Electrically stabilized liquid toners

• US 5,346,796 A
• Filed: 07/20/1992
• Issued: 09/13/1994
• Est. Priority Date: 07/20/1992
• Status: Expired due to Term

• Current Assignee: Hewlett-Packard Indigo BV (HP Inc.)
• Original Assignee: Spectrum Sciences BV
• Inventors: Almog, Yaacov
• Primary Examiner(s): Kight, III, John
• Assistant Examiner(s): Dodson, Shelley A.
• Application Number:
  US07/915,291
• Time in Patent Office: 785 Days
• Field of Search: 430/114, 430/115, 430/904, 430/110, 524/901
• US Class Current: 430/115
• CPC Class Codes: G03G 9/135 characterised by stabiliser or charge-controlling agents
• CPC Class Codes: Y10S 430/105 Polymer in developer
• CPC Class Codes: Y10S 524/901 Electrodepositable compositions

Abstract

A homogeneous liquid composition, for use in the preparation of liquid toners containing at least one charge director and in which the electrical properties of the charge director(s) is/are stabilized, comprises: (1) insulating non-polar carrier liquid compatible with liquid toners for electrostatic imaging; (2) at least one charge director other than an amine salt; and (3) at least one stabilizing component in an amount effective to stabilize the electrical properties of said at least one charge director, said component being selected from non-quaternary amine salts and being soluble in the carrier, e.g. diethylammonium chloride and isopropylamine dodecylbenzenesulfonate. The invention further relates to liquid toners for electrostatic imaging comprise thermoplastic resin particles dispersed in an insulating non polar carrier liquid, preferably a hydrocarbon having a volume resistivity above 10⁹ ohm-cm and a dielectric constant below 3.0, colorant particles micro-dispersed in said carrier liquid, at least one charge director, and at least one stabilizing component (3), as defined above; a method for producing the liquid toners; and an electrostatic imaging process utilizing the liquid toners.

Claims

1. A homogeneous liquid composition, for use in the preparation of liquid toners containing at least one charge director and in which the electrical properties of the charge director(s) is/are stabilized, which composition comprises:

(1) insulating non-polar carrier liquid compatible with liquid toners for electrostatic imaging;

(2) at least one charge director other than an amine salt; and

(3) at least one stabilizing component in an amount effective to stabilize the electrical properties of said at least one charge director, said component being selected from non-quaternary amine salts and being soluble in the carrier.

2. A homogeneous composition according to claim 1, wherein said insulating non-polar carrier liquid comprises an insulating non-polar liquid hydrocarbon having a volume resistivity above 10⁹ ohm-cm and a dielectric constant below 3.0.

3. A homogeneous composition according to claim 1, wherein the weight ratio of stabilizing component to charge director falls within the range of 0.001-2.0:

1.

4. A homogeneous composition according to claim 1, wherein component (3) is selected from non-quaternary salts of aliphatic amines with an acid selected from inorganic acids and alkyl-substituted aromatic sulfonic acids.

5. A homogeneous composition according to claim 1, wherein component (3) is selected from diethylammonium chloride and isopropylamine dodecylbenzenesulfonate.

6. A homogeneous composition according to claim 1, preceding claims, wherein said at least one charge director is selected from lecithin, basic barium petronate and calcium petronate.

7. A homogeneous composition according to claim 6, wherein component (3) is selected from diethylammonium chloride and isopropylamine dodecylbenzenesulfonate.

8. A liquid toner for electrostatic imaging which comprises insulating non-polar carrier liquid, colorant particles, at least one charge director other than an amine salt, and at least one stabilizing component in an amount effective to stabilize the electrical properties of said at least one charge director, said stabilizing component being selected from non-quaternary amine salts and being soluble in the carrier.

9. A liquid toner according to claim 8, wherein said insulating non-polar carrier liquid comprises an insulating non-polar liquid hydrocarbon having a volume resistivity above 10⁹ ohm-cm and a dielectric constant below 3.0.

10. A liquid toner according to claim 8, wherein the weight ratio of stabilizing component to charge director falls within the range of 0.001-2.0:

1.

11. A liquid toner according to claim 8, wherein said stabilizing component is selected from non-quaternary salts of aliphatic amines with an acid selected from inorganic acids and alkyl-substituted aromatic sulfonic acids.

12. A liquid toner according to claim 8, wherein said stabilizing component is selected from diethylammonium chloride and isopropylamine dodecylbenzenesulfonate.

13. A liquid toner according to claim 8, wherein said at least one charge director is selected from lecithin, basic barium petronate and calcium petronate.

14. A liquid toner according to claim 13, wherein said stabilizing component is selected from diethylammonium chloride and isopropylamine dodecylbenzenesulfonate.

15. A liquid toner for electrostatic imaging which comprises thermoplastic resin particles dispersed in an insulating non-polar carrier liquid having a volume resistivity above 10⁹ ohm-cm and a dielectric constant below 3.0;

colorant particles micro-dispersed in said carrier liquid;

at least one charge director other than an amine salt; and

at least one stabilizing component in an amount effective to stabilize the electrical properties of said at least one charge director, said stabilizing component being selected from non-quaternary salts of aliphatic amines with an acid selected from inorganic acids and alkyl-substituted aromatic sulfonic acids, and being soluble in the carrier.

16. A liquid toner according to claim 15, wherein the weight ratio of stabilizing component to charge director falls within the range of 0.001-2.0:

1.

17. A liquid toner according to claim 16, wherein said stabilizing component is selected from diethylammonium chloride and isopropylamine dodecylbenzenesulfonate.

18. A liquid toner according to claim 16, wherein said at least one charge director is selected from lecithin, basic barium petronate and calcium petronate.

19. A liquid toner according to claim 17, wherein said stabilizing component is selected from diethylammonium chloride and isopropylamine dodecylbenzenesulfonate.

20. An electrostatic imaging process which comprises the steps of:

forming a charged latent electrostatic image on a photoconductive surface;

applying to said surface charged colorant particles from a toner composition which comprises insulating non-polar carrier liquid, colorant particles, at least one charge director other than an amine salt and at least one stabilizing component in an amount effective to stabilize the electrical properties of said at least one charge director, said stabilizing component being selected from non-quaternary amine salts and being soluble in the carrier; and

transferring the resulting toner image to a substrate.