Monoaxially oriented multilayered packaging material

• US 5,348,794 A
• Filed: 08/23/1993
• Issued: 09/20/1994
• Est. Priority Date: 01/30/1990
• Status: Expired due to Fees

• Current Assignee: Nippon Petrochemicals Co., Ltd. (ENEOS Holdings, Inc.)
• Original Assignee: Nippon Petrochemicals Co., Ltd. (ENEOS Holdings, Inc.)
• Inventors: Takahashi, Tomonori, Ogasawara, Isamu, Oka, Masataka, Kimura, Masato
• Primary Examiner(s): NAKARANI, DHIRAJLAL S
• Application Number:
  US08/110,492
• Time in Patent Office: 393 Days
• Field of Search: 428/213, 428/215, 428/474.4, 428/474.7, 428/475.2, 428/475.8, 428/476.1, 428/476.3, 428/910, 264/210.2, 264/280, 264/288.4
• US Class Current: 428/213
• CPC Class Codes: B29C 55/023 using multilayered plates or sheets
• CPC Class Codes: B29C 55/04 uniaxial, e.g. oblique
• CPC Class Codes: B29C 55/18 by squeezing between surfaces, e.g. rollers
• CPC Class Codes: B29K 2077/00 Use of PA, i.e. polyamides, e.g. polyesteramides or derivatives thereof, as moulding material
• CPC Class Codes: B29K 2995/0026 Transparent
• CPC Class Codes: B32B 27/34 comprising polyamides
• CPC Class Codes: Y10S 428/91 Product with molecular orientation
• CPC Class Codes: Y10T 428/2495 Thickness [relative or absolute]
• CPC Class Codes: Y10T 428/24967 Absolute thicknesses specified
• CPC Class Codes: Y10T 428/31725 Of polyamide
• CPC Class Codes: Y10T 428/31728 Next to second layer of polyamide
• CPC Class Codes: Y10T 428/31736 Next to polyester
• CPC Class Codes: Y10T 428/31743 Next to addition polymer from unsaturated monomer[s]
• CPC Class Codes: Y10T 428/31746 Polymer of monoethylenically unsaturated hydrocarbon
• CPC Class Codes: Y10T 428/3175 Next to addition polymer from unsaturated monomer[s]

Abstract

A multilayered packaging material having good piercing resistance and tearability and being excellent in appearance, transparency and so forth, can be produced by orienting multilayered structure which is composed of a polyamide resin layer and other thermoplastic resin layer(s) at a monoaxially stretching ratio of 1.5- to 7.0-fold in such a manner that the thickness of the polyamide resin layer is 3 to 30 μm and the thickness(es) of the other thermoplastic resin layer(s) is (are) at least twice as much as that of the polyamide resin layer.

Claims

1. A monoaxially oriented multilayered packaging material obtained by the steps comprising passing a multilayered structure including one polyamide resin layer and another thermoplastic layer through at least one pair of rolls such that the ratio of the thickness of said structure before rolling to the thickness after rolling is 1.5:

1 to 7.0;

1, wherein the thickness of the polyamide resin layer is 3 to 30 μ

m and the thickness of the other thermoplastic resin layer is at least twice that of the polyamide resin layer.

2. The monoaxially oriented multilayered packaging material as claimed in claim 1 wherein said other thermoplastic resin layer is a layer formed of a thermoplastic selected from the group consisting of high density polyethylene, linear low density polyethylene, polypropylene, an ethylene-vinyl alcohol copolymer, polyvinylidene chloride, polyacrylonitrile, a polyester resin and polystyrene.

3. The monoaxially oriented multilayered packaging material as claimed claim 1 or claim 2 wherein a sealant layer having a melting point lower than the melting point of the resins of said multilayered structure is provided on either outside layer of the multilayered packaging material.

4. A method of producing a monoaxially oriented multilayered packaging material which comprises passing a multilayered structure composed of a polyamide resin layer, another thermoplastic layer and a sealant layer in that order, the sealant layer having the lowest melting point of all component resins, through at lest one pair of rolls, which are heated to a temperature in the range of from below the melting point of the sealant layer resin to 70°

C. lower than the melting point of the sealant layer resin, such that the ratio of the thickness of said multilayered structure before rolling to its thickness after rolling is 1.5;

1 to 7.0;

1, wherein the thickness of the polyamide resin layer is 3 to 30 microns and the thickness of said another thermoplastic layer is at least twice that of the polyamide resin layer.

5. The method as claimed in claim 4 wherein the surface roughness of the rolls used in said step of passing said multilayered structure through at least one pair of rolls is, in accordance with JIS B 0601, no greater than 1 s.

6. The method as claimed in claim 4 or claim 5 wherein said another thermoplastic layer is formed of a thermoplastic resin selected from the group consisting of high density polyethylene, linear low density polyethylene, polypropylene, polybutene-1, an ethylene-vinyl alcohol copolymer, polyvinylidene chloride, polyacrylonitrile, a polyester resin and polystyrene.