Enhancement of polycyanoacrylate-developed fingerprints

• US 5,348,159 A
• Filed: 06/29/1992
• Issued: 09/20/1994
• Est. Priority Date: 06/29/1992
• Status: Expired due to Fees

• Current Assignee: Her Majesty The Queen In Right of Canada As Represented By The Solicitor General of Canada
• Original Assignee: Her Majesty The Queen In Right of Canada As Represented By The Solicitor General of Canada
• Inventors: Wilkinson, Della A., Watkin, John E.
• Primary Examiner(s): LUSIGNAN, MICHAEL R
• Application Number:
  US07/905,325
• Time in Patent Office: 813 Days
• Field of Search: 206/568, 427/1, 427/558, 118/31.5, 424/617, 424/2
• US Class Current: 206/568
• CPC Class Codes: A61B 5/1172 using fingerprinting
• CPC Class Codes: C09K 11/06 containing organic luminescent materials

Abstract

The invention disclosed relates to a composition and method for enhancing the contrast of polycyanoacrylate-developed fingerprints and the like. The composition includes a metal chelate of the structural formula ##STR1## wherein R is a UV-absorbing aromatic group, X is an electron attracting group and M is a suitable metal ion, a suitable water-soluble organic solvent and water, at a pH of 3 to 10.

Claims

1. A method of enhancing the contrast of polycyanoacrylate-developed fingerprints, comprising

(a) treating polycyanoacrylate-developed fingerprints with a composition comprising metal chelate of structural formula I, ##STR7## wherein R is an aromatic group capable of absorbing UV light, X is an electron attracting group, and M is a suitable metal ion which upon exposure to sufficient UV radiation, intramolecularly receives UV energy absorbed by the chelate and emits the energy as visible fluorescence in a narrow wavelength emission band characteristic of the metal, a suitable water soluble organic solvent, and water;

and wherein the pH of the composition is 3 to 10, to form a two-phase solution of (i) the solvent and water including dissolved chelate and (ii) the solvent, excluding water but including dissolved chelate, in the cyanoacrylate polymer,

(b) evaporating the solvent leaving the chelate trapped in the cyanoacrylate polymer, and

(c) illuminating with a suitable UV light source to excite the chelate.

2. A method according to claim 1, wherein the organic solvent includes a polar functional group selected from a carbonyl group, a hydroxyl group and an ester group.

3. A method according to claim 2, wherein the organic solvent is a lower-alkyl ketone.

4. A method according to claim 3, wherein the organic solvent is methylethyl ketone.

5. A method according to claim 4, wherein the composition additionally comprises a suitable buffer, and wherein the pH is adjusted to about 8, by means of a suitable mineral acid.

6. A method according to claim 5, wherein the buffer is Tris amine buffer, pH 8.

7. A method according to claim 6, including the additional step of washing the fingerprints with a washing solution of 2-10% of a suitable non-ionic surfactant in methanol.

8. A method according to claim 7, wherein the dissolved chelate is transferred into the polycyanoacrylate in a partition ratio of 100 to 1000 fold.

9. A method according to claim 7, wherein prior to step (a) the composition is sonicated by ultrasound.

10. A method according claim 7, wherein the metal chelate is the tris chelate of thenoyltrifluoroacetone and the europium III ion.

11. A method according to claim 1, wherein the fingerprints are on human cadaver skin.

14. A combination according to claim 3, wherein (a) the organic compound is dissolved in a suitable organic solvent.

15. A combination according to claim 14, wherein the organic solvent is methylethyl ketone.

16. A combination according to claim 15, wherein the buffer is tris amine buffer pH 8.

17. A combination according to claim 16, wherein the salt is europium III chloride hexahydrate.

18. A combination according to claim 17, wherein the organic compound R is thiophene and X is CY₃, where Y is halogen including astatine.

19. A combination according to claim 18, wherein X is CF₃.

12. A kit for enhancing the contrast of polycyanoacrylate-developed fingerprints, comprising in combination

(a) an organic compound of the structural formula ##STR8## wherein R is an aromatic UV absorbing group and X is an electron attracting group,

(b) a suitable europium III salt, dissolved in an aqueous solution adjusted to a pH of about 8 by a suitable mineral acid and a suitable buffer pH 8, and

(c) kit means to separately contain and maintain apart until use, predetermined amounts of (a) (b).

13. A combination according to claim 12, wherein at the time of use (a) and (b) are combined and mixed vigorously with additional water and organic solvent to provide a working solution including about 22% of organic solvent.

20. A combination according to claim 13, wherein (a) includes 0.1 to 1 g of thenoyltrifluoroacetone, and wherein (b) includes 45 to 455 mg of europium III chloride hexahydrate, per litre of solution.

21. A combination according to claim 13, wherein (a) includes about 10 g of thenoyltrifluoroacetone, and wherein (b) includes about 4.55 g of europium III chloride hexahydrate dissolved in about 78 ml of the aqueous solution.