cell stack and the electrolyzer; and

a pressure pump for pressurizing water from the reservoir and feeding the pressurized water to the electrolizer at a pressure greater than that in the oxygen storage means.

15. The fuel cell power system of claim 14, wherein the fuel cell stack is designed to operate at a temperature in the range of from about 75°

to about 130°

F. and at a pressure of from about 15 to about 25 psig.

16. In a process for galvanically generating electricity, the process comprising separately passing hydrogen gas and air through a stack of ion-exchange membrane fuel cells, to generate electrical current and by-product water, and removing the by-product water;

wherein the improvement comprises feeding the air and hydrogen gas to the fuel cell stack at a pressure of not greater than about 30 psig and at a temperature below the ambient boiling point of water, and further providing pure oxygen gas which is admixed with the air fed to the fuel cell stack so that oxygen enriched air is fed to the fuel cell stack when the amperage output from the fuel cell stack is above a set level, wherein the proportion of oxygen in the oxygen enriched air is not greater than about 60% but not less than about 30% by volume.

17. The process of claim 16, further comprising pressurizing the by-product water to a pressure of at least about 200 psig, electrolyzing the by-product water to form hydrogen and oxygen gases to be recycled back to the fuel cell stack.

18. The process of claim 17, wherein the electrical power for electrolyzing the by-product water is generated at least in part by regenerative braking.

19. The process of claim 18, wherein at least a portion of the power for electrolyzing the by-product water is provided from the fuel cell stack when operating at below set power level.