Use of a swellable plastic and process for making a resistive moisture sensor

• US 5,348,761 A
• Filed: 02/28/1992
• Issued: 09/20/1994
• Est. Priority Date: 08/29/1989
• Status: Expired due to Fees

• Current Assignee: E+E Elektronik Ges.m.b.H. (Dr. Johannes Heidenhain GmbH), Imi-Tech Fibres GmbH
• Original Assignee: Lenzing AG (B & C Privatstiftung), E+E Elektronik Ges.m.b.H. (Dr. Johannes Heidenhain GmbH)
• Inventors: Scharizer, Walter, Rossak, Norbert, Mitter, Helmut, Sollradl, Herbert
• Primary Examiner(s): Owens, Terry J.
• Assistant Examiner(s): CAMERON, ERMA C
• Application Number:
  US07/835,471
• Time in Patent Office: 935 Days
• Field of Search: 324/694, 427/8, 427/101, 338/35, 524/424, 524/439, 524/495, 524/496, 252/408.1, 252/963, 252/511, 252/512
• US Class Current: 427/101
• CPC Class Codes: G01M 3/045 with electrical detection means
• CPC Class Codes: G01N 27/121 for determining moisture content, e.g. humidity, of the fluid moisture content of the tested material G01N27/048
• CPC Class Codes: Y10S 252/963 Humidity or moisture indicators

Abstract

A process is disclosed for producing a swellable plastic resistive moisture sensor comprising dispersing an additive selected from the group consisting of carbon in powder, dust or soot form, carbon black, graphite, a metal in powder or dust form, and mixtures thereof, into a plastic comprising a polyimide or a copolyimide or both formed from diisocyanate and dianhydride reactants.

Claims

1. A process for producing a swellable plastic resistive moisture sensor comprising dispersing an additive selected from the group consisting of carbon in a powder, dust or soot physical state, carbon black, graphite, a metal in a powder or dust physical state, and mixtures thereof, into a plastic comprising a polyimide or a copolyimide or both formed from diisocyanate and dianhydride reactants.

2. The process according to claim 1, wherein said additive is selected from the group consisting of graphite in a weight percent concentration of up to 50% and carbon black in a weight percent concentration of 3-15%, wherein said additive has a specific surface area of 100 m/g to 1000 m/g.

3. The process according to claim 1, wherein dispersing agents are used for said additive and said additive has an average particle size of 25 micrometers or smaller.

4. The process according to claim 1, further comprising dissolving a polyimide or a copolyimide, having been completely imidized, in a polar solvent, dispersing said additive using a dispersing agent until the additive is homogeneously distributed in the polyimide or copolyimide, and applying said polyimide or copolyimide with said additive to an inert support, and drying.

5. The process according to claim 4, wherein drying is conducted in at least two to seven stages, with the first stage at a temperature ranging between 80°

and 140°

C., and each succeeding stage at a temperature increased by 50°

to 80°

C.

6. The process according to claim 5, wherein the maximum drying temperature for any stage is 280°

C.

7. The process according to claim 5, wherein the maximum drying temperature for any stage is 260°

C.

8. The process according to claims 4 or 5, wherein the specific resistance of said plastic is 0.5 to 50 kiloOhm-cm.

9. The process according to claims 4 or 5, wherein the specific resistance of said plastic is 5 to 30 kiloOhm-cm.

10. The process according to claim 4, wherein said copolyimide comprises, 3,3'"'"'4,4'"'"'-benzophenone tetracarboxylic acid dianhydride and at least one compound selected from the group consisting of toluylene diamine and toluylene diisocyante and at least one compound selected from the group consisting of 4'"'"'4-methylene-bis-(phenylamine) and 4,4'"'"'-methylene-bis-(phenylisocyanate), in a polar solvent.